Literature DB >> 22473627

Immobilization of large, aliovalent cations in the small-pore zeolite K-natrolite by means of pressure.

Yongjae Lee1, Yongmoon Lee, Donghoon Seoung, Jun-Hyuk Im, Hee-Jung Hwang, Tae-Hyun Kim, Dan Liu, Zhenxian Liu, Seung Yeop Lee, Chi-Chang Kao, Thomas Vogt.   

Abstract

High-pressure ion exchange of small-pore zeolite K-natrolite allows immobilization of nominally non-exchangeable aliovalent cations such as trivalent europium. A sample exchanged at 3.0(1) GPa and 250 °C contains about 4.7 Eu(III) ions per unit cell, which is equivalent to over 90 % of the K(+) cations being exchanged.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID: 22473627     DOI: 10.1002/anie.201201045

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  Pressure- and Temperature-Induced Insertion of N2, O2 and CH4 to Ag-Natrolite.

Authors:  Donghoon Seoung; Hyeonsu Kim; Pyosang Kim; Yongmoon Lee
Journal:  Materials (Basel)       Date:  2020-09-15       Impact factor: 3.623

  1 in total

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