Literature DB >> 22369242

"Zeoball" [Sn36Ge24Se132]24-: a molecular anion with zeolite-related composition and spherical shape.

Yumei Lin1, Werner Massa, Stefanie Dehnen.   

Abstract

Ionothermal reactions of [Ge(4)Se(10)](4-) with SnCl(4)·5H(2)O yielded [BMMIm](24)[Sn(36)Ge(24)Se(132)] (ZBT-1) and [BMIm](24)[Sn(32.5)Ge(27.5)Se(132)] [ZBT-2; B(M)MIm = 1-butyl-(2,)3-(di)methylimidazolium]. These contain the largest known discrete polyanion consisting only of main-group elements. In spite of a zeolite-related composition, the 192-atom "zeoball" anion adopts a spherical shape, which has been unprecedented in the chemistry of zeolites and their homologues and relatives. Preliminary studies indicated that ZBT-1 traps I(2) molecules and induces heterolytic I-I bond cleavage.

Entities:  

Year:  2012        PMID： 22369242     DOI： 10.1021/ja2115635

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

Review 1.  Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids.

Authors:  Matthias F Groh; Alexander Wolff; Matthias A Grasser; Michael Ruck
Journal:  Int J Mol Sci       Date:  2016-09-01       Impact factor: 5.923

2.  An Icosidodecahedral Supramolecule Based on Pentaphosphaferrocene: From a Disordered Average Structure to Individual Isomers.

Authors:  Claudia Heindl; Eugenia Peresypkina; Alexander V Virovets; Ivan S Bushmarinov; Michael G Medvedev; Barbara Krämer; Birger Dittrich; Manfred Scheer
Journal:  Angew Chem Int Ed Engl       Date:  2017-09-18       Impact factor: 15.336

3.  Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles.

Authors:  Bertram Peters; Silke Santner; Carsten Donsbach; Pascal Vöpel; Bernd Smarsly; Stefanie Dehnen
Journal:  Chem Sci       Date:  2019-04-22       Impact factor: 9.825

4.  Metal-Deficient Supramolecule Based on a Fivefold-Symmetric Building Block.

Authors:  Jana Schiller; Eugenia Peresypkina; Alexander V Virovets; Manfred Scheer
Journal:  Angew Chem Int Ed Engl       Date:  2020-05-26       Impact factor: 15.336

5.  Hydrazine-solvothermal methods to synthesize polymeric thioarsenates from one-dimensional chains to a three-dimensional framework.

Authors:  Jingyu Han; Shufen Li; Chunying Tang; Wei Zheng; Wenqing Jiang; Dingxian Jia
Journal:  RSC Adv       Date:  2018-10-04       Impact factor: 4.036

Review 6.  Current advances in tin cluster chemistry.

Authors:  Bertram Peters; Niels Lichtenberger; Eike Dornsiepen; Stefanie Dehnen
Journal:  Chem Sci       Date:  2019-10-21       Impact factor: 9.825
  6 in total

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