Literature DB >> 22219834

1-(4-Iodo-benz-yl)-3-methyl-pyridinium bis-(benzene-1,2-dithiol-ato)nickelate(III).

Guang-Xiang Liu1.   

Abstract

The asymmetric unit of the title compound, (C(13)H(13)IN)[Ni(C(6)H(4)S(2))(2)], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the Ni(III) ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions exhibit two different packing modes by stacking along the a axis in face-to-face and side-by-side fashions. Inter-ionic C-H⋯S hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.6947 (5) Å] are observed.

Entities:  

Year:  2011        PMID: 22219834      PMCID: PMC3247529          DOI: 10.1107/S1600536811043522

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  5 in total

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2.  Ionic pair complexes with well-separated columnar stack structure based on [Pt(mnt)2]- ions showing unusual magnetic transition: syntheses, crystal structures, and magnetic properties.

Authors:  X M Ren; H Okudera; R K Kremer; Y Song; C He; Q J Meng; P H Wu
Journal:  Inorg Chem       Date:  2004-04-19       Impact factor: 5.165

3.  Conducting metal dithiolene complexes: structural and electronic properties.

Authors:  Reizo Kato
Journal:  Chem Rev       Date:  2004-11       Impact factor: 60.622

4.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

5.  Observation of intermolecular charge transfer in a quasi-one-dimensional molecular alloy system.

Authors:  Xiaoming Ren; Yunxia Sui; Guangxiang Liu; Jingli Xie
Journal:  J Phys Chem A       Date:  2008-08-12       Impact factor: 2.781

  5 in total

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