| Literature DB >> 22455034 |
Kenneth R Harris1, Mitsuhiro Kanakubo.
Abstract
High pressure measurements have been made of viscosities, ion self-diffusion coefficients and electrical conductivities of ionic liquids, mainly of imidazolium salts. We review how these properties have been analysed in terms of the empirical Stokes-Einstein, Walden and Nernst-Einstein equations, and examine trends revealed by the phenomenological approach of velocity correlation coefficients and the more general theory of density scaling. Finally we examine the possibility of dynamic crossover in the transport properties of ionic liquids.Entities:
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Year: 2012 PMID: 22455034 DOI: 10.1039/c1fd00085c
Source DB: PubMed Journal: Faraday Discuss ISSN: 1359-6640 Impact factor: 4.008