Literature DB >> 22455074

In situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N.

Daniel J Bull1, Natalie Sorbie, Gael Baldissin, David Moser, Mark T F Telling, Ronald I Smith, Duncan H Gregory, D Keith Ross.   

Abstract

The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a non-stoichiometric Li4-2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4-2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.

Entities:  

Year:  2011        PMID: 22455074     DOI: 10.1039/c0fd00020e

Source DB:  PubMed          Journal:  Faraday Discuss        ISSN: 1359-6640            Impact factor:   4.008


  1 in total

1.  Compositional flexibility in Li-N-H materials: implications for ammonia catalysis and hydrogen storage.

Authors:  Joshua W Makepeace; Jake M Brittain; Alisha Sukhwani Manghnani; Claire A Murray; Thomas J Wood; William I F David
Journal:  Phys Chem Chem Phys       Date:  2021-07-21       Impact factor: 3.676

  1 in total

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