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Literature DB >> 22245936

Generation of (nonafluoro-tert-butoxy)methyl ponytails for enhanced fluorous partition of aromatics and heterocycles.

Xi Zhao¹, Wing Yan Ng, Kai-Chung Lau, Alana E C Collis, István T Horváth.

Abstract

The reaction of sodium perfluoro-tert-butoxide with benzylic carbon-bromide bond(s) leads to the formation of (nonafluoro-tert-butoxy)methyl ponytail(s), which can enhance the fluorous solubility and partition of aromatics and heterocycles.

Entities: Chemical

Year: 2012 PMID： 22245936 DOI： 10.1039/c2cp23113a

Source DB: PubMed Journal: Phys Chem Chem Phys ISSN： 1463-9076 Impact factor: 3.676

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Cited

3 in total

Review 1. New frontiers and developing applications in 19F NMR.

Authors: Jian-Xin Yu; Rami R Hallac; Srinivas Chiguru; Ralph P Mason
Journal: Prog Nucl Magn Reson Spectrosc Date: 2012-11-02 Impact factor: 9.795

2. A General Approach to Biocompatible Branched Fluorous Tags for Increased Solubility in Perfluorocarbon Solvents.

Authors: Margeaux A Miller; Ellen M Sletten
Journal: Org Lett Date: 2018-10-24 Impact factor: 6.005

Review 3. Perfluorocarbons in Chemical Biology.

Authors: Margeaux A Miller; Ellen M Sletten
Journal: Chembiochem Date: 2020-08-05 Impact factor: 3.164

3 in total