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Literature DB >> 22296290

Effect of water during the quantitation of formate in photocatalytic studies on CO2 reduction in dimethylformamide.

Avishek Paul¹, Damian Connolly, Martin Schulz, Mary T Pryce, Johannes G Vos.

Abstract

The effect of the water concentration on the quantitation of formate from dimethylformamide in the presence of electron-donating bases using ion chromatography is reported. This observation has important implications in the area of the photocatalytic reduction of CO(2), where formate levels are often used to calculate catalyst turnover numbers.

Entities: Chemical

Year: 2012 PMID： 22296290 DOI： 10.1021/ic202121s

Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165

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Cited

6 in total

1. Unexpected effect of catalyst concentration on photochemical CO₂ reduction by trans(Cl)-Ru(bpy)(CO)₂Cl₂: new mechanistic insight into the CO/HCOO^- selectivity.

Authors: Yusuke Kuramochi; Jun Itabashi; Kyohei Fukaya; Akito Enomoto; Makoto Yoshida; Hitoshi Ishida
Journal: Chem Sci Date: 2015-03-12 Impact factor: 9.825

6. A Heterometallic Three-Dimensional Metal-Organic Framework Bearing an Unprecedented One-Dimensional Branched-Chain Secondary Building Unit.

Authors: Jing Chen; Meng-Yao Chao; Yan Liu; Bo-Wei Xu; Wen-Hua Zhang; David J Young
Journal: Molecules Date: 2020-05-07 Impact factor: 4.411

6 in total

Effect of water during the quantitation of formate in photocatalytic studies on CO2 reduction in dimethylformamide.

1. Unexpected effect of catalyst concentration on photochemical CO₂ reduction by trans(Cl)-Ru(bpy)(CO)₂Cl₂: new mechanistic insight into the CO/HCOO^- selectivity.

Review 2. The Coordination Chemistry of Bio-Relevant Ligands and Their Magnesium Complexes.

3. CO₂ capture by Mn(i) and Re(i) complexes with a deprotonated triethanolamine ligand.

4. High-efficiency photocatalytic CO₂ reduction in organic-aqueous system: a new insight into the role of water.

5. Highly efficient, selective, and durable photocatalytic system for CO₂ reduction to formic acid.

6. A Heterometallic Three-Dimensional Metal-Organic Framework Bearing an Unprecedented One-Dimensional Branched-Chain Secondary Building Unit.

Effect of water during the quantitation of formate in photocatalytic studies on CO2 reduction in dimethylformamide.

1. Unexpected effect of catalyst concentration on photochemical CO2 reduction by trans(Cl)-Ru(bpy)(CO)2Cl2: new mechanistic insight into the CO/HCOO- selectivity.

Review 2. The Coordination Chemistry of Bio-Relevant Ligands and Their Magnesium Complexes.

3. CO2 capture by Mn(i) and Re(i) complexes with a deprotonated triethanolamine ligand.

4. High-efficiency photocatalytic CO2 reduction in organic-aqueous system: a new insight into the role of water.

5. Highly efficient, selective, and durable photocatalytic system for CO2 reduction to formic acid.

6. A Heterometallic Three-Dimensional Metal-Organic Framework Bearing an Unprecedented One-Dimensional Branched-Chain Secondary Building Unit.

1. Unexpected effect of catalyst concentration on photochemical CO₂ reduction by trans(Cl)-Ru(bpy)(CO)₂Cl₂: new mechanistic insight into the CO/HCOO^- selectivity.

3. CO₂ capture by Mn(i) and Re(i) complexes with a deprotonated triethanolamine ligand.

4. High-efficiency photocatalytic CO₂ reduction in organic-aqueous system: a new insight into the role of water.

5. Highly efficient, selective, and durable photocatalytic system for CO₂ reduction to formic acid.