(2,4-Difluoro-phen-yl)[1-(1H-1,2,4-triazol-1-yl)cyclo-prop-yl]methanone.

The asymmetric unit of the title compound, C(12)H(9)F(2)N(3)O, contains two independent mol-ecules (A and B) in which the benzene and cyclo-propane rings form dihedral angles of 33.0 (1) and 29.7 (1)°, respectively. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link alternating A and B mol-ecules into chains along [010].

Related literature

For applications of triazole derivatives, see: Che & Zhang (2009 ▶); Lieven & Leo (2005 ▶). For related structures, see: Tarun et al. (1998 ▶).

Experimental

Crystal data

C12H9F2N3O

M = 249.22

Triclinic,

a = 9.6067 (11) Å

b = 11.4840 (13) Å

c = 11.9127 (14) Å

α = 73.652 (1)°

β = 84.202 (2)°

γ = 69.260 (1)°

V = 1179.4 (2) Å3

Z = 4

Mo Kα radiation

μ = 0.12 mm−1

T = 298 K

0.49 × 0.40 × 0.38 mm

Data collection

Rigaku R-AXIS CCD detector diffractometer

Absorption correction: multi-scan (ABSCOR; Higashi, 1995 ▶) T min = 0.983, T max = 0.986

5900 measured reflections

4080 independent reflections

2816 reflections with I > 2σ(I)

R int = 0.017

Refinement

R[F 2 > 2σ(F 2)] = 0.038

wR(F 2) = 0.111

S = 1.02

4080 reflections

326 parameters

H-atom parameters constrained

Δρmax = 0.14 e Å−3

Δρmin = −0.16 e Å−3

Data collection: R-AXIS II Software (Rigaku, 1997 ▶); cell refinement: R-AXIS II Software; data reduction: R-AXIS II Software; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: TEXSAN (Molecular Structure Corporation, 1992 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536811040037/cv5156sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811040037/cv5156Isup2.hkl

Supplementary material file. DOI: 10.1107/S1600536811040037/cv5156Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C12H9F2N3O	F(000) = 512
Mr = 249.22	Dx = 1.404 Mg m−3
Triclinic, P1	Melting point: 362.15 K
a = 9.6067 (11) Å	Mo Kα radiation, λ = 0.71073 Å
b = 11.4840 (13) Å	Cell parameters from 2449 reflections
c = 11.9127 (14) Å	θ = 4.9–52.5°
α = 73.652 (1)°	µ = 0.12 mm−1
β = 84.202 (2)°	T = 298 K
γ = 69.260 (1)°	Block, colourless
V = 1179.4 (2) Å3	0.49 × 0.40 × 0.38 mm
Z = 4

Rigaku R-AXIS CCD detector diffractometer	4080 independent reflections
Radiation source: fine-focus sealed tube	2816 reflections with I > 2σ(I)
graphite	Rint = 0.017
φ and ω scans	θmax = 25.0°, θmin = 2.4°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −10→11
Tmin = 0.983, Tmax = 0.986	k = −13→12
5900 measured reflections	l = −13→14

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.038	H-atom parameters constrained
wR(F2) = 0.111	w = 1/[σ2(Fo2) + (0.0469P)2 + 0.2296P] where P = (Fo2 + 2Fc2)/3
S = 1.02	(Δ/σ)max < 0.001
4080 reflections	Δρmax = 0.14 e Å−3
326 parameters	Δρmin = −0.16 e Å−3
0 restraints	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.0200 (19)

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
F1	1.40947 (15)	0.64219 (16)	0.00685 (15)	0.1017 (5)
F2	0.96387 (13)	0.81942 (11)	0.18986 (12)	0.0717 (4)
F3	0.93617 (18)	0.62666 (18)	0.51796 (17)	0.1195 (6)
F4	0.49568 (16)	0.58407 (11)	0.69708 (13)	0.0857 (4)
C1	1.2783 (2)	0.6334 (2)	0.0552 (2)	0.0647 (6)
C2	1.2443 (2)	0.5265 (2)	0.0588 (2)	0.0668 (6)
H2A	1.3102	0.4597	0.0302	0.080*
C3	1.1099 (2)	0.52091 (19)	0.10591 (18)	0.0584 (5)
H3A	1.0851	0.4485	0.1102	0.070*
C4	1.0094 (2)	0.62149 (17)	0.14757 (16)	0.0478 (5)
C5	1.0544 (2)	0.72398 (18)	0.14347 (17)	0.0512 (5)
C6	1.1876 (2)	0.7330 (2)	0.09827 (18)	0.0591 (6)
H6A	1.2151	0.8033	0.0969	0.071*
C7	0.8640 (2)	0.61067 (19)	0.19488 (18)	0.0556 (5)
C8	0.7238 (2)	0.72473 (17)	0.16397 (16)	0.0463 (5)
C9	0.5788 (2)	0.7042 (2)	0.1994 (2)	0.0678 (6)
H9A	0.4949	0.7541	0.1470	0.081*
H9B	0.5817	0.6175	0.2403	0.081*
C10	0.6327 (3)	0.7735 (2)	0.26206 (19)	0.0700 (6)
H10A	0.6689	0.7291	0.3413	0.084*
H10B	0.5820	0.8658	0.2480	0.084*
N2	0.7482 (2)	0.78048 (16)	−0.04611 (14)	0.0591 (5)
N3	0.7144 (2)	0.99200 (16)	−0.08345 (15)	0.0647 (5)
C13	0.8010 (3)	0.6783 (3)	0.5629 (2)	0.0762 (7)
C14	0.7534 (3)	0.8061 (2)	0.5600 (2)	0.0788 (7)
H14A	0.8135	0.8558	0.5296	0.095*
C15	0.6152 (3)	0.8589 (2)	0.6032 (2)	0.0691 (7)
H15A	0.5821	0.9455	0.6030	0.083*
C16	0.5225 (2)	0.78710 (18)	0.64746 (18)	0.0573 (6)
C17	0.5794 (3)	0.65813 (19)	0.64870 (19)	0.0604 (6)
C18	0.7182 (3)	0.6007 (2)	0.6075 (2)	0.0690 (6)
H18A	0.7540	0.5134	0.6100	0.083*
C19	0.3729 (3)	0.8500 (2)	0.69230 (19)	0.0678 (6)
C20	0.2382 (2)	0.83360 (19)	0.65607 (17)	0.0582 (5)
C21	0.1380 (3)	0.7875 (3)	0.7494 (2)	0.0928 (9)
H21A	0.0900	0.7320	0.7342	0.111*
H21B	0.1660	0.7684	0.8303	0.111*
C22	0.0889 (3)	0.9228 (3)	0.6814 (2)	0.0884 (8)
H22A	0.0864	0.9871	0.7204	0.106*
H22B	0.0105	0.9507	0.6244	0.106*
N6	0.2577 (2)	0.69776 (17)	0.41577 (15)	0.0633 (5)
N5	0.26550 (18)	0.87964 (14)	0.44550 (14)	0.0533 (4)
C12	0.7074 (2)	0.94269 (18)	0.02927 (17)	0.0536 (5)
H12A	0.6907	0.9894	0.0846	0.064*
C11	0.7406 (3)	0.8883 (2)	−0.12474 (18)	0.0662 (6)
H11A	0.7525	0.8930	−0.2042	0.079*
N1	0.72688 (16)	0.81780 (13)	0.05495 (12)	0.0423 (4)
N4	0.25081 (17)	0.79612 (14)	0.54907 (13)	0.0464 (4)
C24	0.2467 (2)	0.68990 (19)	0.52741 (19)	0.0588 (5)
H24A	0.2371	0.6190	0.5847	0.071*
C23	0.2694 (2)	0.81488 (19)	0.37037 (18)	0.0542 (5)
H23A	0.2797	0.8479	0.2904	0.065*
O1	0.85746 (19)	0.50900 (16)	0.25590 (17)	0.0984 (6)
O2	0.3590 (2)	0.9191 (2)	0.75643 (18)	0.1132 (7)

	U11	U22	U33	U12	U13	U23
F1	0.0625 (9)	0.1236 (13)	0.1359 (14)	−0.0376 (9)	0.0205 (9)	−0.0597 (11)
F2	0.0660 (8)	0.0637 (8)	0.0980 (10)	−0.0180 (6)	−0.0012 (7)	−0.0458 (7)
F3	0.0818 (12)	0.1246 (14)	0.1586 (17)	−0.0256 (10)	−0.0010 (10)	−0.0595 (13)
F4	0.1023 (11)	0.0479 (7)	0.1065 (11)	−0.0320 (7)	−0.0159 (8)	−0.0061 (7)
C1	0.0459 (12)	0.0778 (16)	0.0745 (15)	−0.0183 (11)	−0.0014 (10)	−0.0297 (13)
C2	0.0566 (14)	0.0630 (14)	0.0824 (16)	−0.0086 (11)	−0.0069 (11)	−0.0345 (12)
C3	0.0601 (13)	0.0419 (11)	0.0718 (14)	−0.0118 (10)	−0.0159 (11)	−0.0146 (10)
C4	0.0504 (11)	0.0401 (10)	0.0495 (11)	−0.0122 (9)	−0.0116 (9)	−0.0065 (8)
C5	0.0519 (12)	0.0468 (11)	0.0566 (12)	−0.0101 (9)	−0.0101 (9)	−0.0215 (9)
C6	0.0542 (13)	0.0580 (13)	0.0741 (15)	−0.0230 (10)	−0.0108 (11)	−0.0225 (11)
C7	0.0643 (13)	0.0430 (12)	0.0546 (12)	−0.0207 (10)	−0.0066 (10)	−0.0001 (9)
C8	0.0522 (11)	0.0431 (11)	0.0444 (11)	−0.0203 (9)	−0.0006 (9)	−0.0075 (8)
C9	0.0594 (13)	0.0629 (14)	0.0797 (16)	−0.0295 (11)	0.0040 (11)	−0.0068 (12)
C10	0.0797 (16)	0.0751 (15)	0.0522 (13)	−0.0272 (13)	0.0119 (11)	−0.0155 (11)
N2	0.0828 (13)	0.0495 (10)	0.0472 (10)	−0.0189 (9)	−0.0041 (8)	−0.0197 (8)
N3	0.0933 (14)	0.0466 (10)	0.0496 (11)	−0.0238 (9)	−0.0031 (9)	−0.0048 (8)
C13	0.0669 (16)	0.0743 (17)	0.0896 (18)	−0.0180 (14)	−0.0208 (13)	−0.0258 (14)
C14	0.0871 (19)	0.0678 (16)	0.0901 (18)	−0.0367 (15)	−0.0249 (15)	−0.0121 (14)
C15	0.0893 (18)	0.0437 (12)	0.0798 (16)	−0.0221 (12)	−0.0336 (14)	−0.0140 (11)
C16	0.0774 (15)	0.0406 (11)	0.0577 (13)	−0.0164 (10)	−0.0262 (11)	−0.0146 (9)
C17	0.0800 (16)	0.0407 (11)	0.0635 (14)	−0.0227 (11)	−0.0236 (11)	−0.0075 (10)
C18	0.0771 (16)	0.0447 (12)	0.0835 (16)	−0.0082 (12)	−0.0308 (13)	−0.0198 (11)
C19	0.0935 (18)	0.0516 (13)	0.0608 (14)	−0.0151 (12)	−0.0176 (12)	−0.0253 (11)
C20	0.0743 (14)	0.0527 (12)	0.0469 (12)	−0.0143 (11)	−0.0016 (10)	−0.0210 (10)
C21	0.117 (2)	0.112 (2)	0.0538 (15)	−0.0430 (19)	0.0201 (14)	−0.0304 (15)
C22	0.0852 (18)	0.094 (2)	0.0825 (18)	−0.0074 (15)	0.0070 (14)	−0.0493 (16)
N6	0.0885 (13)	0.0544 (11)	0.0570 (11)	−0.0311 (10)	0.0008 (9)	−0.0215 (9)
N5	0.0702 (11)	0.0415 (9)	0.0490 (10)	−0.0234 (8)	0.0010 (8)	−0.0078 (8)
C12	0.0735 (14)	0.0383 (11)	0.0507 (12)	−0.0181 (10)	−0.0012 (10)	−0.0151 (9)
C11	0.0932 (17)	0.0598 (14)	0.0409 (12)	−0.0215 (12)	−0.0025 (11)	−0.0111 (11)
N1	0.0511 (9)	0.0361 (8)	0.0403 (8)	−0.0138 (7)	−0.0024 (7)	−0.0117 (7)
N4	0.0597 (10)	0.0391 (8)	0.0428 (9)	−0.0187 (7)	−0.0004 (7)	−0.0121 (7)
C24	0.0857 (15)	0.0456 (12)	0.0534 (13)	−0.0350 (11)	0.0014 (10)	−0.0105 (9)
C23	0.0663 (13)	0.0528 (12)	0.0447 (11)	−0.0221 (10)	0.0050 (9)	−0.0140 (9)
O1	0.0834 (12)	0.0565 (10)	0.1217 (15)	−0.0247 (9)	−0.0031 (10)	0.0301 (10)
O2	0.1266 (16)	0.1143 (15)	0.1246 (16)	−0.0233 (12)	−0.0190 (12)	−0.0879 (14)

F1—C1	1.357 (3)	C13—C14	1.365 (3)
F2—C5	1.354 (2)	C14—C15	1.364 (3)
F3—C13	1.348 (3)	C14—H14A	0.9300
F4—C17	1.348 (2)	C15—C16	1.390 (3)
C1—C6	1.366 (3)	C15—H15A	0.9300
C1—C2	1.366 (3)	C16—C17	1.382 (3)
C2—C3	1.371 (3)	C16—C19	1.483 (3)
C2—H2A	0.9300	C17—C18	1.371 (3)
C3—C4	1.396 (3)	C18—H18A	0.9300
C3—H3A	0.9300	C19—O2	1.215 (2)
C4—C5	1.378 (3)	C19—C20	1.493 (3)
C4—C7	1.486 (3)	C20—N4	1.437 (2)
C5—C6	1.364 (3)	C20—C22	1.498 (3)
C6—H6A	0.9300	C20—C21	1.502 (3)
C7—O1	1.209 (2)	C21—C22	1.464 (4)
C7—C8	1.498 (3)	C21—H21A	0.9700
C8—N1	1.436 (2)	C21—H21B	0.9700
C8—C9	1.494 (3)	C22—H22A	0.9700
C8—C10	1.503 (3)	C22—H22B	0.9700
C9—C10	1.470 (3)	N6—C24	1.303 (3)
C9—H9A	0.9700	N6—C23	1.342 (3)
C9—H9B	0.9700	N5—C23	1.305 (2)
C10—H10A	0.9700	N5—N4	1.363 (2)
C10—H10B	0.9700	C12—N1	1.327 (2)
N2—C11	1.309 (3)	C12—H12A	0.9300
N2—N1	1.361 (2)	C11—H11A	0.9300
N3—C12	1.307 (2)	N4—C24	1.330 (2)
N3—C11	1.348 (3)	C24—H24A	0.9300
C13—C18	1.364 (3)	C23—H23A	0.9300
F1—C1—C6	117.4 (2)	C17—C16—C15	116.4 (2)
F1—C1—C2	118.9 (2)	C17—C16—C19	124.0 (2)
C6—C1—C2	123.7 (2)	C15—C16—C19	119.55 (19)
C1—C2—C3	117.9 (2)	F4—C17—C18	118.42 (19)
C1—C2—H2A	121.1	F4—C17—C16	117.9 (2)
C3—C2—H2A	121.1	C18—C17—C16	123.6 (2)
C2—C3—C4	121.47 (19)	C13—C18—C17	116.4 (2)
C2—C3—H3A	119.3	C13—C18—H18A	121.8
C4—C3—H3A	119.3	C17—C18—H18A	121.8
C5—C4—C3	116.77 (19)	O2—C19—C16	119.7 (2)
C5—C4—C7	124.50 (17)	O2—C19—C20	119.5 (2)
C3—C4—C7	118.72 (17)	C16—C19—C20	120.83 (17)
F2—C5—C6	117.88 (17)	N4—C20—C19	116.14 (18)
F2—C5—C4	118.42 (18)	N4—C20—C22	116.23 (18)
C6—C5—C4	123.66 (18)	C19—C20—C22	117.79 (19)
C5—C6—C1	116.47 (19)	N4—C20—C21	117.26 (19)
C5—C6—H6A	121.8	C19—C20—C21	118.64 (19)
C1—C6—H6A	121.8	C22—C20—C21	58.42 (17)
O1—C7—C4	120.29 (19)	C22—C21—C20	60.67 (17)
O1—C7—C8	119.54 (19)	C22—C21—H21A	117.7
C4—C7—C8	120.14 (16)	C20—C21—H21A	117.7
N1—C8—C9	116.98 (16)	C22—C21—H21B	117.7
N1—C8—C7	115.56 (15)	C20—C21—H21B	117.7
C9—C8—C7	118.05 (17)	H21A—C21—H21B	114.8
N1—C8—C10	117.75 (16)	C21—C22—C20	60.91 (16)
C9—C8—C10	58.74 (14)	C21—C22—H22A	117.7
C7—C8—C10	117.95 (17)	C20—C22—H22A	117.7
C10—C9—C8	60.96 (14)	C21—C22—H22B	117.7
C10—C9—H9A	117.7	C20—C22—H22B	117.7
C8—C9—H9A	117.7	H22A—C22—H22B	114.8
C10—C9—H9B	117.7	C24—N6—C23	102.17 (16)
C8—C9—H9B	117.7	C23—N5—N4	102.04 (15)
H9A—C9—H9B	114.8	N3—C12—N1	111.64 (17)
C9—C10—C8	60.30 (14)	N3—C12—H12A	124.2
C9—C10—H10A	117.7	N1—C12—H12A	124.2
C8—C10—H10A	117.7	N2—C11—N3	115.84 (18)
C9—C10—H10B	117.7	N2—C11—H11A	122.1
C8—C10—H10B	117.7	N3—C11—H11A	122.1
H10A—C10—H10B	114.9	C12—N1—N2	108.90 (15)
C11—N2—N1	101.85 (15)	C12—N1—C8	132.04 (15)
C12—N3—C11	101.76 (17)	N2—N1—C8	119.02 (14)
F3—C13—C18	118.3 (2)	C24—N4—N5	108.55 (15)
F3—C13—C14	118.2 (3)	C24—N4—C20	131.78 (17)
C18—C13—C14	123.4 (3)	N5—N4—C20	119.64 (15)
C15—C14—C13	118.1 (2)	N6—C24—N4	111.46 (18)
C15—C14—H14A	120.9	N6—C24—H24A	124.3
C13—C14—H14A	120.9	N4—C24—H24A	124.3
C14—C15—C16	122.0 (2)	N5—C23—N6	115.78 (18)
C14—C15—H15A	119.0	N5—C23—H23A	122.1
C16—C15—H15A	119.0	N6—C23—H23A	122.1
F1—C1—C2—C3	−178.8 (2)	C17—C16—C19—O2	132.8 (2)
C6—C1—C2—C3	1.6 (4)	C15—C16—C19—O2	−45.8 (3)
C1—C2—C3—C4	0.9 (3)	C17—C16—C19—C20	−49.5 (3)
C2—C3—C4—C5	−2.6 (3)	C15—C16—C19—C20	131.9 (2)
C2—C3—C4—C7	178.48 (19)	O2—C19—C20—N4	156.3 (2)
C3—C4—C5—F2	−175.89 (17)	C16—C19—C20—N4	−21.4 (3)
C7—C4—C5—F2	2.9 (3)	O2—C19—C20—C22	11.7 (3)
C3—C4—C5—C6	2.1 (3)	C16—C19—C20—C22	−166.0 (2)
C7—C4—C5—C6	−179.09 (19)	O2—C19—C20—C21	−55.6 (3)
F2—C5—C6—C1	178.18 (18)	C16—C19—C20—C21	126.7 (2)
C4—C5—C6—C1	0.2 (3)	N4—C20—C21—C22	−105.5 (2)
F1—C1—C6—C5	178.23 (19)	C19—C20—C21—C22	106.7 (2)
C2—C1—C6—C5	−2.1 (3)	N4—C20—C22—C21	107.2 (2)
C5—C4—C7—O1	−137.7 (2)	C19—C20—C22—C21	−108.2 (2)
C3—C4—C7—O1	41.0 (3)	C11—N3—C12—N1	−0.4 (2)
C5—C4—C7—C8	44.3 (3)	N1—N2—C11—N3	−0.8 (3)
C3—C4—C7—C8	−136.94 (19)	C12—N3—C11—N2	0.8 (3)
O1—C7—C8—N1	−152.1 (2)	N3—C12—N1—N2	−0.1 (2)
C4—C7—C8—N1	25.9 (2)	N3—C12—N1—C8	−177.66 (18)
O1—C7—C8—C9	−6.6 (3)	C11—N2—N1—C12	0.5 (2)
C4—C7—C8—C9	171.43 (17)	C11—N2—N1—C8	178.46 (17)
O1—C7—C8—C10	60.9 (3)	C9—C8—N1—C12	93.1 (2)
C4—C7—C8—C10	−121.1 (2)	C7—C8—N1—C12	−121.0 (2)
N1—C8—C9—C10	−107.59 (19)	C10—C8—N1—C12	26.0 (3)
C7—C8—C9—C10	107.3 (2)	C9—C8—N1—N2	−84.3 (2)
N1—C8—C10—C9	106.28 (19)	C7—C8—N1—N2	61.6 (2)
C7—C8—C10—C9	−107.5 (2)	C10—C8—N1—N2	−151.36 (17)
F3—C13—C14—C15	178.6 (2)	C23—N5—N4—C24	−0.2 (2)
C18—C13—C14—C15	−0.7 (4)	C23—N5—N4—C20	−178.35 (17)
C13—C14—C15—C16	−1.0 (3)	C19—C20—N4—C24	115.3 (2)
C14—C15—C16—C17	1.9 (3)	C22—C20—N4—C24	−99.5 (3)
C14—C15—C16—C19	−179.5 (2)	C21—C20—N4—C24	−33.2 (3)
C15—C16—C17—F4	176.35 (18)	C19—C20—N4—N5	−67.0 (2)
C19—C16—C17—F4	−2.2 (3)	C22—C20—N4—N5	78.1 (2)
C15—C16—C17—C18	−1.1 (3)	C21—C20—N4—N5	144.4 (2)
C19—C16—C17—C18	−179.7 (2)	C23—N6—C24—N4	0.2 (2)
F3—C13—C18—C17	−177.9 (2)	N5—N4—C24—N6	0.0 (2)
C14—C13—C18—C17	1.4 (3)	C20—N4—C24—N6	177.81 (19)
F4—C17—C18—C13	−177.89 (19)	N4—N5—C23—N6	0.4 (2)
C16—C17—C18—C13	−0.5 (3)	C24—N6—C23—N5	−0.4 (2)

D—H···A	D—H	H···A	D···A	D—H···A
C12—H12A···O2i	0.93	2.35	3.268 (2)	171.
C24—H24A···O1ii	0.93	2.37	3.265 (3)	161.

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C12—H12A⋯O2i	0.93	2.35	3.268 (2)	171
C24—H24A⋯O1ii	0.93	2.37	3.265 (3)	161

Symmetry codes: (i) ; (ii) .