Literature DB >> 22430713

Rhodium-catalysed intramolecular trans-bis-silylation of alkynes to synthesise 3-silyl-1-benzosiloles.

Takanori Matsuda1, Yoichiro Ichioka.   

Abstract

Intramolecular addition of a Si-Si bond across a C-C triple bond occurs in a trans fashion in the presence of rhodium(I) catalysts. The trans-bis-silylation reaction of (2-alkynylphenyl)disilanes affords 3-silyl-1-benzosiloles. This journal is © The Royal Society of Chemistry 2012

Entities:  

Year:  2012        PMID: 22430713     DOI: 10.1039/c2ob25242b

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  2 in total

Review 1.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

2.  Synthesis of Pyridine-Fused Siloles by Palladium-Catalyzed Intramolecular Bis-Silylation.

Authors:  Akinobu Naka; Natsumi Shimomura; Hisayoshi Kobayashi
Journal:  ACS Omega       Date:  2022-08-16
  2 in total

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