Literature DB >> 22304103

Stripe and line textures in the B2 phase of bent-shape molecules in samples with polar surface anchoring.

Lubor Lejček1, Vladimíra Novotná, Milada Glogarová.   

Abstract

In the B2 phase formed by bent-shaped molecules a dense line texture is frequently observed. For the texture description a model is proposed consisting of a periodic system of anticlinic antiferroelectric bulk domains with opposite chiralities separated by π walls in which polarization rotates. The bulk domains are situated between layers of synclinic ferroelectric phase near the upper and lower surfaces. In the surface layers induced by polar anchoring domains of opposite chirality are separated by defect lines. Under the electric field the ferroelectric layer near one sample surface is growing against the antiferroelectric structure in the sample bulk and the stripe texture is fading out, but still in the saturated field surface lines or walls persist separating ferroelectric domains of opposite chirality. The proposed model is adapted also for a case when the anticlinic antiferroelectric structure in the sample bulk is sandwiched between anticlinic ferroelectric layers near the surfaces. In that case the applied electric field eliminates all the lines because the resulting anticlinic ferroelectric structure is racemic, with no chiral domains.

Year:  2011        PMID: 22304103     DOI: 10.1103/PhysRevE.84.061701

Source DB:  PubMed          Journal:  Phys Rev E Stat Nonlin Soft Matter Phys        ISSN: 1539-3755


  1 in total

1.  Unusual polymorphism in new bent-shaped liquid crystals based on biphenyl as a central molecular core.

Authors:  Anna Kovářová; Svatopluk Světlík; Václav Kozmík; Jiří Svoboda; Vladimíra Novotná; Damian Pociecha; Ewa Gorecka; Natalia Podoliak
Journal:  Beilstein J Org Chem       Date:  2014-04-07       Impact factor: 2.883

  1 in total

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