Literature DB >> 22311614

Extrusion of CO from aryl ketones: rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group.

Zhi-Quan Lei1, Hu Li, Yang Li, Xi-Sha Zhang, Kang Chen, Xin Wang, Jian Sun, Zhang-Jie Shi.   

Abstract

Snipping tool: the rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields. A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 22311614     DOI： 10.1002/anie.201107136

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  13 in total

1.  Rh-Catalyzed decarbonylative coupling with alkynes via C-C activation of isatins.

Authors:  Rong Zeng; Guangbin Dong
Journal:  J Am Chem Soc       Date:  2015-01-15       Impact factor: 15.419

2.  Rhodium(I)-catalyzed decarbonylative spirocyclization through C-C bond cleavage of benzocyclobutenones: an efficient approach to functionalized spirocycles.

Authors:  Tao Xu; Nikolas A Savage; Guangbin Dong
Journal:  Angew Chem Int Ed Engl       Date:  2014-01-20       Impact factor: 15.336

3.  Efficient Benzimidazolidinone Synthesis via Rhodium-Catalyzed Double-Decarbonylative C-C Activation/Cycloaddition between Isatins and Isocyanates.

Authors:  Rong Zeng; Peng-Hao Chen; Guangbin Dong
Journal:  ACS Catal       Date:  2015-12-30       Impact factor: 13.084

4.  Computational Study of Rh-Catalyzed Carboacylation of Olefins: Ligand-Promoted Rhodacycle Isomerization Enables Regioselective C-C Bond Functionalization of Benzocyclobutenones.

Authors:  Gang Lu; Cheng Fang; Tao Xu; Guangbin Dong; Peng Liu
Journal:  J Am Chem Soc       Date:  2015-06-19       Impact factor: 15.419

5.  Ruthenium-Catalyzed Reductive Cleavage of Unstrained Aryl-Aryl Bonds: Reaction Development and Mechanistic Study.

Authors:  Jun Zhu; Peng-Hao Chen; Gang Lu; Peng Liu; Guangbin Dong
Journal:  J Am Chem Soc       Date:  2019-11-12       Impact factor: 15.419

6.  Direct activation of relatively unstrained carbon-carbon bonds in homogeneous systems.

Authors:  Alpay Dermenci; Jotham W Coe; Guangbin Dong
Journal:  Org Chem Front       Date:  2014-03-27       Impact factor: 5.281

7.  Synthesis and applications of rhodacyclopentanones derived from C-C bond activation.

Authors:  Megan H Shaw; John F Bower
Journal:  Chem Commun (Camb)       Date:  2016-07-07       Impact factor: 6.222

8.  Light-driven transition-metal-free direct decarbonylation of unstrained diaryl ketones via a dual C-C bond cleavage.

Authors:  Dawei Cao; Mohamad Ataya; Zhangpei Chen; Huiying Zeng; Yong Peng; Rustam Z Khaliullin; Chao-Jun Li
Journal:  Nat Commun       Date:  2022-04-04       Impact factor: 14.919

9.  C-Cl Oxidative Addition and C-C Reductive Elimination Reactions in the Context of the Rhodium-Promoted Direct Arylation.

Authors:  Laura A de Las Heras; Miguel A Esteruelas; Montserrat Oliván; Enrique Oñate
Journal:  Organometallics       Date:  2022-03-17       Impact factor: 3.876

10.  Cobalt-catalyzed intramolecular decarbonylative coupling of acylindoles and diarylketones through the cleavage of C-C bonds.

Authors:  Tian-Yang Yu; Wen-Hua Xu; Hong Lu; Hao Wei
Journal:  Chem Sci       Date:  2020-10-16       Impact factor: 9.825
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