Literature DB >> 22371205

A non-metal catalysed oxidation of primary azides to nitriles at ambient temperature.

Manjunath Lamani1, Pradeep Devadig, Kandikere Ramaiah Prabhu.   

Abstract

A novel non-metal catalyzed oxidation of organic azides to nitriles under solvent-free conditions is presented employing catalytic amounts of KI, and DABCO in aq. TBHP at room temperature. This non-metal catalyzed oxidation of azides provides good selectivity as double and triple bonds were not oxidized under the present reaction conditions. This journal is © The Royal Society of Chemistry 2012

Entities:  

Year:  2012        PMID: 22371205     DOI: 10.1039/c2ob06949k

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  2 in total

Review 1.  Allylic azides: synthesis, reactivity, and the Winstein rearrangement.

Authors:  Angela S Carlson; Joseph J Topczewski
Journal:  Org Biomol Chem       Date:  2019-05-08       Impact factor: 3.876

2.  On the Unique Reactivity of Pd(OAc)2 with Organic Azides: Expedient Synthesis of Nitriles and Imines.

Authors:  Laura Martínez-Sarti; Silvia Díez-González
Journal:  ChemCatChem       Date:  2013-04-10       Impact factor: 5.686

  2 in total

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