Literature DB >> 22421951

Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles.

Xinxin Qi1, Xianxiu Xu, Cheol-Min Park.   

Abstract

Free carbenes generated from α-diazo oxime ethers by photolysis undergo facile N-O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent yields. This method allowed for the development of a tandem reaction for pyrrole synthesis via 1,3-dipolar cycloaddition.

Entities:  

Year:  2012        PMID： 22421951     DOI： 10.1039/c2cc30490b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Copper-catalyzed condensation of imines and α-diazo-β-dicarbonyl compounds: modular and regiocontrolled synthesis of multisubstituted pyrroles.

Authors:  Wei Wen Tan; Naohiko Yoshikai
Journal:  Chem Sci       Date:  2015-08-03       Impact factor: 9.825

2.  One-pot sequential multicomponent reaction between in situ generated aldimines and succinaldehyde: facile synthesis of substituted pyrrole-3-carbaldehydes and applications towards medicinally important fused heterocycles.

Authors:  Anoop Singh; Nisar A Mir; Sachin Choudhary; Deepika Singh; Preetika Sharma; Rajni Kant; Indresh Kumar
Journal:  RSC Adv       Date:  2018-04-24       Impact factor: 4.036
  2 in total

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