| Literature DB >> 22344391 |
Kenji Matsumoto1, Hiromichi Egami, Takuya Oguma, Tsutomu Katsuki.
Abstract
A few Fe-salan dimer complexes serve as catalysts for aerobic oxidative coupling (AOC) of 2-naphthols, but some others do not. X-Ray and cyclic voltammetry studies of various Fe-salan complexes revealed that the absence or the presence of double hydrogen bonding in Fe-salan dimers, the oxidation potential of monomeric Fe-salan species and the location of the resulting radical cation are critical factors for the catalytic activity of iron-salan complexes for the AOC.Entities:
Year: 2012 PMID: 22344391 DOI: 10.1039/c2cc18090a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222