Literature DB >> 22293977

Fluorogenic sensing of CH3CO2- and H2PO4- by ditopic receptor through conformational change.

Nisar Ahmed1, Vangaru Suresh, Bahareh Shirinfar, Inacrist Geronimo, Amita Bist, In-Chul Hwang, Kwang S Kim.   

Abstract

Cyclo-bis-(urea-3,6-dichlorocarbazole) (1) forms a 1 : 2 complex with CH(3)CO(2)(-) and H(2)PO(4)(-) through hydrogen bonding with the two urea moieties, resulting in fluorescence enhancement via a combined photoinduced electron transfer (PET) and energy transfer mechanism. The binding mechanism involves a conformational change of the two urea receptors to a trans orientation after binding of the first anion, which facilitates the second interaction.

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Year:  2012        PMID: 22293977     DOI: 10.1039/c2ob06994f

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  2 in total

1.  NO3- anions can act as Lewis acid in the solid state.

Authors:  Antonio Bauzá; Antonio Frontera; Tiddo J Mooibroek
Journal:  Nat Commun       Date:  2017-02-21       Impact factor: 14.919

2.  Design, synthesis and application of carbazole macrocycles in anion sensors.

Authors:  Alo Rüütel; Ville Yrjänä; Sandip A Kadam; Indrek Saar; Mihkel Ilisson; Astrid Darnell; Kristjan Haav; Tõiv Haljasorg; Lauri Toom; Johan Bobacka; Ivo Leito
Journal:  Beilstein J Org Chem       Date:  2020-08-04       Impact factor: 2.883

  2 in total

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