Literature DB >> 22259347

trans-Bis(ethyl-enediamine-κN,N')bis-(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ,3-oxathia-zin-3-ido-κN)copper(II).

Necmi Dege, Güneş Demirtaş, Hasan Içbudak.   

Abstract

In the crystal structure of the title compound, [Cu(C(4)H(4)NO(4)S)(2)(C(2)H(8)N(2))(2)], the Cu(2+) ion resides on a centre of symmetry. The environment of Cu(2+) ion is a distorted octa-hedron. The axial bond lengths between the Cu(II) ion and the N atoms are considerably longer than the equatorial bond distances between the Cu(II) ion and the N atoms of the ethyl-enediamine ligand as a consequence of the Jahn-Teller effect. The mol-ecular conformation is stabilized by intra-molecular N-H⋯O hydrogen bonds. In the crystal, mol-ecules are connected by inter-molecular N-H⋯O hydrogen bonds into chains running along the a axis.

Entities:  

Year:  2011        PMID: 22259347      PMCID: PMC3254316          DOI: 10.1107/S1600536811051658

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  9 in total

1.  Structural properties of trans-cyclohexane-1,2-diamine complexes of copper(II) and zinc(II) acesulfamates.

Authors:  Zarife Sibel Şahin; Fatma Sevindi; Hasan İçbudak; Şamil Işık
Journal:  Acta Crystallogr C       Date:  2010-09-29       Impact factor: 1.172

2.  Polymorphism in acesulfame sweetener: structure-property and stability relationships of bending and brittle crystals.

Authors:  Sitaram P Velaga; Venu R Vangala; Srinivas Basavoju; Dan Boström
Journal:  Chem Commun (Camb)       Date:  2010-04-27       Impact factor: 6.222

3.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

Review 4.  Position of the American Dietetic Association: use of nutritive and nonnutritive sweeteners.

Authors:  V B Duffy; G H Anderson
Journal:  J Am Diet Assoc       Date:  1998-05

5.  Pt(II) and Ag(I) complexes with acesulfame: crystal structure and a study of their antitumoral, antimicrobial and antiviral activities.

Authors:  Maurício Cavicchioli; Antonio C Massabni; Tassiele A Heinrich; Claudio M Costa-Neto; Emiliana P Abrão; Benedito A L Fonseca; Eduardo E Castellano; Pedro P Corbi; Wilton R Lustri; Clarice Q F Leite
Journal:  J Inorg Biochem       Date:  2010-01-18       Impact factor: 4.155

6.  Bis(acesulfamato-kappa2N3,O4)bis(2-aminopyrimidine-kappaN1)copper(II).

Authors:  Ahmet Bulut; Hasan Içbudak; Gözde Sezer; Canan Kazak
Journal:  Acta Crystallogr C       Date:  2005-04-23       Impact factor: 1.172

7.  Bis(acesulfamato)tetraaquacobalt(II).

Authors:  Hasan Içbudak; Ahmet Bulut; Naziye Cetin; Canan Kazak
Journal:  Acta Crystallogr C       Date:  2004-12-11       Impact factor: 1.172

8.  Di-mu-acesulfamato-kappa3N,O:O;kappa3O:N,O-bis[(acesulfamato-kappa2N,O)bis(3-methylpyridine)cadmium(II)].

Authors:  Zarife Sibel Sahin; Hasan Içbudak; Samil Işik
Journal:  Acta Crystallogr C       Date:  2009-11-07       Impact factor: 1.172

9.  Structure validation in chemical crystallography.

Authors:  Anthony L Spek
Journal:  Acta Crystallogr D Biol Crystallogr       Date:  2009-01-20
  9 in total

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