| Literature DB >> 22473788 |
Paul Benndorf1, Sophia Schmitt, Ralf Köppe, Pascual Oña-Burgos, Andreas Scheurer, Karsten Meyer, Peter W Roesky.
Abstract
Easy come, easy go: the first molecular SO(2) complexes of the lanthanides (Ln=Sm, Eu) have been prepared. The compounds can reversibly coordinate gaseous SO(2). Concomitant with the addition and removal of SO(2), the color of the complexes changes reversibly. The structures of the SO(2) compounds could be confirmed in solution and in the solid state.Entities:
Year: 2012 PMID： 22473788 DOI： 10.1002/anie.201109109
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336