Literature DB >> 22235803

Isotropic high field NMR spectra of Li-ion battery materials with anisotropy >1 MHz.

Ivan Hung1, Lina Zhou, Frédérique Pourpoint, Clare P Grey, Zhehong Gan.   

Abstract

The use of a magic-angle turning and phase-adjusted spinning sideband NMR experiment to resolve and quantify the individual local environments in the high field (7)Li and (31)P NMR spectra of paramagnetic lithium-ion battery materials is demonstrated. The use of short radio frequency pulses provides an excitation bandwidth that is sufficient to cover shift anisotropy of >1 MHz in breadth, allowing isotropic and anisotropic components to be resolved.
© 2012 American Chemical Society

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Year:  2012        PMID: 22235803     DOI: 10.1021/ja209600m

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  5 in total

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Authors:  Fiona C Strobridge; Raphaële J Clément; Michal Leskes; Derek S Middlemiss; Olaf J Borkiewicz; Kamila M Wiaderek; Karena W Chapman; Peter J Chupas; Clare P Grey
Journal:  Chem Mater       Date:  2014-10-09       Impact factor: 9.811

2.  Probing Oxide-Ion Mobility in the Mixed Ionic-Electronic Conductor La2NiO4+δ by Solid-State (17)O MAS NMR Spectroscopy.

Authors:  David M Halat; Rıza Dervişoğlu; Gunwoo Kim; Matthew T Dunstan; Frédéric Blanc; Derek S Middlemiss; Clare P Grey
Journal:  J Am Chem Soc       Date:  2016-09-02       Impact factor: 15.419

3.  Mitigating oxygen loss to improve the cycling performance of high capacity cation-disordered cathode materials.

Authors:  Jinhyuk Lee; Joseph K Papp; Raphaële J Clément; Shawn Sallis; Deok-Hwang Kwon; Tan Shi; Wanli Yang; Bryan D McCloskey; Gerbrand Ceder
Journal:  Nat Commun       Date:  2017-10-17       Impact factor: 14.919

4.  Sequential delithiation behavior and structural rearrangement of a nanoscale composite-structured Li1.2Ni0.2Mn0.6O2 during charge-discharge cycles.

Authors:  Keiji Shimoda; Koji Yazawa; Toshiyuki Matsunaga; Miwa Murakami; Keisuke Yamanaka; Toshiaki Ohta; Eiichiro Matsubara; Zempachi Ogumi; Takeshi Abe
Journal:  Sci Rep       Date:  2020-06-22       Impact factor: 4.379

5.  Structural Origins of Voltage Hysteresis in the Na-Ion Cathode P2-Na0.67[Mg0.28Mn0.72]O2: A Combined Spectroscopic and Density Functional Theory Study.

Authors:  Euan N Bassey; Philip J Reeves; Michael A Jones; Jeongjae Lee; Ieuan D Seymour; Giannantonio Cibin; Clare P Grey
Journal:  Chem Mater       Date:  2021-06-21       Impact factor: 9.811

  5 in total

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