Literature DB >> 22243318

Preparation and relaxation of very stable glassy states of a simulated liquid.

Robert L Jack1, Lester O Hedges, Juan P Garrahan, David Chandler.   

Abstract

We prepare metastable glassy states in a model glass former made of Lennard-Jones particles by sampling biased ensembles of trajectories with low dynamical activity. These trajectories form an inactive dynamical phase whose "fast" vibrational degrees of freedom are maintained at thermal equilibrium by contact with a heat bath, while the "slow" structural degrees of freedom are located in deep valleys of the energy landscape. We examine the relaxation to equilibrium and the vibrational properties of these metastable states. The glassy states we prepare by our trajectory sampling method are very stable to thermal fluctuations and also more mechanically rigid than low-temperature equilibrated configurations.

Year:  2011        PMID: 22243318     DOI: 10.1103/PhysRevLett.107.275702

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  7 in total

1.  Supercooled liquids with enhanced orientational order.

Authors:  Simona Capponi; Simone Napolitano; Michael Wübbenhorst
Journal:  Nat Commun       Date:  2012       Impact factor: 14.919

2.  Ultrastable glasses from in silico vapour deposition.

Authors:  Sadanand Singh; M D Ediger; Juan J de Pablo
Journal:  Nat Mater       Date:  2013-01-06       Impact factor: 43.841

3.  Frozen in beta.

Authors:  Rohit V Pappu
Journal:  Biophys J       Date:  2014-08-19       Impact factor: 4.033

4.  Dynamical phase transitions reveal amyloid-like states on protein folding landscapes.

Authors:  Jeffrey K Weber; Robert L Jack; Christian R Schwantes; Vijay S Pande
Journal:  Biophys J       Date:  2014-08-19       Impact factor: 4.033

5.  Theory of amorphous ices.

Authors:  David T Limmer; David Chandler
Journal:  Proc Natl Acad Sci U S A       Date:  2014-05-23       Impact factor: 11.205

6.  Dynamic phase transitions in freestanding polymer thin films.

Authors:  Robert J S Ivancic; Robert A Riggleman
Journal:  Proc Natl Acad Sci U S A       Date:  2020-10-02       Impact factor: 11.205

7.  Structural-dynamical transition in the Wahnström mixture.

Authors:  Francesco Turci; Thomas Speck; C Patrick Royall
Journal:  Eur Phys J E Soft Matter       Date:  2018-04-26       Impact factor: 1.890

  7 in total

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