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Literature DB >> 22266606

Mirror symmetry breaking and chiral amplification in foldamer-based supramolecular helical aggregates.

Simon Azeroual¹, Jamie Surprenant, Thomas D Lazzara, Marta Kocun, Ye Tao, Louis A Cuccia, Jean-Marie Lehn.

Abstract

Spontaneous asymmetric generation of supramolecular chiral fibers was observed in the folding induced self-assembly of a lock-washer shaped foldamer. A secondary nucleation growth mechanism is proposed to explain the observed chiral amplification or deracemization of these supramolecular fibers. This journal is © The Royal Society of Chemistry 2012

Year: 2012 PMID： 22266606 DOI： 10.1039/c2cc16266k

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

5 in total

1. A supramolecular helix that disregards chirality.

Authors: Cécile Roche; Hao-Jan Sun; Pawaret Leowanawat; Fumito Araoka; Benjamin E Partridge; Mihai Peterca; Daniela A Wilson; Margaret E Prendergast; Paul A Heiney; Robert Graf; Hans W Spiess; Xiangbing Zeng; Goran Ungar; Virgil Percec
Journal: Nat Chem Date: 2015-11-16 Impact factor: 24.427

Mirror symmetry breaking and chiral amplification in foldamer-based supramolecular helical aggregates.

1. A supramolecular helix that disregards chirality.

Review 2. Transmission of chirality through space and across length scales.

Review 3. The Diverse World of Foldamers: Endless Possibilities of Self-Assembly.

4. Chiral Selectivity of Secondary Nucleation in Amyloid Fibril Propagation.

5. Solid Phase Deracemization of an Atropisomer.