| Literature DB >> 22369157 |
Akihiro Ogura1, Kohei Yamada, Satoshi Yokoshima, Tohru Fukuyama.
Abstract
A novel synthetic route to (-)-anisatin has been developed. Our synthesis features a rhodium-catalyzed 1,4-addition of an arylboronic acid, an intramolecular Diels-Alder reaction of an ortho-quinone monoketal, a stereoselective [2,3]-Wittig rearrangement, and construction of the oxabicyclo [3.3.1] skeleton via cleavage of an epoxide by a primary amide.Entities:
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Year: 2012 PMID: 22369157 DOI: 10.1021/ol300390k
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005