Literature DB >> 22220096

4-(2-Chloro-anilino)-3-phenyl-furan-2(5H)-one.

Zhu-Ping Xiao1, Ze-Jun Huang, Xiao-Yang Liu, Kai-Shuang Xiang, She-Rong Yu.   

Abstract

The title compound, C(16)H(12)ClNO(2), featuring a furan-2(5H)-one (γ-butyrolactone) core, contains two mol-ecules (A and B) in the asymmetric unit, with different dihedral angles between the central ring and the pendant phenyl and chloro-benzene rings [43.33 (8) and 20.16 (8)°, respectively, for A, and 47.79 (8) and 13.87 (8)°, respectively, for B]. In the crystal, the A mol-ecules are linked into [001] chains by single C-H⋯O inter-actions. The B mol-ecules also form [001] chains, but their relative orientations in the chains are quite different to those of the A mol-ecules so that adjacent B mol-ecules are linked by two C-H⋯O hydrogen bonds. Finally, C-H⋯O inter-actions and aromatic π-π stacking contacts [centroid-centroid separations = 3.754 (1) and 3.817 (1) Å] link the chains into a two-dimensional array parallel to (010).

Entities:  

Year:  2011        PMID: 22220096      PMCID: PMC3247478          DOI: 10.1107/S1600536811044308

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  2 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  3-(4-Bromo-phen-yl)-4-[2-(4-nitro-phen-yl)hydrazin-yl]furan-2(5H)-one.

Authors:  Zhu-Ping Xiao; Li-Cheng Yi; Jia-Liang Li; Bo Zhang; Mei-Ling Liao
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-10-29
  2 in total

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