Literature DB >> 22372403

Guest-to-host transmission of structural changes for stimuli-responsive adsorption property.

Nobuhiro Yanai1, Takashi Uemura, Masafumi Inoue, Ryotaro Matsuda, Tomohiro Fukushima, Masahiko Tsujimoto, Seiji Isoda, Susumu Kitagawa.   

Abstract

We show that structural changes of a guest molecule can trigger structural transformations of a crystalline host framework. Azobenzene was introduced into a flexible porous coordination polymer (PCP), and cis/trans isomerizations of the guest azobenzene by light or heat successfully induced structural transformations of the host PCP in a reversible fashion. This guest-to-host structural transmission resulted in drastic changes in the gas adsorption property of the host-guest composite, displaying a new strategy for creating stimuli-responsive porous materials.

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Year:  2012        PMID： 22372403     DOI： 10.1021/ja2115713

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  25 in total

1.  Photoinduced reversible switching of porosity in molecular crystals based on star-shaped azobenzene tetramers.

Authors:  Massimo Baroncini; Simone d'Agostino; Giacomo Bergamini; Paola Ceroni; Angiolina Comotti; Piero Sozzani; Irene Bassanetti; Fabrizia Grepioni; Taylor M Hernandez; Serena Silvi; Margherita Venturi; Alberto Credi
Journal:  Nat Chem       Date:  2015-07-06       Impact factor: 24.427

2.  Supramolecular-jack-like guest in ultramicroporous crystal for exceptional thermal expansion behaviour.

Authors:  Hao-Long Zhou; Yue-Biao Zhang; Jie-Peng Zhang; Xiao-Ming Chen
Journal:  Nat Commun       Date:  2015-04-21       Impact factor: 14.919

3.  Tunable two-color luminescence and host-guest energy transfer of fluorescent chromophores encapsulated in metal-organic frameworks.

Authors:  Dongpeng Yan; Yanqun Tang; Heyang Lin; Dan Wang
Journal:  Sci Rep       Date:  2014-03-11       Impact factor: 4.379

4.  Tunable molecular separation by nanoporous membranes.

Authors:  Zhengbang Wang; Alexander Knebel; Sylvain Grosjean; Danny Wagner; Stefan Bräse; Christof Wöll; Jürgen Caro; Lars Heinke
Journal:  Nat Commun       Date:  2016-12-20       Impact factor: 14.919

5.  Light driven mesoscale assembly of a coordination polymeric gelator into flowers and stars with distinct properties.

Authors:  Rahul Dev Mukhopadhyay; Vakayil K Praveen; Arpan Hazra; Tapas Kumar Maji; Ayyappanpillai Ajayaghosh
Journal:  Chem Sci       Date:  2015-08-12       Impact factor: 9.825

6.  Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation.

Authors:  Nicholaus Prasetya; Anastasia A Teck; Bradley P Ladewig
Journal:  Sci Rep       Date:  2018-02-13       Impact factor: 4.379

7.  Redox-switchable breathing behavior in tetrathiafulvalene-based metal-organic frameworks.

Authors:  Jian Su; Shuai Yuan; Hai-Ying Wang; Lan Huang; Jing-Yuan Ge; Elizabeth Joseph; Junsheng Qin; Tahir Cagin; Jing-Lin Zuo; Hong-Cai Zhou
Journal:  Nat Commun       Date:  2017-12-08       Impact factor: 14.919

8.  Metal-organic tube or layered assembly: reversible sheet-to-tube transformation and adaptive recognition.

Authors:  Jiayue Tian; Luyao Liu; Kang Zhou; Zixiao Hong; Qihui Chen; Feilong Jiang; Daqiang Yuan; Qingfu Sun; Maochun Hong
Journal:  Chem Sci       Date:  2020-08-12       Impact factor: 9.825

9.  Controlling the alignment of 1D nanochannel arrays in oriented metal-organic framework films for host-guest materials design.

Authors:  Kenji Okada; Miharu Nakanishi; Ken Ikigaki; Yasuaki Tokudome; Paolo Falcaro; Christian J Doonan; Masahide Takahashi
Journal:  Chem Sci       Date:  2020-07-14       Impact factor: 9.825

10.  Electrically Induced Breathing of the MIL-53(Cr) Metal-Organic Framework.

Authors:  Aziz Ghoufi; Karima Benhamed; Leila Boukli-Hacene; Guillaume Maurin
Journal:  ACS Cent Sci       Date:  2017-04-07       Impact factor: 14.553
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