Literature DB >> 22296173

Recycling of carbon and silicon wastes: room temperature formylation of N-H bonds using carbon dioxide and polymethylhydrosiloxane.

Olivier Jacquet1, Christophe Das Neves Gomes, Michel Ephritikhine, Thibault Cantat.   

Abstract

A highly active organocatalytic system based on N-heterocyclic carbenes has been designed for the formylation of N-H bonds in a large variety of nitrogen molecules and heterocycles, using two chemical wastes: CO(2) and polymethylhydrosiloxane (PMHS).

Entities:  

Year:  2012        PMID： 22296173     DOI： 10.1021/ja211527q

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  11 in total

1.  N-formylation and N-methylation of amines using metal-free N-heterocyclic carbene catalysts and CO2 as carbon source.

Authors:  Felix D Bobbink; Shoubhik Das; Paul J Dyson
Journal:  Nat Protoc       Date:  2017-01-26       Impact factor: 13.491

2.  Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides.

Authors:  Tongtong Wang; Maotong Xu; Andrew R Jupp; Zheng-Wang Qu; Stefan Grimme; Douglas W Stephan
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-03       Impact factor: 16.823

3.  A Porous Metal-Organic Framework Assembled by [Cu30] Nanocages: Serving as Recyclable Catalysts for CO2 Fixation with Aziridines.

Authors:  Hang Xu; Xiao-Fang Liu; Chun-Shuai Cao; Bin Zhao; Peng Cheng; Liang-Nian He
Journal:  Adv Sci (Weinh)       Date:  2016-05-17       Impact factor: 16.806

4.  Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO2, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Authors:  Yu Lu; Zhong-Hua Gao; Xiang-Yu Chen; Jiandong Guo; Zheyuan Liu; Yanfeng Dang; Song Ye; Zhi-Xiang Wang
Journal:  Chem Sci       Date:  2017-09-11       Impact factor: 9.825

5.  Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO2 Using a Molecular Cobalt(II) Triazine Complex.

Authors:  Hanna H Cramer; Basujit Chatterjee; Thomas Weyhermüller; Christophe Werlé; Walter Leitner
Journal:  Angew Chem Int Ed Engl       Date:  2020-06-02       Impact factor: 15.336

Review 6.  Toward ideal carbon dioxide functionalization.

Authors:  Yang Yang; Ji-Woong Lee
Journal:  Chem Sci       Date:  2019-02-20       Impact factor: 9.825

Review 7.  From CO2 activation to catalytic reduction: a metal-free approach.

Authors:  Sreejyothi P; Swadhin K Mandal
Journal:  Chem Sci       Date:  2020-08-20       Impact factor: 9.825

8.  Fully-automated radiosynthesis of the amyloid tracer [11C] PiB via direct [11C]CO2 fixation-reduction.

Authors:  Pablo Buccino; Eduardo Savio; Williams Porcal
Journal:  EJNMMI Radiopharm Chem       Date:  2019-07-16

9.  Selective synthesis of formamides, 1,2-bis(N-heterocyclic)ethanes and methylamines from cyclic amines and CO2/H2 catalyzed by an ionic liquid-Pd/C system.

Authors:  Ruipeng Li; Yanfei Zhao; Huan Wang; Junfeng Xiang; Yunyan Wu; Bo Yu; Buxing Han; Zhimin Liu
Journal:  Chem Sci       Date:  2019-09-03       Impact factor: 9.825

10.  Catalytic CO2 Reduction with Boron- and Aluminum Hydrides.

Authors:  Daniel Franz; Christian Jandl; Claire Stark; Shigeyoshi Inoue
Journal:  ChemCatChem       Date:  2019-09-30       Impact factor: 5.686
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