| Literature DB >> 22307580 |
M Angeles García-Monforte1, Pablo J Alonso, Irene Ara, Babil Menjón, Pilar Romero.
Abstract
Eliminating restraints: a trigonal-bipyramidal structure has been found to be the energetically favored geometry of the hypervalent AX(5) molecule Sb(C(6)F(5))(5) in the solid state and also in fluid solution, where molecules move freely and no crystal packing effects operate.Entities:
Year: 2012 PMID： 22307580 DOI： 10.1002/anie.201108858
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336