μ-Oxido-bis-[bis-(phenanthroline-κN,N')(sulfato-κO)iron(III)] octa-hydrate.

The title complex, [Fe(2)O(SO(4))(2)(C(12)H(8)N(2))(4)]·8H(2)O, contains two unique Fe(III) cations, one oxide anion, four 1,10-phenanthroline (phen) ligands, two coordinated sulfate anions and eight lattice water mol-ecules. Each Fe(III) ion has an approximate octa-hedral geometry, coordinated by four N atoms from two phen mol-ecules, two O atoms from oxide and sulfate anions, respectively. The parallel phen mol-ecules form two-dimensional supermolecules through π-π stacking inter-actions [centroid-centroid distances = 3.684 (3), 3.711 (3), 3.790 (3), 3.847 (3), 3.746 (3), 3.732 (3) and 3.729 (3) Å]. This architecture is further stabilized by O-H⋯O hydrogen bonds involving the lattice water mol-ecules and sulfate O atoms.

Related literature

For transition metal complexes containing organic ligands with nitro­gen heteroatoms, see: Manson et al. (2001 ▶); Wu et al. (2009 ▶); Accorsi et al. (2009 ▶); Xie & Huang (2011 ▶); Feng et al. (2006 ▶); Yu et al. (2010 ▶); Weyhermüller et al. (2005 ▶). For phen (1,10-phenanthroline) ligands, see: Gu et al. (2006 ▶); Hu et al. (2009 ▶). For related bond lengths and angles, see: Yang et al. (2010 ▶).

Experimental

Crystal data

[Fe2O(SO4)2(C12H8N2)4]·8H2O

M = 1184.76

Monoclinic,

a = 21.589 (15) Å

b = 14.181 (10) Å

c = 16.500 (12) Å

β = 97.289 (9)°

V = 5010 (6) Å3

Z = 4

Mo Kα radiation

μ = 0.75 mm−1

T = 273 K

0.20 × 0.10 × 0.04 mm

Data collection

Bruker APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1995 ▶) T min = 0.865, T max = 0.971

11655 measured reflections

4398 independent reflections

3506 reflections with I > 2σ(I)

R int = 0.029

Refinement

R[F 2 > 2σ(F 2)] = 0.037

wR(F 2) = 0.107

S = 1.05

4398 reflections

372 parameters

15 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.66 e Å−3

Δρmin = −0.34 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536811042723/jj2103sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811042723/jj2103Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Fe2O(SO4)2(C12H8N2)4]·8H2O	F(000) = 2448
Mr = 1184.76	Dx = 1.571 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 5306 reflections
a = 21.589 (15) Å	θ = 2.2–27.3°
b = 14.181 (10) Å	µ = 0.75 mm−1
c = 16.500 (12) Å	T = 273 K
β = 97.289 (9)°	Block, black
V = 5010 (6) Å3	0.20 × 0.10 × 0.04 mm
Z = 4

Bruker APEXII CCD area-detector diffractometer	4398 independent reflections
Radiation source: fine-focus sealed tube	3506 reflections with I > 2σ(I)
graphite	Rint = 0.029
φ and ω scans	θmax = 25.0°, θmin = 2.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 1995)	h = −25→24
Tmin = 0.865, Tmax = 0.971	k = −15→16
11655 measured reflections	l = −10→19

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.037	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.107	H atoms treated by a mixture of independent and constrained refinement
S = 1.05	w = 1/[σ2(Fo2) + (0.059P)2 + 4.8592P] where P = (Fo2 + 2Fc2)/3
4398 reflections	(Δ/σ)max < 0.001
372 parameters	Δρmax = 0.66 e Å−3
15 restraints	Δρmin = −0.34 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Fe1	0.448260 (15)	0.23530 (3)	0.15718 (2)	0.02377 (13)
S1	0.33448 (3)	0.07600 (5)	0.16883 (4)	0.03358 (19)
N1	0.38927 (10)	0.34694 (15)	0.19124 (14)	0.0311 (5)
N2	0.49425 (10)	0.36835 (15)	0.12194 (13)	0.0300 (5)
N3	0.40007 (10)	0.24313 (16)	0.02909 (14)	0.0324 (5)
N4	0.50712 (9)	0.15827 (15)	0.08713 (13)	0.0280 (5)
C1	0.33823 (14)	0.3357 (2)	0.2267 (2)	0.0451 (8)
H1A	0.3242	0.2749	0.2350	0.054*
C2	0.30476 (15)	0.4114 (2)	0.2520 (2)	0.0542 (9)
H2A	0.2688	0.4007	0.2762	0.065*
C3	0.32438 (15)	0.5010 (2)	0.2414 (2)	0.0529 (9)
H3A	0.3023	0.5518	0.2591	0.063*
C4	0.37800 (14)	0.5163 (2)	0.20385 (19)	0.0405 (7)
C5	0.40939 (12)	0.43659 (18)	0.18015 (16)	0.0299 (6)
C6	0.54657 (13)	0.3774 (2)	0.08885 (18)	0.0374 (7)
H6A	0.5667	0.3232	0.0742	0.045*
C7	0.57287 (14)	0.4650 (2)	0.0749 (2)	0.0468 (8)
H7A	0.6100	0.4688	0.0519	0.056*
C8	0.54351 (15)	0.5446 (2)	0.0954 (2)	0.0481 (8)
H8A	0.5603	0.6034	0.0859	0.058*
C9	0.48812 (14)	0.5384 (2)	0.13080 (18)	0.0390 (7)
C10	0.46545 (12)	0.44758 (18)	0.14267 (16)	0.0294 (6)
C11	0.40202 (17)	0.6080 (2)	0.1890 (2)	0.0527 (9)
H11A	0.3810	0.6612	0.2037	0.063*
C12	0.45421 (17)	0.6181 (2)	0.1542 (2)	0.0536 (9)
H12A	0.4687	0.6784	0.1450	0.064*
C13	0.34567 (14)	0.2827 (2)	0.0008 (2)	0.0483 (8)
H13A	0.3242	0.3157	0.0372	0.058*
C14	0.31937 (16)	0.2773 (3)	−0.0807 (2)	0.0602 (10)
H14A	0.2809	0.3053	−0.0975	0.072*
C15	0.35054 (17)	0.2305 (3)	−0.1358 (2)	0.0566 (9)
H15A	0.3335	0.2263	−0.1904	0.068*
C16	0.40840 (15)	0.1890 (2)	−0.10906 (18)	0.0440 (7)
C17	0.43098 (13)	0.1969 (2)	−0.02581 (16)	0.0327 (6)
C18	0.56001 (12)	0.1158 (2)	0.11755 (19)	0.0368 (7)
H18A	0.5726	0.1188	0.1735	0.044*
C19	0.59695 (14)	0.0673 (2)	0.0685 (2)	0.0440 (8)
H19A	0.6337	0.0387	0.0917	0.053*
C20	0.57940 (15)	0.0616 (2)	−0.0132 (2)	0.0456 (8)
H20A	0.6040	0.0289	−0.0460	0.055*
C21	0.52383 (14)	0.1052 (2)	−0.04818 (18)	0.0384 (7)
C22	0.48900 (12)	0.15288 (18)	0.00512 (16)	0.0308 (6)
C23	0.44517 (19)	0.1396 (3)	−0.1616 (2)	0.0552 (9)
H23A	0.4306	0.1343	−0.2169	0.066*
C24	0.50066 (18)	0.1005 (2)	−0.1325 (2)	0.0524 (9)
H24A	0.5240	0.0701	−0.1683	0.063*
O1	0.5000	0.22796 (18)	0.2500	0.0307 (6)
O1W	0.65938 (13)	0.2776 (2)	0.01141 (19)	0.0760 (8)
O2	0.39311 (9)	0.13274 (15)	0.17760 (13)	0.0445 (5)
O2W	0.32992 (16)	0.80292 (19)	0.14393 (18)	0.0765 (8)
O3	0.31002 (12)	0.0750 (2)	0.08246 (15)	0.0694 (7)
O3W	0.21915 (15)	0.9578 (3)	0.9884 (2)	0.1018 (11)
O4	0.35088 (12)	−0.01746 (17)	0.19715 (18)	0.0709 (8)
O4W	0.26638 (15)	0.1716 (2)	0.36928 (17)	0.0777 (8)
O5	0.29116 (11)	0.12164 (18)	0.21519 (16)	0.0640 (7)
H2WA	0.334 (2)	0.792 (3)	0.0943 (11)	0.096*
H4WA	0.2455 (19)	0.220 (2)	0.352 (2)	0.096*
H2WB	0.333 (2)	0.8619 (9)	0.151 (2)	0.096*
H1WA	0.6784 (19)	0.250 (3)	0.0541 (19)	0.096*
H4WB	0.2867 (18)	0.153 (3)	0.3310 (18)	0.096*
H1WB	0.6807 (17)	0.3280 (18)	0.008 (3)	0.096*
H3WB	0.2496 (13)	0.936 (3)	0.966 (3)	0.096*
H3WA	0.2316 (17)	1.0085 (18)	1.013 (3)	0.096*

	U11	U22	U33	U12	U13	U23
Fe1	0.0213 (2)	0.0267 (2)	0.0239 (2)	0.00157 (14)	0.00528 (14)	−0.00084 (15)
S1	0.0288 (4)	0.0339 (4)	0.0391 (4)	−0.0059 (3)	0.0086 (3)	−0.0057 (3)
N1	0.0267 (11)	0.0321 (13)	0.0356 (13)	0.0037 (9)	0.0089 (10)	−0.0025 (10)
N2	0.0285 (12)	0.0313 (12)	0.0305 (12)	0.0006 (9)	0.0054 (9)	0.0018 (10)
N3	0.0249 (12)	0.0375 (13)	0.0338 (13)	−0.0004 (9)	−0.0003 (10)	0.0025 (10)
N4	0.0270 (11)	0.0290 (12)	0.0285 (12)	0.0002 (9)	0.0057 (9)	−0.0043 (9)
C1	0.0353 (16)	0.0445 (18)	0.059 (2)	−0.0010 (13)	0.0179 (15)	−0.0051 (15)
C2	0.0362 (17)	0.061 (2)	0.070 (2)	0.0075 (15)	0.0244 (17)	−0.0127 (19)
C3	0.0414 (18)	0.055 (2)	0.062 (2)	0.0223 (15)	0.0065 (16)	−0.0137 (17)
C4	0.0385 (16)	0.0369 (17)	0.0448 (18)	0.0129 (13)	−0.0001 (14)	−0.0047 (14)
C5	0.0280 (13)	0.0315 (15)	0.0288 (15)	0.0064 (11)	−0.0014 (11)	−0.0006 (11)
C6	0.0326 (15)	0.0409 (17)	0.0402 (17)	−0.0023 (12)	0.0101 (13)	0.0034 (13)
C7	0.0376 (17)	0.055 (2)	0.049 (2)	−0.0118 (15)	0.0106 (14)	0.0064 (16)
C8	0.0517 (19)	0.0401 (18)	0.051 (2)	−0.0160 (15)	0.0028 (16)	0.0063 (15)
C9	0.0460 (17)	0.0319 (15)	0.0370 (16)	−0.0044 (13)	−0.0021 (13)	0.0050 (13)
C10	0.0312 (14)	0.0285 (14)	0.0270 (14)	0.0011 (11)	−0.0021 (11)	0.0011 (11)
C11	0.065 (2)	0.0285 (16)	0.063 (2)	0.0141 (15)	0.0031 (18)	−0.0055 (15)
C12	0.070 (2)	0.0262 (16)	0.063 (2)	−0.0002 (15)	0.0034 (19)	0.0021 (15)
C13	0.0364 (17)	0.060 (2)	0.0479 (19)	0.0023 (15)	0.0028 (14)	0.0070 (16)
C14	0.0385 (18)	0.079 (3)	0.057 (2)	−0.0018 (17)	−0.0150 (17)	0.023 (2)
C15	0.057 (2)	0.071 (2)	0.0373 (18)	−0.0160 (18)	−0.0108 (16)	0.0111 (17)
C16	0.0529 (19)	0.0467 (18)	0.0312 (16)	−0.0169 (15)	0.0009 (14)	0.0044 (14)
C17	0.0367 (15)	0.0324 (14)	0.0291 (15)	−0.0084 (12)	0.0049 (12)	0.0015 (12)
C18	0.0297 (14)	0.0370 (16)	0.0441 (17)	0.0026 (12)	0.0057 (12)	−0.0030 (13)
C19	0.0305 (15)	0.0391 (17)	0.064 (2)	0.0040 (12)	0.0138 (15)	−0.0052 (15)
C20	0.0472 (18)	0.0387 (17)	0.057 (2)	−0.0020 (14)	0.0297 (16)	−0.0101 (15)
C21	0.0473 (17)	0.0331 (15)	0.0386 (17)	−0.0110 (13)	0.0206 (14)	−0.0049 (13)
C22	0.0366 (15)	0.0283 (14)	0.0285 (14)	−0.0067 (11)	0.0083 (12)	−0.0002 (11)
C23	0.081 (3)	0.058 (2)	0.0278 (17)	−0.0188 (19)	0.0112 (17)	−0.0084 (15)
C24	0.074 (2)	0.051 (2)	0.0370 (18)	−0.0136 (18)	0.0265 (17)	−0.0101 (15)
O1	0.0298 (14)	0.0383 (15)	0.0241 (13)	0.000	0.0038 (11)	0.000
O1W	0.0698 (19)	0.077 (2)	0.084 (2)	0.0032 (15)	0.0218 (16)	0.0093 (16)
O2	0.0327 (11)	0.0473 (12)	0.0547 (14)	−0.0119 (9)	0.0102 (10)	−0.0007 (10)
O2W	0.109 (2)	0.0455 (15)	0.076 (2)	−0.0050 (16)	0.0158 (18)	−0.0005 (14)
O3	0.0637 (16)	0.089 (2)	0.0500 (15)	−0.0046 (14)	−0.0119 (12)	−0.0159 (14)
O3W	0.081 (2)	0.119 (3)	0.104 (3)	−0.027 (2)	0.005 (2)	−0.030 (2)
O4	0.0770 (18)	0.0403 (14)	0.094 (2)	−0.0042 (12)	0.0056 (15)	0.0135 (13)
O4W	0.078 (2)	0.096 (2)	0.0598 (18)	0.0219 (16)	0.0127 (15)	−0.0060 (16)
O5	0.0531 (14)	0.0703 (17)	0.0763 (18)	−0.0122 (12)	0.0377 (13)	−0.0198 (14)

Fe1—O1	1.7804 (10)	C9—C12	1.427 (4)
Fe1—O2	1.936 (2)	C11—C12	1.335 (5)
Fe1—N4	2.125 (2)	C11—H11A	0.9300
Fe1—N1	2.151 (2)	C12—H12A	0.9300
Fe1—N3	2.237 (3)	C13—C14	1.393 (5)
Fe1—N2	2.243 (2)	C13—H13A	0.9300
S1—O4	1.435 (3)	C14—C15	1.370 (5)
S1—O5	1.435 (2)	C14—H14A	0.9300
S1—O3	1.456 (3)	C15—C16	1.401 (5)
S1—O2	1.491 (2)	C15—H15A	0.9300
N1—C1	1.321 (4)	C16—C17	1.403 (4)
N1—C5	1.363 (3)	C16—C23	1.431 (5)
N2—C6	1.322 (3)	C17—C22	1.434 (4)
N2—C10	1.349 (3)	C18—C19	1.389 (4)
N3—C13	1.332 (4)	C18—H18A	0.9300
N3—C17	1.360 (4)	C19—C20	1.355 (5)
N4—C18	1.331 (3)	C19—H19A	0.9300
N4—C22	1.362 (3)	C20—C21	1.407 (5)
C1—C2	1.387 (4)	C20—H20A	0.9300
C1—H1A	0.9300	C21—C22	1.401 (4)
C2—C3	1.358 (5)	C21—C24	1.419 (4)
C2—H2A	0.9300	C23—C24	1.351 (5)
C3—C4	1.398 (4)	C23—H23A	0.9300
C3—H3A	0.9300	C24—H24A	0.9300
C4—C5	1.399 (4)	O1—Fe1i	1.7804 (10)
C4—C11	1.432 (5)	O1W—H1WA	0.861 (10)
C5—C10	1.436 (4)	O1W—H1WB	0.856 (10)
C6—C7	1.397 (4)	O2W—H2WA	0.849 (10)
C6—H6A	0.9300	O2W—H2WB	0.845 (10)
C7—C8	1.358 (5)	O3W—H3WB	0.848 (7)
C7—H7A	0.9300	O3W—H3WA	0.849 (7)
C8—C9	1.399 (4)	O4W—H4WA	0.851 (10)
C8—H8A	0.9300	O4W—H4WB	0.854 (10)
C9—C10	1.400 (4)
O1—Fe1—O2	97.99 (10)	C9—C8—H8A	119.9
O1—Fe1—N4	94.85 (9)	C8—C9—C10	116.7 (3)
O2—Fe1—N4	97.58 (10)	C8—C9—C12	123.9 (3)
O1—Fe1—N1	98.39 (9)	C10—C9—C12	119.4 (3)
O2—Fe1—N1	96.31 (10)	N2—C10—C9	123.4 (3)
N4—Fe1—N1	159.26 (9)	N2—C10—C5	117.4 (2)
O1—Fe1—N3	168.95 (6)	C9—C10—C5	119.3 (2)
O2—Fe1—N3	88.80 (9)	C12—C11—C4	121.0 (3)
N4—Fe1—N3	75.53 (9)	C12—C11—H11A	119.5
N1—Fe1—N3	89.46 (9)	C4—C11—H11A	119.5
O1—Fe1—N2	91.27 (9)	C11—C12—C9	121.4 (3)
O2—Fe1—N2	168.33 (8)	C11—C12—H12A	119.3
N4—Fe1—N2	88.65 (9)	C9—C12—H12A	119.3
N1—Fe1—N2	75.21 (10)	N3—C13—C14	123.3 (3)
N3—Fe1—N2	83.19 (8)	N3—C13—H13A	118.4
O4—S1—O5	113.16 (17)	C14—C13—H13A	118.4
O4—S1—O3	110.74 (17)	C15—C14—C13	119.5 (3)
O5—S1—O3	110.24 (16)	C15—C14—H14A	120.2
O4—S1—O2	107.19 (15)	C13—C14—H14A	120.2
O5—S1—O2	107.91 (14)	C14—C15—C16	119.2 (3)
O3—S1—O2	107.35 (14)	C14—C15—H15A	120.4
C1—N1—C5	118.0 (2)	C16—C15—H15A	120.4
C1—N1—Fe1	125.6 (2)	C15—C16—C17	117.4 (3)
C5—N1—Fe1	116.24 (17)	C15—C16—C23	123.8 (3)
C6—N2—C10	118.0 (2)	C17—C16—C23	118.8 (3)
C6—N2—Fe1	128.21 (19)	N3—C17—C16	123.5 (3)
C10—N2—Fe1	113.67 (18)	N3—C17—C22	116.9 (2)
C13—N3—C17	117.1 (3)	C16—C17—C22	119.5 (3)
C13—N3—Fe1	129.5 (2)	N4—C18—C19	122.2 (3)
C17—N3—Fe1	113.38 (17)	N4—C18—H18A	118.9
C18—N4—C22	118.3 (2)	C19—C18—H18A	118.9
C18—N4—Fe1	124.80 (19)	C20—C19—C18	120.0 (3)
C22—N4—Fe1	116.94 (17)	C20—C19—H19A	120.0
N1—C1—C2	122.4 (3)	C18—C19—H19A	120.0
N1—C1—H1A	118.8	C19—C20—C21	119.9 (3)
C2—C1—H1A	118.8	C19—C20—H20A	120.1
C3—C2—C1	120.2 (3)	C21—C20—H20A	120.1
C3—C2—H2A	119.9	C22—C21—C20	116.9 (3)
C1—C2—H2A	119.9	C22—C21—C24	119.2 (3)
C2—C3—C4	119.4 (3)	C20—C21—C24	123.9 (3)
C2—C3—H3A	120.3	N4—C22—C21	122.8 (3)
C4—C3—H3A	120.3	N4—C22—C17	117.2 (2)
C3—C4—C5	117.2 (3)	C21—C22—C17	120.0 (3)
C3—C4—C11	123.7 (3)	C24—C23—C16	121.4 (3)
C5—C4—C11	119.1 (3)	C24—C23—H23A	119.3
N1—C5—C4	122.8 (3)	C16—C23—H23A	119.3
N1—C5—C10	117.3 (2)	C23—C24—C21	121.0 (3)
C4—C5—C10	119.8 (3)	C23—C24—H24A	119.5
N2—C6—C7	122.8 (3)	C21—C24—H24A	119.5
N2—C6—H6A	118.6	Fe1i—O1—Fe1	173.30 (17)
C7—C6—H6A	118.6	H1WA—O1W—H1WB	103 (2)
C8—C7—C6	119.1 (3)	S1—O2—Fe1	157.16 (15)
C8—C7—H7A	120.5	H2WA—O2W—H2WB	107 (2)
C6—C7—H7A	120.5	H3WB—O3W—H3WA	107.4
C7—C8—C9	120.1 (3)	H4WA—O4W—H4WB	107 (2)
C7—C8—H8A	119.9

D—H···A	D—H	H···A	D···A	D—H···A
O3W—H3WA···O3ii	0.85 (1)	2.14 (3)	2.872 (4)	144 (4)
O2W—H2WB···O4iii	0.85 (1)	1.89 (2)	2.713 (4)	163 (4)
O4W—H4WB···O5	0.85 (1)	1.98 (2)	2.756 (4)	151 (4)
O1W—H1WB···O3Wiv	0.86 (1)	2.06 (1)	2.909 (5)	171 (4)
O1W—H1WA···O4Wi	0.86 (1)	1.97 (2)	2.811 (5)	165 (5)
O3W—H3WB···O4Wv	0.85 (1)	2.28 (3)	2.964 (5)	138 (3)

Table 1

Selected geometric parameters (Å, °)

Fe1—O1	1.7804 (10)
Fe1—O2	1.936 (2)
Fe1—N4	2.125 (2)
Fe1—N1	2.151 (2)
Fe1—N3	2.237 (3)
Fe1—N2	2.243 (2)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O3W—H3WA⋯O3i	0.85 (1)	2.14 (3)	2.872 (4)	144 (4)
O2W—H2WB⋯O4ii	0.85 (1)	1.89 (2)	2.713 (4)	163 (4)
O4W—H4WB⋯O5	0.85 (1)	1.98 (2)	2.756 (4)	151 (4)
O1W—H1WB⋯O3Wiii	0.86 (1)	2.06 (1)	2.909 (5)	171 (4)
O1W—H1WA⋯O4Wiv	0.86 (1)	1.97 (2)	2.811 (5)	165 (5)
O3W—H3WB⋯O4Wv	0.85 (1)	2.28 (3)	2.964 (5)	138 (3)

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) .