Literature DB >> 22475006

Cavitand-functionalized SWCNTs for N-methylammonium detection.

Marco Dionisio1, Jan M Schnorr, Vladimir K Michaelis, Robert G Griffin, Timothy M Swager, Enrico Dalcanale.   

Abstract

Single-walled carbon nanotubes (SWCNTs) have been functionalized with highly selective tetraphosphonate cavitand receptors. The binding of charged N-methylammonium species to the functionalized SWCNTs was analyzed by X-ray photoelectron spectroscopy and confirmed by (31)P MAS NMR spectroscopy. The cavitand-functionalized SWCNTs were shown to function as chemiresistive sensory materials for the detection of sarcosine and its ethyl ester hydrochloride in water with high selectivity at concentrations as low as 0.02 mM. Exposure to sarcosine and its derivative resulted in an increased conductance, in contrast to a decreased conductance response observed for potential interferents such as the structurally related glycine ethyl ester hydrochloride.
© 2012 American Chemical Society

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Year:  2012        PMID: 22475006      PMCID: PMC3334860          DOI: 10.1021/ja301174m

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  29 in total

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