Literature DB >> 22335795

Metal-free aromatic hydrogenation: aniline to cyclohexyl-amine derivatives.

Tayseer Mahdi1, Zachariah M Heiden, Stefan Grimme, Douglas W Stephan.   

Abstract

Hydrogenation of the N-bound phenyl rings of amines, imines, and aziridine is achieved in the presence of H(2) and B(C(6)F(5))(3), affording the corresponding N-cyclohexylammonium hydridoborate salts.
© 2012 American Chemical Society

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Year:  2012        PMID: 22335795     DOI: 10.1021/ja300228a

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  5 in total

1.  A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes.

Authors:  Konstantin Chernichenko; Adám Madarász; Imre Pápai; Martin Nieger; Markku Leskelä; Timo Repo
Journal:  Nat Chem       Date:  2013-07-07       Impact factor: 24.427

2.  Metal-free hydrogenation catalyzed by an air-stable borane: use of solvent as a frustrated Lewis base.

Authors:  Daniel J Scott; Matthew J Fuchter; Andrew E Ashley
Journal:  Angew Chem Int Ed Engl       Date:  2014-08-11       Impact factor: 15.336

3.  Microwave-activated Ni/carbon catalysts for highly selective hydrogenation of nitrobenzene to cyclohexylamine.

Authors:  Xinhuan Lu; Jie He; Run Jing; Peipei Tao; Renfeng Nie; Dan Zhou; Qinghua Xia
Journal:  Sci Rep       Date:  2017-06-01       Impact factor: 4.379

4.  Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.

Authors:  Gabriella Skara; Freija De Vleeschouwer; Paul Geerlings; Frank De Proft; Balazs Pinter
Journal:  Sci Rep       Date:  2017-11-22       Impact factor: 4.379

5.  A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis.

Authors:  Jeffrey M Farrell; Roy T Posaratnanathan; Douglas W Stephan
Journal:  Chem Sci       Date:  2015-01-26       Impact factor: 9.825

  5 in total

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