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Literature DB >> 22319022

From esters to alcohols and back with ruthenium and osmium catalysts.

Denis Spasyuk¹, Samantha Smith, Dmitry G Gusev.

Abstract

There and back again: hydrogenation of esters and the reverse reaction of dehydrogenative coupling of alcohols are efficiently catalyzed by dimeric complexes of Ru and Os under neutral conditions. The Os dimer is an outstanding catalyst for the hydrogenation of alkenoates and triglycerides, and allows production of fatty alcohols from olive oil. This complex converts ethanol into ethyl acetate and hydrogen under reflux.

Entities: Chemical Species

Year: 2012 PMID： 22319022 DOI： 10.1002/anie.201108956

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

11 in total

1. Catalytic acceptorless dehydrogenations: Ru-Macho catalyzed construction of amides and imines.

Authors: Nathan J Oldenhuis; Vy M Dong; Zhibin Guan
Journal: Tetrahedron Date: 2014-07-08 Impact factor: 2.457

2. Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide.

Authors: Martin Nielsen; Elisabetta Alberico; Wolfgang Baumann; Hans-Joachim Drexler; Henrik Junge; Serafino Gladiali; Matthias Beller
Journal: Nature Date: 2013-02-27 Impact factor: 49.962

3. CH₂ Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

Authors: Xiaolong Fang; Mingjun Sun; Jianwei Zheng; Bin Li; Linmin Ye; Xiaoping Wang; Zexing Cao; Hongping Zhu; Youzhu Yuan
Journal: Sci Rep Date: 2017-06-21 Impact factor: 4.379

4. Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters.

Authors: Robbert van Putten; Evgeny A Uslamin; Marcel Garbe; Chong Liu; Angela Gonzalez-de-Castro; Martin Lutz; Kathrin Junge; Emiel J M Hensen; Matthias Beller; Laurent Lefort; Evgeny A Pidko
Journal: Angew Chem Int Ed Engl Date: 2017-04-21 Impact factor: 15.336

5. Iridium-catalyzed asymmetric hydrogenation of racemic α-substituted lactones to chiral diols.

Authors: Xiao-Hui Yang; Hai-Tao Yue; Na Yu; Yi-Pan Li; Jian-Hua Xie; Qi-Lin Zhou
Journal: Chem Sci Date: 2016-11-15 Impact factor: 9.825

6. Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex.

Authors: Veronica Papa; Jose R Cabrero-Antonino; Elisabetta Alberico; Anke Spanneberg; Kathrin Junge; Henrik Junge; Matthias Beller
Journal: Chem Sci Date: 2017-03-08 Impact factor: 9.825

From esters to alcohols and back with ruthenium and osmium catalysts.

1. Catalytic acceptorless dehydrogenations: Ru-Macho catalyzed construction of amides and imines.

2. Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide.

3. CH₂ Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

4. Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters.

5. Iridium-catalyzed asymmetric hydrogenation of racemic α-substituted lactones to chiral diols.

6. Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex.

7. Chemoselective dehydrogenative esterification of aldehydes and alcohols with a dimeric rhodium(ii) catalyst.

8. Storing redox equivalent in the phenalenyl backbone towards catalytic multi-electron reduction.

Review 9. Ester Hydrogenation with Bifunctional Metal-NHC Catalysts: Recent Advances.

10. From racemic alcohols to enantiopure amines: Ru-catalyzed diastereoselective amination.