Literature DB >> 22266838

α,β-Unsaturated imines via Ru-catalyzed coupling of allylic alcohols and amines.

Jared W Rigoli1, Sara A Moyer, Simon D Pearce, Jennifer M Schomaker.   

Abstract

A convenient synthesis of α,β-unsaturated imines requiring only an allylic alcohol, an amine and a Ru catalyst has been developed. The use of large excesses of oxidant and the purification of sensitive intermediates can be avoided.

Entities:  

Mesh：

Substances：

Year:  2012        PMID： 22266838     DOI： 10.1039/c2ob06921k

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  4 in total

1.  Low temperature n-butyllithium-induced [3,3]-sigmatropic rearrangement/electrophile trapping reactions of allyl-1,1-dichlorovinyl ethers. Synthesis of β-, γ- and δ-lactones.

Authors:  Aaron Christopher; Dahniel Brandes; Stephen Kelly; Thomas G Minehan
Journal:  Org Biomol Chem       Date:  2013-10-10       Impact factor: 3.876

2.  Catalytic acceptorless dehydrogenations: Ru-Macho catalyzed construction of amides and imines.

Authors:  Nathan J Oldenhuis; Vy M Dong; Zhibin Guan
Journal:  Tetrahedron       Date:  2014-07-08       Impact factor: 2.457

3.  The key role of the latent N-H group in Milstein's catalyst for ester hydrogenation.

Authors:  John Pham; Cole E Jarczyk; Eamon F Reynolds; Sophie E Kelly; Thao Kim; Tianyi He; Jason M Keith; Anthony R Chianese
Journal:  Chem Sci       Date:  2021-05-24       Impact factor: 9.825

4.  From racemic alcohols to enantiopure amines: Ru-catalyzed diastereoselective amination.

Authors:  Nathan J Oldenhuis; Vy M Dong; Zhibin Guan
Journal:  J Am Chem Soc       Date:  2014-08-29       Impact factor: 15.419
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.