Literature DB >> 22372582

1,1-Carboboration route to substituted naphthalenes.

René Liedtke1, Marcel Harhausen, Roland Fröhlich, Gerald Kehr, Gerhard Erker.   

Abstract

1,2-Bis(alkynyl)benzene derivatives react with strongly electrophilic boranes to yield in boryl-functionalized bulky naphthalene derivatives by means of a sequence of 1,1-carboboration reactions. These substrates can be functionalized by transition metal catalyzed cross-coupling reactions.

Entities:  

Year:  2012        PMID: 22372582     DOI: 10.1021/ol300193e

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Contrasting Frustrated Lewis Pair Reactivity with Selenium- and Boron-Based Lewis Acids.

Authors:  Lewis C Wilkins; Benjamin A R Günther; Melanie Walther; James R Lawson; Thomas Wirth; Rebecca L Melen
Journal:  Angew Chem Int Ed Engl       Date:  2016-08-03       Impact factor: 15.336

2.  Advanced 1,1-carboboration reactions with pentafluorophenylboranes.

Authors:  Gerald Kehr; Gerhard Erker
Journal:  Chem Sci       Date:  2015-10-08       Impact factor: 9.825

  2 in total

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