Modeling the viscosity and aggregation of suspensions of highly anisotropic nanoparticles.

The rheology of nanofiber suspensions is studied solving numerically the Population Balance Equations (PBE). To account for the anisotropic nature of nanofibers, a relation is proposed for their hydrodynamic volume. The suspension viscosity is calculated using the computed aggregate size distributions together with the Krieger-Dougherty constitutive equation. The model is fitted to experimental flow curves for Carbon NanoFibers (CNF) and for NanoFibrillated Cellulose (NFC), giving a first estimation of the microscopic anisotropy parameter, and yielding information on the structural properties and rheology of each system.