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Literature DB >> 22431399

Simple gold-catalyzed synthesis of benzofulvenes--gem-diaurated species as "instant dual-activation" precatalysts.

A Stephen K Hashmi¹, Ingo Braun, Pascal Nösel, Johannes Schädlich, Marcel Wieteck, Matthias Rudolph, Frank Rominger.

Abstract

Entities: Chemical

Year: 2012 PMID： 22431399 DOI： 10.1002/anie.201109183

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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22 in total

1. Direct Evidence for the Origin of Bis-Gold Intermediates: Probing Gold Catalysis with Mass Spectrometry.

Authors: Mei Lu; Yijin Su; Pengyi Zhao; Xiaohan Ye; Yi Cai; Xiaodong Shi; Eric Masson; Fengyao Li; J Larry Campbell; Hao Chen
Journal: Chemistry Date: 2018-01-17 Impact factor: 5.236

2. Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.

Authors: Timothy J Brown; Dieter Weber; Michel R Gagné; Ross A Widenhoefer
Journal: J Am Chem Soc Date: 2012-05-29 Impact factor: 15.419

3. Mechanism of AuCl₃-catalyzed cyclization of 1-(indol-2-yl)-3-alkyn-1-ols: a DFT study.

Authors: Jingna Shao; Rongxing He; Wei Shen; Ming Li
Journal: J Mol Model Date: 2014-05-07 Impact factor: 1.810

4. Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes.

Authors: Gaël Ung; Michele Soleilhavoup; Guy Bertrand
Journal: Angew Chem Int Ed Engl Date: 2012-11-21 Impact factor: 15.336

Simple gold-catalyzed synthesis of benzofulvenes--gem-diaurated species as "instant dual-activation" precatalysts.

1. Direct Evidence for the Origin of Bis-Gold Intermediates: Probing Gold Catalysis with Mass Spectrometry.

2. Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.

3. Mechanism of AuCl₃-catalyzed cyclization of 1-(indol-2-yl)-3-alkyn-1-ols: a DFT study.

4. Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes.

5. σ-π-Diauration as an alternative binding mode for digold intermediates in gold(i) catalysis.

6. Gold-catalyzed cyclizations of cis-enediynes: insights into the nature of gold-aryne interactions.

7. Monoaurated vs. diaurated intermediates: causality or independence?

8. Dissecting Anion Effects in Gold(I)-Catalyzed Intermolecular Cycloadditions.

9. Synthesis of axially chiral gold complexes and their applications in asymmetric catalyses.

10. Anatomy of gold catalysts: facts and myths.