Poly[(μ(3)-biphenyl-3,3'-dicarboxyl-ato)(1,10-phenanthroline)cadmium].

In the title compound, [Cd(C(14)H(8)O(4))(C(12)H(8)N(2))](n), the Cd(II) ion is seven-coordinated in a distorted penta-gonal-bipyramidal coordination geometry by five O atoms from bridging biphenyl-3,3'-dicarboylate (dpda) ligands and two N atoms from a 1,10-phenanthroline (1,10-phen) ligand. In the crystal, dinuclear units with a Cd⋯Cd separation of 3.8208 (7) Å are observed. Each of these dinuclear units is bridged via 3,3'-bpda in a chelating/chelating and bridging fashion, generating a zigzag chain along the c axis. Neighboring chains are further packed via weak π-π inter-actions between inter-chain parallel 1,10-phen rings [centroid-centroid distance = 3.5197 (9) Å] into a three-dimensional supra-molecular architecture.

Related literature

For the use of biphenyl­dicarboxyl­ato ligands in supra­molecular chemistry, see: Furukawa et al. (2008 ▶); Qu (2007 ▶); Zhu (2010 ▶).

Experimental

Crystal data

[Cd(C14H8O4)(C12H8N2)]

M = 532.81

Monoclinic,

a = 26.1947 (17) Å

b = 9.7258 (5) Å

c = 21.2247 (14) Å

β = 127.411 (1)°

V = 4295.0 (5) Å3

Z = 8

Mo Kα radiation

μ = 1.05 mm−1

T = 296 K

0.22 × 0.16 × 0.12 mm

Data collection

Bruker APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2001 ▶) T min = 0.804, T max = 0.887

12984 measured reflections

4902 independent reflections

3799 reflections with I > 2σ(I)

R int = 0.029

Refinement

R[F 2 > 2σ(F 2)] = 0.033

wR(F 2) = 0.075

S = 1.04

4902 reflections

298 parameters

20 restraints

H-atom parameters constrained

Δρmax = 0.68 e Å−3

Δρmin = −0.39 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SIR97 (Altomare et al., 1999 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536811042085/im2322sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811042085/im2322Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cd(C14H8O4)(C12H8N2)]	F(000) = 2128
Mr = 532.81	Dx = 1.648 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 4252 reflections
a = 26.1947 (17) Å	θ = 2.3–26.6°
b = 9.7258 (5) Å	µ = 1.05 mm−1
c = 21.2247 (14) Å	T = 296 K
β = 127.411 (1)°	Block, colorless
V = 4295.0 (5) Å3	0.22 × 0.16 × 0.12 mm
Z = 8

Bruker APEXII CCD area-detector diffractometer	4902 independent reflections
Radiation source: fine-focus sealed tube	3799 reflections with I > 2σ(I)
graphite	Rint = 0.029
φ and ω scans	θmax = 27.5°, θmin = 2.0°
Absorption correction: multi-scan (SADABS; Bruker, 2001)	h = −33→34
Tmin = 0.804, Tmax = 0.887	k = −12→12
12984 measured reflections	l = −22→27

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.033	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.075	H-atom parameters constrained
S = 1.04	w = 1/[σ2(Fo2) + (0.0264P)2 + 5.2631P] where P = (Fo2 + 2Fc2)/3
4902 reflections	(Δ/σ)max = 0.002
298 parameters	Δρmax = 0.68 e Å−3
20 restraints	Δρmin = −0.39 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cd1	0.576743 (12)	0.54986 (2)	0.356955 (13)	0.03981 (9)
O4	0.58387 (13)	0.7247 (2)	0.43196 (14)	0.0562 (6)
O2	0.53633 (12)	1.4416 (2)	0.71597 (14)	0.0510 (6)
N1	0.55605 (13)	0.3153 (3)	0.35361 (14)	0.0391 (6)
N2	0.66457 (14)	0.4227 (3)	0.38232 (16)	0.0462 (7)
O1	0.60664 (16)	1.2882 (2)	0.80000 (16)	0.0743 (9)
O3	0.63552 (15)	0.5452 (3)	0.50456 (15)	0.0715 (8)
C8	0.63079 (16)	0.9542 (3)	0.62890 (18)	0.0419 (7)
C22	0.7643 (2)	0.2526 (5)	0.4166 (2)	0.0690 (11)
H22	0.7980	0.1969	0.4287	0.083*
C15	0.50313 (17)	0.2623 (4)	0.33813 (19)	0.0493 (8)
H15	0.4707	0.3218	0.3267	0.059*
C9	0.61051 (15)	0.8739 (3)	0.56284 (18)	0.0384 (7)
H9	0.5779	0.9068	0.5125	0.046*
C6	0.60253 (15)	1.1531 (3)	0.67908 (18)	0.0378 (7)
H6	0.6193	1.1044	0.7256	0.045*
C25	0.66020 (16)	0.2840 (3)	0.38477 (18)	0.0429 (8)
C7	0.57685 (16)	1.2827 (3)	0.66989 (18)	0.0398 (7)
C5	0.60382 (15)	1.0940 (3)	0.62004 (18)	0.0372 (7)
C21	0.70931 (19)	0.1938 (4)	0.4015 (2)	0.0540 (9)
C26	0.60325 (16)	0.2285 (3)	0.37016 (17)	0.0410 (7)
C24	0.71735 (19)	0.4739 (4)	0.3960 (2)	0.0607 (10)
H24	0.7207	0.5686	0.3937	0.073*
C14	0.61750 (17)	0.6662 (3)	0.4976 (2)	0.0462 (8)
C10	0.63737 (18)	0.7474 (4)	0.5699 (2)	0.0510 (9)
C23	0.7685 (2)	0.3906 (5)	0.4137 (2)	0.0713 (12)
H23	0.8049	0.4303	0.4234	0.086*
C2	0.5534 (2)	1.3575 (4)	0.6021 (2)	0.0577 (10)
H2	0.5363	1.4447	0.5957	0.069*
C1	0.57283 (18)	1.3394 (3)	0.7327 (2)	0.0475 (8)
C3	0.5556 (2)	1.3028 (4)	0.5438 (2)	0.0668 (12)
H3	0.5407	1.3539	0.4986	0.080*
C17	0.5397 (2)	0.0336 (4)	0.3544 (2)	0.0605 (11)
H17	0.5336	−0.0606	0.3544	0.073*
C4	0.57985 (18)	1.1717 (4)	0.5526 (2)	0.0513 (9)
H4	0.5801	1.1351	0.5123	0.062*
C16	0.4936 (2)	0.1214 (4)	0.3381 (2)	0.0600 (10)
H16	0.4555	0.0885	0.3270	0.072*
C19	0.6478 (2)	−0.0034 (4)	0.3886 (2)	0.0646 (11)
H19	0.6439	−0.0982	0.3901	0.078*
C11	0.6841 (3)	0.6979 (5)	0.6435 (3)	0.0999 (17)
H11	0.7014	0.6111	0.6491	0.120*
C18	0.59693 (19)	0.0839 (3)	0.37142 (19)	0.0505 (9)
C13	0.6786 (2)	0.9026 (5)	0.7021 (2)	0.0867 (16)
H13	0.6926	0.9536	0.7470	0.104*
C12	0.7065 (3)	0.7767 (6)	0.7108 (3)	0.118 (2)
H12	0.7399	0.7446	0.7610	0.142*
C20	0.7008 (2)	0.0496 (4)	0.4026 (2)	0.0659 (11)
H20	0.7332	−0.0095	0.4135	0.079*

	U11	U22	U33	U12	U13	U23
Cd1	0.05906 (17)	0.02976 (12)	0.03860 (14)	−0.00476 (11)	0.03382 (12)	−0.00224 (10)
O4	0.0822 (18)	0.0413 (13)	0.0422 (14)	0.0027 (13)	0.0362 (14)	−0.0058 (11)
O2	0.0564 (15)	0.0473 (13)	0.0569 (15)	0.0043 (12)	0.0383 (13)	−0.0115 (11)
N1	0.0439 (15)	0.0375 (14)	0.0341 (14)	−0.0049 (12)	0.0227 (12)	0.0023 (11)
N2	0.0523 (17)	0.0492 (17)	0.0444 (16)	−0.0107 (14)	0.0332 (14)	−0.0059 (13)
O1	0.145 (3)	0.0429 (14)	0.0609 (17)	0.0272 (16)	0.0757 (19)	0.0103 (12)
O3	0.107 (2)	0.0565 (13)	0.0489 (9)	0.0251 (13)	0.0461 (13)	0.0007 (11)
C8	0.0485 (19)	0.0465 (18)	0.0372 (17)	0.0058 (16)	0.0295 (15)	−0.0008 (15)
C22	0.066 (3)	0.094 (3)	0.058 (2)	0.010 (3)	0.043 (2)	−0.002 (2)
C15	0.055 (2)	0.049 (2)	0.046 (2)	−0.0103 (17)	0.0320 (18)	0.0016 (16)
C9	0.0429 (18)	0.0410 (17)	0.0334 (16)	0.0023 (14)	0.0243 (14)	−0.0009 (13)
C6	0.0468 (18)	0.0352 (15)	0.0384 (17)	−0.0041 (14)	0.0295 (15)	−0.0034 (13)
C25	0.052 (2)	0.0461 (19)	0.0315 (17)	−0.0015 (16)	0.0260 (16)	−0.0051 (14)
C7	0.0506 (19)	0.0361 (16)	0.0413 (17)	−0.0006 (14)	0.0324 (16)	−0.0045 (14)
C5	0.0402 (17)	0.0390 (16)	0.0388 (17)	−0.0025 (13)	0.0273 (15)	−0.0064 (13)
C21	0.061 (2)	0.067 (2)	0.0387 (19)	0.0051 (19)	0.0325 (18)	−0.0048 (17)
C26	0.054 (2)	0.0372 (17)	0.0282 (16)	−0.0054 (15)	0.0231 (15)	−0.0034 (13)
C24	0.065 (3)	0.066 (3)	0.061 (2)	−0.016 (2)	0.044 (2)	−0.0065 (19)
C14	0.061 (2)	0.0433 (14)	0.0453 (19)	0.0021 (16)	0.0380 (18)	−0.0038 (15)
C10	0.068 (2)	0.0494 (19)	0.0386 (18)	0.0156 (18)	0.0343 (18)	0.0033 (15)
C23	0.056 (3)	0.103 (4)	0.070 (3)	−0.008 (2)	0.046 (2)	−0.003 (3)
C2	0.086 (3)	0.0426 (19)	0.056 (2)	0.0179 (19)	0.049 (2)	0.0063 (17)
C1	0.074 (2)	0.0332 (17)	0.053 (2)	−0.0027 (17)	0.048 (2)	−0.0059 (16)
C3	0.107 (3)	0.057 (2)	0.053 (2)	0.024 (2)	0.057 (2)	0.0156 (18)
C17	0.083 (3)	0.039 (2)	0.048 (2)	−0.019 (2)	0.034 (2)	−0.0024 (16)
C4	0.071 (2)	0.053 (2)	0.0431 (19)	0.0113 (18)	0.0417 (19)	−0.0005 (16)
C16	0.071 (3)	0.055 (2)	0.050 (2)	−0.024 (2)	0.035 (2)	−0.0018 (18)
C19	0.093 (3)	0.0386 (19)	0.055 (2)	0.006 (2)	0.041 (2)	−0.0048 (17)
C11	0.136 (4)	0.084 (3)	0.060 (3)	0.060 (3)	0.050 (3)	0.004 (2)
C18	0.072 (3)	0.0370 (17)	0.0343 (18)	−0.0015 (17)	0.0277 (18)	−0.0024 (14)
C13	0.112 (4)	0.089 (3)	0.037 (2)	0.051 (3)	0.034 (2)	−0.002 (2)
C12	0.150 (4)	0.109 (3)	0.056 (3)	0.073 (3)	0.042 (3)	0.006 (2)
C20	0.088 (3)	0.056 (2)	0.054 (2)	0.023 (2)	0.043 (2)	−0.0011 (19)

Cd1—O4	2.258 (2)	C6—H6	0.9300
Cd1—N1	2.336 (3)	C25—C21	1.413 (5)
Cd1—N2	2.368 (3)	C25—C26	1.432 (4)
Cd1—O2i	2.368 (2)	C7—C2	1.380 (4)
Cd1—O1ii	2.388 (2)	C7—C1	1.505 (4)
Cd1—O2ii	2.497 (2)	C5—C4	1.387 (4)
Cd1—O3	2.515 (3)	C21—C20	1.423 (5)
Cd1—C14	2.731 (3)	C26—C18	1.419 (4)
O4—C14	1.245 (4)	C24—C23	1.406 (6)
O2—C1	1.271 (4)	C24—H24	0.9300
O2—Cd1i	2.368 (2)	C14—C10	1.509 (4)
O2—Cd1iii	2.497 (2)	C10—C11	1.360 (5)
N1—C15	1.320 (4)	C23—H23	0.9300
N1—C26	1.355 (4)	C2—C3	1.378 (5)
N2—C24	1.325 (4)	C2—H2	0.9300
N2—C25	1.358 (4)	C3—C4	1.386 (5)
O1—C1	1.238 (4)	C3—H3	0.9300
O1—Cd1iii	2.388 (2)	C17—C16	1.341 (6)
O3—C14	1.243 (4)	C17—C18	1.401 (6)
C8—C13	1.367 (5)	C17—H17	0.9300
C8—C9	1.397 (4)	C4—H4	0.9300
C8—C5	1.491 (4)	C16—H16	0.9300
C22—C23	1.352 (6)	C19—C20	1.336 (6)
C22—C21	1.393 (5)	C19—C18	1.428 (6)
C22—H22	0.9300	C19—H19	0.9300
C15—C16	1.393 (5)	C11—C12	1.398 (6)
C15—H15	0.9300	C11—H11	0.9300
C9—C10	1.380 (4)	C13—C12	1.380 (6)
C9—H9	0.9300	C13—H13	0.9300
C6—C7	1.385 (4)	C12—H12	0.9300
C6—C5	1.398 (4)	C20—H20	0.9300
O4—Cd1—N1	132.46 (9)	C4—C5—C6	117.3 (3)
O4—Cd1—N2	125.46 (10)	C4—C5—C8	120.7 (3)
N1—Cd1—N2	70.87 (9)	C6—C5—C8	122.0 (3)
O4—Cd1—O2i	88.24 (9)	C22—C21—C25	117.3 (4)
N1—Cd1—O2i	80.75 (9)	C22—C21—C20	123.4 (4)
N2—Cd1—O2i	145.46 (8)	C25—C21—C20	119.3 (4)
O4—Cd1—O1ii	87.04 (9)	N1—C26—C18	121.6 (3)
N1—Cd1—O1ii	140.34 (9)	N1—C26—C25	119.2 (3)
N2—Cd1—O1ii	83.53 (10)	C18—C26—C25	119.2 (3)
O2i—Cd1—O1ii	108.10 (10)	N2—C24—C23	122.6 (4)
O4—Cd1—O2ii	127.82 (8)	N2—C24—H24	118.7
N1—Cd1—O2ii	94.27 (8)	C23—C24—H24	118.7
N2—Cd1—O2ii	86.32 (8)	O3—C14—O4	121.7 (3)
O2i—Cd1—O2ii	76.36 (8)	O3—C14—C10	120.2 (3)
O1ii—Cd1—O2ii	53.28 (8)	O4—C14—C10	118.1 (3)
O4—Cd1—O3	53.83 (8)	O3—C14—Cd1	66.77 (18)
N1—Cd1—O3	88.58 (8)	O4—C14—Cd1	54.92 (16)
N2—Cd1—O3	86.12 (9)	C10—C14—Cd1	172.8 (2)
O2i—Cd1—O3	113.01 (9)	C11—C10—C9	118.9 (3)
O1ii—Cd1—O3	120.11 (10)	C11—C10—C14	119.8 (3)
O2ii—Cd1—O3	170.56 (9)	C9—C10—C14	121.2 (3)
O4—Cd1—C14	26.82 (9)	C22—C23—C24	119.6 (4)
N1—Cd1—C14	111.54 (9)	C22—C23—H23	120.2
N2—Cd1—C14	106.69 (10)	C24—C23—H23	120.2
O2i—Cd1—C14	101.72 (9)	C3—C2—C7	119.8 (3)
O1ii—Cd1—C14	104.46 (9)	C3—C2—H2	120.1
O2ii—Cd1—C14	153.63 (9)	C7—C2—H2	120.1
O3—Cd1—C14	27.01 (9)	O1—C1—O2	121.8 (3)
C14—O4—Cd1	98.26 (19)	O1—C1—C7	119.2 (3)
C1—O2—Cd1i	129.8 (2)	O2—C1—C7	119.0 (3)
C1—O2—Cd1iii	89.51 (19)	C2—C3—C4	120.0 (3)
Cd1i—O2—Cd1iii	103.50 (8)	C2—C3—H3	120.0
C15—N1—C26	118.5 (3)	C4—C3—H3	120.0
C15—N1—Cd1	125.3 (2)	C16—C17—C18	120.0 (3)
C26—N1—Cd1	116.2 (2)	C16—C17—H17	120.0
C24—N2—C25	117.8 (3)	C18—C17—H17	120.0
C24—N2—Cd1	126.5 (3)	C3—C4—C5	121.5 (3)
C25—N2—Cd1	115.8 (2)	C3—C4—H4	119.2
C1—O1—Cd1iii	95.4 (2)	C5—C4—H4	119.2
C14—O3—Cd1	86.2 (2)	C17—C16—C15	119.5 (4)
C13—C8—C9	117.5 (3)	C17—C16—H16	120.2
C13—C8—C5	121.0 (3)	C15—C16—H16	120.2
C9—C8—C5	121.4 (3)	C20—C19—C18	120.7 (4)
C23—C22—C21	119.9 (4)	C20—C19—H19	119.7
C23—C22—H22	120.1	C18—C19—H19	119.7
C21—C22—H22	120.1	C10—C11—C12	120.4 (4)
N1—C15—C16	123.1 (4)	C10—C11—H11	119.8
N1—C15—H15	118.5	C12—C11—H11	119.8
C16—C15—H15	118.5	C17—C18—C26	117.4 (4)
C10—C9—C8	122.1 (3)	C17—C18—C19	123.1 (4)
C10—C9—H9	118.9	C26—C18—C19	119.5 (4)
C8—C9—H9	118.9	C8—C13—C12	121.6 (4)
C7—C6—C5	121.5 (3)	C8—C13—H13	119.2
C7—C6—H6	119.3	C12—C13—H13	119.2
C5—C6—H6	119.3	C13—C12—C11	119.3 (4)
N2—C25—C21	122.8 (3)	C13—C12—H12	120.3
N2—C25—C26	117.9 (3)	C11—C12—H12	120.3
C21—C25—C26	119.4 (3)	C19—C20—C21	121.9 (4)
C2—C7—C6	119.8 (3)	C19—C20—H20	119.0
C2—C7—C1	120.3 (3)	C21—C20—H20	119.0
C6—C7—C1	119.9 (3)
N1—Cd1—O4—C14	45.0 (3)	Cd1—N2—C24—C23	177.4 (3)
N2—Cd1—O4—C14	−51.1 (2)	Cd1—O3—C14—O4	0.5 (4)
O2i—Cd1—O4—C14	120.7 (2)	Cd1—O3—C14—C10	−178.2 (3)
O1ii—Cd1—O4—C14	−131.0 (2)	Cd1—O4—C14—O3	−0.5 (4)
O2ii—Cd1—O4—C14	−168.08 (19)	Cd1—O4—C14—C10	178.2 (3)
O3—Cd1—O4—C14	0.3 (2)	O4—Cd1—C14—O3	179.5 (4)
O4—Cd1—N1—C15	60.5 (3)	N1—Cd1—C14—O3	33.6 (3)
N2—Cd1—N1—C15	−178.5 (3)	N2—Cd1—C14—O3	−41.9 (2)
O2i—Cd1—N1—C15	−18.5 (2)	O2i—Cd1—C14—O3	118.2 (2)
O1ii—Cd1—N1—C15	−125.7 (3)	O1ii—Cd1—C14—O3	−129.4 (2)
O2ii—Cd1—N1—C15	−93.9 (2)	O2ii—Cd1—C14—O3	−158.9 (2)
O3—Cd1—N1—C15	95.1 (2)	N1—Cd1—C14—O4	−145.9 (2)
O4—Cd1—N1—C26	−118.5 (2)	N2—Cd1—C14—O4	138.5 (2)
N2—Cd1—N1—C26	2.46 (19)	O2i—Cd1—C14—O4	−61.3 (2)
O2i—Cd1—N1—C26	162.5 (2)	O1ii—Cd1—C14—O4	51.1 (2)
O1ii—Cd1—N1—C26	55.2 (3)	O2ii—Cd1—C14—O4	21.6 (3)
O2ii—Cd1—N1—C26	87.1 (2)	O3—Cd1—C14—O4	−179.5 (4)
O3—Cd1—N1—C26	−83.9 (2)	O4—Cd1—C14—C10	−12.9 (19)
O4—Cd1—N2—C24	−51.3 (3)	N1—Cd1—C14—C10	−158.8 (19)
N1—Cd1—N2—C24	179.7 (3)	N2—Cd1—C14—C10	126 (2)
O2i—Cd1—N2—C24	143.2 (3)	O2i—Cd1—C14—C10	−74 (2)
O1ii—Cd1—N2—C24	30.4 (3)	O1ii—Cd1—C14—C10	38 (2)
O2ii—Cd1—N2—C24	83.9 (3)	O2ii—Cd1—C14—C10	9(2)
O3—Cd1—N2—C24	−90.5 (3)	O3—Cd1—C14—C10	168 (2)
O4—Cd1—N2—C25	127.0 (2)	C8—C9—C10—C11	1.4 (6)
N1—Cd1—N2—C25	−2.0 (2)	C8—C9—C10—C14	−176.3 (3)
O2i—Cd1—N2—C25	−38.5 (3)	O3—C14—C10—C11	12.1 (6)
O1ii—Cd1—N2—C25	−151.3 (2)	O4—C14—C10—C11	−166.7 (4)
O2ii—Cd1—N2—C25	−97.8 (2)	O3—C14—C10—C9	−170.2 (4)
O3—Cd1—N2—C25	87.8 (2)	O4—C14—C10—C9	11.0 (5)
O4—Cd1—O3—C14	−0.3 (2)	C21—C22—C23—C24	0.5 (6)
N1—Cd1—O3—C14	−149.0 (2)	N2—C24—C23—C22	0.5 (6)
N2—Cd1—O3—C14	140.1 (2)	C6—C7—C2—C3	0.2 (6)
O2i—Cd1—O3—C14	−69.7 (2)	C1—C7—C2—C3	−178.0 (4)
O1ii—Cd1—O3—C14	59.9 (3)	Cd1iii—O1—C1—O2	−2.7 (4)
O2ii—Cd1—O3—C14	103.3 (5)	Cd1iii—O1—C1—C7	174.9 (3)
C26—N1—C15—C16	0.1 (5)	Cd1i—O2—C1—O1	−104.7 (4)
Cd1—N1—C15—C16	−178.9 (2)	Cd1iii—O2—C1—O1	2.6 (4)
C13—C8—C9—C10	−0.4 (5)	Cd1i—O2—C1—C7	77.7 (4)
C5—C8—C9—C10	176.5 (3)	Cd1iii—O2—C1—C7	−175.0 (3)
C24—N2—C25—C21	0.3 (5)	C2—C7—C1—O1	−163.1 (4)
Cd1—N2—C25—C21	−178.1 (2)	C6—C7—C1—O1	18.7 (5)
C24—N2—C25—C26	179.9 (3)	C2—C7—C1—O2	14.6 (5)
Cd1—N2—C25—C26	1.5 (3)	C6—C7—C1—O2	−163.6 (3)
C5—C6—C7—C2	−1.8 (5)	C7—C2—C3—C4	1.4 (6)
C5—C6—C7—C1	176.4 (3)	C2—C3—C4—C5	−1.5 (6)
C7—C6—C5—C4	1.6 (5)	C6—C5—C4—C3	0.0 (5)
C7—C6—C5—C8	−179.4 (3)	C8—C5—C4—C3	−178.9 (4)
C13—C8—C5—C4	149.9 (4)	C18—C17—C16—C15	0.2 (5)
C9—C8—C5—C4	−26.9 (5)	N1—C15—C16—C17	−0.1 (5)
C13—C8—C5—C6	−29.0 (5)	C9—C10—C11—C12	−2.7 (8)
C9—C8—C5—C6	154.2 (3)	C14—C10—C11—C12	175.1 (5)
C23—C22—C21—C25	−1.0 (5)	C16—C17—C18—C26	−0.3 (5)
C23—C22—C21—C20	179.4 (4)	C16—C17—C18—C19	−179.5 (3)
N2—C25—C21—C22	0.6 (5)	N1—C26—C18—C17	0.4 (5)
C26—C25—C21—C22	−179.0 (3)	C25—C26—C18—C17	−178.1 (3)
N2—C25—C21—C20	−179.8 (3)	N1—C26—C18—C19	179.6 (3)
C26—C25—C21—C20	0.6 (5)	C25—C26—C18—C19	1.1 (5)
C15—N1—C26—C18	−0.3 (4)	C20—C19—C18—C17	178.4 (4)
Cd1—N1—C26—C18	178.9 (2)	C20—C19—C18—C26	−0.7 (5)
C15—N1—C26—C25	178.2 (3)	C9—C8—C13—C12	0.7 (7)
Cd1—N1—C26—C25	−2.7 (3)	C5—C8—C13—C12	−176.2 (5)
N2—C25—C26—N1	0.8 (4)	C8—C13—C12—C11	−2.0 (10)
C21—C25—C26—N1	−179.6 (3)	C10—C11—C12—C13	3.0 (10)
N2—C25—C26—C18	179.3 (3)	C18—C19—C20—C21	0.3 (6)
C21—C25—C26—C18	−1.1 (4)	C22—C21—C20—C19	179.3 (4)
C25—N2—C24—C23	−0.9 (5)	C25—C21—C20—C19	−0.2 (6)