| Literature DB >> 22458387 |
Juan Diwu1, Thomas E Albrecht-Schmitt.
Abstract
A mixed-valent uranium(IV,VI) diphosphonate, (H(3)O)(2)(UO(2))(3)U(H(2)O)(2)[CH(2)(PO(3))(2)](3)·6H(2)O (UC1P2S), has been synthesized under hydrothermal conditions. S-2-butanol was used to reduce uranium VI to IV. The tetravalent uranium centers adopt eight-coordinate geometries, while hexavalent uranyl units are all tetragonal bipyramids. The UV-vis-NIR spectrum of UC1P2S shows absorption features for both U(VI) and U(IV).Entities:
Year: 2012 PMID： 22458387 DOI： 10.1021/ic300391p
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165