Literature DB >> 22441208

A general and efficient aldehyde decarbonylation reaction by using a palladium catalyst.

Atanu Modak1, Arghya Deb, Tuhin Patra, Sujoy Rana, Soham Maity, Debabrata Maiti.   

Abstract

A facile decarbonylation reaction of aldehydes has been developed by employing Pd(OAc)(2). A wide variety of substrates are decarbonylated, without using any exogenous ligand for palladium as well as CO-scavenger.

Entities:  

Year:  2012        PMID： 22441208     DOI： 10.1039/c2cc31144e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  11 in total

1.  Aldehyde Decarbonylases: Enigmatic Enzymes of Hydrocarbon Biosynthesis.

Authors:  E Neil G Marsh; Matthew W Waugh
Journal:  ACS Catal       Date:  2013-11-01       Impact factor: 13.084

2.  Controlled Rh-Catalyzed Mono- and Double-decarbonylation of Alkynyl α-Diones To Form Conjugated Ynones and Disubstituted Alkynes.

Authors:  Rachel E Whittaker; Guangbin Dong
Journal:  Org Lett       Date:  2015-10-27       Impact factor: 6.005

3.  Bidentate Nitrogen-Ligated I(V) Reagents, Bi(N)-HVIs: Preparation, Stability, Structure, and Reactivity.

Authors:  Xiao Xiao; Jessica M Roth; Nathaniel S Greenwood; Maria K Velopolcek; Jordan Aguirre; Mona Jalali; Alireza Ariafard; Sarah E Wengryniuk
Journal:  J Org Chem       Date:  2021-04-19       Impact factor: 4.198

4.  α-Hydroxy acid as an aldehyde surrogate: metal-free synthesis of pyrrolo[1,2-a]quinoxalines, quinazolinones, and other N-heterocycles via decarboxylative oxidative annulation reaction.

Authors:  Mayavan Viji; Manjunatha Vishwanath; Jaeuk Sim; Yunjeong Park; Chanhyun Jung; Seohu Lee; Heesoon Lee; Kiho Lee; Jae-Kyung Jung
Journal:  RSC Adv       Date:  2020-10-07       Impact factor: 4.036

5.  A Domino Oxidation/Arylation/Protodecarboxylation Reaction of Salicylaldehydes: Expanded Access to meta-Arylphenols.

Authors:  Junfei Luo; Sara Preciado; Solomon Olatokunbo Araromi; Igor Larrosa
Journal:  Chem Asian J       Date:  2015-06-25

6.  Synthesis of (E,E)-Dienones and (E,E)-Dienals via Palladium-Catalyzed γ,δ-Dehydrogenation of Enones and Enals.

Authors:  Gao-Fei Pan; Xing-Long Zhang; Xue-Qing Zhu; Rui-Li Guo; Yong-Qiang Wang
Journal:  iScience       Date:  2019-09-21

7.  Rh-Catalyzed Decarbonylation of Conjugated Ynones via Carbon-Alkyne Bond Activation: Reaction Scope and Mechanistic Exploration via DFT Calculations.

Authors:  Alpay Dermenci; Rachel E Whittaker; Yang Gao; Faben A Cruz; Zhi-Xiang Yu; Guangbin Dong
Journal:  Chem Sci       Date:  2015       Impact factor: 9.825

8.  Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol.

Authors:  Marina Caporaso; Giancarlo Cravotto; Spyros Georgakopoulos; George Heropoulos; Katia Martina; Silvia Tagliapietra
Journal:  Beilstein J Org Chem       Date:  2014-06-26       Impact factor: 2.883

9.  The reactivity of acyl chlorides towards sodium phosphaethynolate, Na(OCP): a mechanistic case study.

Authors:  Dominikus Heift; Zoltán Benkő; Riccardo Suter; René Verel; Hansjörg Grützmacher
Journal:  Chem Sci       Date:  2016-06-17       Impact factor: 9.825

10.  Total Synthesis of Xanthoangelol B and Its Various Fragments: Toward Inhibition of Virulence Factor Production of Staphylococcus aureus.

Authors:  Pushpak Mizar; Rekha Arya; Truc Kim; Soyoung Cha; Kyoung-Seok Ryu; Won-Sik Yeo; Taeok Bae; Dae Wook Kim; Ki Hun Park; Kyeong Kyu Kim; Seung Seo Lee
Journal:  J Med Chem       Date:  2018-11-14       Impact factor: 7.446
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