Literature DB >> 22374241

Heterolytic dihydrogen activation by B(C6F5)3 and carbonyl compounds.

Markus Lindqvist1, Nina Sarnela, Victor Sumerin, Konstantin Chernichenko, Markku Leskelä, Timo Repo.   

Abstract

Aromatic carbonyl compounds in combination with B(C(6)F(5))(3) are able to activate H(2) heterolytically. The reactivity of the carbonyl-B(C(6)F(5))(3) adduct is initiated by its thermal dissociation into components. After H(2) addition, aromatic carbonyl compounds convert into aryl-substituted methanes or alcohols.

Entities:  

Year:  2012        PMID: 22374241     DOI: 10.1039/c2dt12268e

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  2 in total

1.  Direct Reductive Amination of Carbonyl Compounds Catalyzed by a Moisture Tolerant Tin(IV) Lewis Acid.

Authors:  Joshua S Sapsford; Daniel J Scott; Nathan J Allcock; Matthew J Fuchter; Christopher J Tighe; Andrew E Ashley
Journal:  Adv Synth Catal       Date:  2018-01-15       Impact factor: 5.837

Review 2.  Defunctionalisation catalysed by boron Lewis acids.

Authors:  Huaquan Fang; Martin Oestreich
Journal:  Chem Sci       Date:  2020-07-28       Impact factor: 9.825

  2 in total

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