| Literature DB >> 22430897 |
Boris A Trofimov1, Andrey V Ivanov, Igor A Ushakov, Elena Yu Schmidt, Lyubov N Sobenina, Alexander M Vasil'tsov, Albina I Mikhaleva.
Abstract
N-Vinylpyrroles and -indoles bearing electron-withdrawing substituents at the pyrrole ring are mercurated, with 1 equivalent of Hg(OAc)(2) in dry MeCN (20-80 °C), regioselectively at the vinyl group (yields are almost quantitative), while their congeners without electron-withdrawing functions are mercurated both at the N-vinyl group and the pyrrole ring.Entities:
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Year: 2012 PMID: 22430897 DOI: 10.1039/c2dt12393b
Source DB: PubMed Journal: Dalton Trans ISSN: 1477-9226 Impact factor: 4.390