Literature DB >> 22488638

The elusive tetrasulfate anion [S4O13](2-).

Christian Logemann1, Thorsten Klüner, Mathias S Wickleder.   

Abstract

Sulfates united: the unique tetrasulfate S(4)O(13)(2-) anion was observed in the structure of (NO(2))(2)[S(4)O(13)] that forms in the reaction of N(2)O(5) with SO(3). Theoretical investigations show that the anion is a stable member of the polysulfate series [S(n)O(3n+1)](2-), which was investigated up to n=11.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 22488638     DOI： 10.1002/anie.201108206

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Coordination polymer flexibility leads to polymorphism and enables a crystalline solid-vapour reaction: a multi-technique mechanistic study.

Authors:  Iñigo J Vitórica-Yrezábal; Stefano Libri; Jason R Loader; Guillermo Mínguez Espallargas; Michael Hippler; Ashleigh J Fletcher; Stephen P Thompson; John E Warren; Daniele Musumeci; Michael D Ward; Lee Brammer
Journal:  Chemistry       Date:  2015-05-11       Impact factor: 5.236

2.  Arene Selectivity by a Flexible Coordination Polymer Host.

Authors:  James S Wright; Iñigo J Vitórica-Yrezábal; Stephen P Thompson; Lee Brammer
Journal:  Chemistry       Date:  2016-08-02       Impact factor: 5.236

3.  S6 N2 O15 -A Nitrogen-Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido-tris-Sulfuric Acid.

Authors:  David van Gerven; Mathias S Wickleder
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-04       Impact factor: 15.336
  3 in total

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