| Literature DB >> 22219834 |
Abstract
The asymmetric unit of the title compound, (C(13)H(13)IN)[Ni(C(6)H(4)S(2))(2)], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the Ni(III) ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions exhibit two different packing modes by stacking along the a axis in face-to-face and side-by-side fashions. Inter-ionic C-H⋯S hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.6947 (5) Å] are observed.Entities:
Year: 2011 PMID: 22219834 PMCID: PMC3247529 DOI: 10.1107/S1600536811043522
Source DB: PubMed Journal: Acta Crystallogr Sect E Struct Rep Online ISSN: 1600-5368