Literature DB >> 22366725

A heterotrimetallic Pd-Sm-Pd complex for asymmetric Friedel-Crafts alkylations of pyrroles with nitroalkenes.

Guoqi Zhang1.   

Abstract

Catalytic asymmetric Friedel-Crafts alkylations of pyrroles and nitroalkenes were carried out by using a novel heterotrimetallic Pd-Sm-Pd catalyst based on a simple chiral ligand 1, to give the adducts with high yields and up to 93% ee.

Entities:  

Year:  2012        PMID： 22366725     DOI： 10.1039/c2ob25074h

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  2 in total

1.  1,4-Addition of TMSCCl₃ to nitroalkenes: efficient reaction conditions and mechanistic understanding.

Authors:  Na Wu; Benoit Wahl; Simon Woodward; William Lewis
Journal:  Chemistry       Date:  2014-05-21       Impact factor: 5.236

2.  Structural, Luminescent and Thermal Properties of Heteronuclear PdII⁻LnIII⁻PdII Complexes of Hexadentate N₂O₄ Schiff Base Ligand.

Authors:  Barbara Miroslaw; Beata Cristóvão; Zbigniew Hnatejko
Journal:  Molecules       Date:  2018-09-21       Impact factor: 4.411
  2 in total

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