Literature DB >> 22287117

Palladium-catalyzed oxidative arylating carbocyclization of allenynes.

Youqian Deng1, Teresa Bartholomeyzik, Andreas K Å Persson, Junliang Sun, Jan-E Bäckvall.   

Abstract

Vinylallenes or cross-conjugated trienes are obtained selectively in the title reaction. Two possible mechanisms are suggested to rationalize the formation of the different types of products. Control experiments indicate that p-benzoquinone (BQ) plays an important role as a ligand in addition to its role as an oxidant. E=CO(2)Me.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 22287117     DOI： 10.1002/anie.201107592

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  11 in total

1.  Palladium(II)-Catalyzed Tandem Oxidative Acetoxylation/ortho C-H Activation/Carbocyclization of Arylallenes.

Authors:  Javier Mazuela; Debasis Banerjee; Jan-E Bäckvall
Journal:  J Am Chem Soc       Date:  2015-07-28       Impact factor: 15.419

2.  Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Oxidative Arylation of Allenes.

Authors:  Can Zhu; Bin Yang; Tuo Jiang; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2015-06-16       Impact factor: 15.336

3.  Iron-catalyzed Cross-Coupling of Propargyl Carboxylates and Grignard Reagents: Synthesis of Substituted Allenes.

Authors:  Simon N Kessler; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2016-02-17       Impact factor: 15.336

4.  Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenes to Cyclobutenes.

Authors:  Youai Qiu; Bin Yang; Can Zhu; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-18       Impact factor: 15.336

5.  Palladium-Catalyzed Oxidative Domino Carbocyclization-Arylation of Bisallenes.

Authors:  Chandra M R Volla; Jan-E Bäckvall
Journal:  ACS Catal       Date:  2016-08-23       Impact factor: 13.084

6.  Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion.

Authors:  Youai Qiu; Bin Yang; Can Zhu; Jan-E Bäckvall
Journal:  Chem Sci       Date:  2016-09-15       Impact factor: 9.825

7.  Palladium-catalyzed oxidative acyloxylation/carbocyclization of allenynes.

Authors:  Youqian Deng; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2013-02-05       Impact factor: 15.336

8.  Control of selectivity in palladium-catalyzed oxidative carbocyclization/borylation of allenynes.

Authors:  Youqian Deng; Teresa Bartholomeyzik; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2013-05-17       Impact factor: 15.336

9.  Palladium-catalyzed oxidative regio- and diastereoselective diarylating carbocyclization of dienynes.

Authors:  Min Jiang; Jan-E Bäckvall
Journal:  Chemistry       Date:  2013-04-09       Impact factor: 5.236

10.  Synthesis of Cross-Conjugated Polyenes via Palladium-Catalyzed Oxidative C-C Bond Forming Cascade Reactions of Allenes.

Authors:  Veluru Ramesh Naidu; Jan-E Bäckvall
Journal:  J Org Chem       Date:  2020-04-02       Impact factor: 4.354
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