Literature DB >> 22219797

Dibromido{2-[(4-nitro-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).

Sadegh Salehzadeh, Mehdi Khalaj, Saeed Dehghanpour, Isaac Tarmoradi.

Abstract

In the title compound, [ZnBr(2)(C(12)H(9)N(3)O(2))], the Zn(II) ion is bonded to two Br ions and two N atoms of the diimine ligand in a distorted tetra-hedral geometry. With the exception of the Br atoms, all other atoms are disordered over two sets of sites corresponding to a 180° rotation of the mol-ecule along [[Formula: see text]02]. The refined occupancies of the components are 0.809 (2) and 0.191 (2). In addition, the crystal studied was a non-merohedral twin with a refined component ratio of 0.343 (2):0.657 (2).

Entities: Chemical Disease Species

Year: 2011 PMID： 22219797 PMCID： PMC3246977 DOI： 10.1107/S1600536811042231

Source DB: PubMed Journal: Acta Crystallogr Sect E Struct Rep Online ISSN： 1600-5368

Related literature

For related structures, see: Khalaj et al. (2009 ▶). For background information on diimine complexes, see: Khalaj et al. (2010 ▶); Salehzadeh et al. (2011 ▶).

Experimental

Crystal data

[ZnBr2(C12H9N3O2)] M = 452.41 Triclinic, a = 7.2614 (5) Å b = 7.9228 (8) Å c = 13.6436 (15) Å α = 87.724 (4)° β = 74.719 (6)° γ = 82.007 (6)° V = 749.81 (12) Å3 Z = 2 Mo Kα radiation μ = 6.97 mm−1 T = 150 K 0.28 × 0.15 × 0.08 mm

Data collection

Nonius KappaCCD diffractometer Absorption correction: multi-scan (SORTAV; Blessing, 1995 ▶) T min = 0.417, T max = 0.588 5868 measured reflections 3252 independent reflections 2630 reflections with I > 2σ(I) R int = 0.082

Refinement

R[F 2 > 2σ(F 2)] = 0.056 wR(F 2) = 0.140 S = 1.04 3252 reflections 237 parameters 48 restraints H-atom parameters constrained Δρmax = 0.70 e Å−3 Δρmin = −1.24 e Å−3 Data collection: COLLECT (Nonius, 2002 ▶); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997 ▶); data reduction: DENZO-SMN; program(s) used to solve structure: SIR92 (Altomare et al., 1994 ▶); program(s) used to refine structure: SHELXTL (Sheldrick, 2008 ▶); molecular graphics: PLATON (Spek, 2009 ▶); software used to prepare material for publication: SHELXTL. Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536811042231/gk2406sup1.cif Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811042231/gk2406Isup2.hkl Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[ZnBr₂(C₁₂H₉N₃O₂)]	Z = 2
M_r = 452.41	F(000) = 436
Triclinic, P1	D_x = 2.004 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 7.2614 (5) Å	Cell parameters from 6572 reflections
b = 7.9228 (8) Å	θ = 2.6–27.5°
c = 13.6436 (15) Å	µ = 6.97 mm⁻¹
α = 87.724 (4)°	T = 150 K
β = 74.719 (6)°	Plate, colourless
γ = 82.007 (6)°	0.28 × 0.15 × 0.08 mm
V = 749.81 (12) Å³

Nonius KappaCCD diffractometer	3252 independent reflections
Radiation source: fine-focus sealed tube	2630 reflections with I > 2σ(I)
graphite	R_int = 0.082
Detector resolution: 9 pixels mm^-1	θ_max = 27.6°, θ_min = 2.6°
φ scans and ω scans with κ offsets	h = −9→9
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	k = −10→10
T_min = 0.417, T_max = 0.588	l = −9→17
5868 measured reflections

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.056	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.140	H-atom parameters constrained
S = 1.04	w = 1/[σ²(F_o²) + (0.0564P)² + 2.802P] where P = (F_o² + 2F_c²)/3
3252 reflections	(Δ/σ)_max < 0.001
237 parameters	Δρ_max = 0.70 e Å⁻³
48 restraints	Δρ_min = −1.24 e Å⁻³

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	U_iso*/U_eq	Occ. (<1)
Br1	0.33600 (13)	0.49862 (12)	0.72990 (8)	0.0358 (2)
Br2	0.43682 (13)	−0.00007 (12)	0.71961 (8)	0.0366 (3)
Zn1	0.20560 (17)	0.24153 (16)	0.74480 (11)	0.0259 (3)	0.809 (2)
O1	0.056 (2)	0.137 (2)	0.2086 (8)	0.036 (3)	0.809 (2)
O2	0.2084 (14)	0.3589 (19)	0.1962 (8)	0.034 (3)	0.809 (2)
N1	−0.0223 (12)	0.2369 (13)	0.8687 (7)	0.027 (2)	0.809 (2)
N2	−0.0123 (10)	0.2536 (11)	0.6714 (6)	0.0235 (16)	0.809 (2)
N3	0.1139 (15)	0.2531 (18)	0.2458 (5)	0.027 (2)	0.809 (2)
C1	−0.0292 (14)	0.2250 (15)	0.9678 (9)	0.032 (2)	0.809 (2)
H1A	0.0888	0.2123	0.9868	0.038*	0.809 (2)
C2	−0.2000 (15)	0.2302 (17)	1.0447 (9)	0.036 (3)	0.809 (2)
H2A	−0.1998	0.2239	1.1143	0.043*	0.809 (2)
C3	−0.3711 (15)	0.245 (2)	1.0150 (10)	0.038 (3)	0.809 (2)
H3A	−0.4906	0.2452	1.0647	0.046*	0.809 (2)
C4	−0.3672 (16)	0.259 (2)	0.9150 (10)	0.042 (3)	0.809 (2)
H4A	−0.4839	0.2762	0.8947	0.050*	0.809 (2)
C5	−0.1929 (19)	0.249 (2)	0.8435 (6)	0.029 (2)	0.809 (2)
C6	−0.1789 (12)	0.2637 (12)	0.7350 (8)	0.027 (2)	0.809 (2)
H6A	−0.2922	0.2807	0.7115	0.032*	0.809 (2)
C7	0.0079 (12)	0.2568 (13)	0.5649 (7)	0.022 (2)	0.809 (2)
C8	−0.1213 (16)	0.1964 (17)	0.5189 (8)	0.026 (2)	0.809 (2)
H8A	−0.2320	0.1533	0.5603	0.032*	0.809 (2)
C9	−0.091 (2)	0.198 (2)	0.4148 (11)	0.028 (3)	0.809 (2)
H9A	−0.1801	0.1597	0.3837	0.033*	0.809 (2)
C10	0.074 (3)	0.259 (2)	0.3573 (6)	0.023 (3)	0.809 (2)
C11	0.2013 (19)	0.3242 (17)	0.3996 (9)	0.024 (3)	0.809 (2)
H11A	0.3071	0.3731	0.3575	0.029*	0.809 (2)
C12	0.1737 (16)	0.3183 (16)	0.5044 (8)	0.027 (2)	0.809 (2)
H12A	0.2651	0.3551	0.5345	0.032*	0.809 (2)
Zn1A	−0.4500 (7)	0.2540 (7)	0.7425 (4)	0.0259 (3)	0.191 (2)
O1A	0.101 (12)	0.141 (12)	0.196 (3)	0.036 (3)	0.191 (2)
O2A	0.252 (8)	0.354 (10)	0.211 (3)	0.034 (3)	0.191 (2)
N1A	−0.349 (2)	0.259 (6)	0.8676 (10)	0.027 (2)	0.191 (2)
N2A	−0.1587 (13)	0.243 (4)	0.6709 (11)	0.0235 (16)	0.191 (2)
N3A	0.156 (7)	0.240 (8)	0.2468 (11)	0.027 (2)	0.191 (2)
C1A	−0.441 (3)	0.265 (6)	0.9666 (11)	0.032 (2)	0.191 (2)
H1AA	−0.5778	0.2718	0.9850	0.038*	0.191 (2)
C2A	−0.348 (4)	0.262 (8)	1.0440 (14)	0.036 (3)	0.191 (2)
H2AA	−0.4183	0.2797	1.1130	0.043*	0.191 (2)
C3A	−0.147 (4)	0.233 (9)	1.0156 (16)	0.038 (3)	0.191 (2)
H3AA	−0.0783	0.2113	1.0660	0.046*	0.191 (2)
C4A	−0.051 (3)	0.234 (10)	0.916 (2)	0.042 (3)	0.191 (2)
H4AA	0.0856	0.2229	0.8961	0.050*	0.191 (2)
C5A	−0.154 (3)	0.252 (7)	0.8437 (12)	0.029 (2)	0.191 (2)
C6A	−0.0591 (17)	0.252 (5)	0.7351 (15)	0.027 (2)	0.191 (2)
H6AA	0.0752	0.2576	0.7121	0.032*	0.191 (2)
C7A	−0.072 (2)	0.246 (4)	0.5645 (11)	0.022 (2)	0.191 (2)
C8A	0.108 (4)	0.298 (7)	0.5209 (16)	0.026 (2)	0.191 (2)
H8AA	0.1774	0.3375	0.5635	0.032*	0.191 (2)
C9A	0.187 (6)	0.292 (10)	0.4172 (18)	0.028 (3)	0.191 (2)
H9AA	0.3085	0.3294	0.3875	0.033*	0.191 (2)
C10A	0.083 (8)	0.231 (11)	0.3581 (11)	0.023 (3)	0.191 (2)
C11A	−0.090 (8)	0.169 (11)	0.3986 (17)	0.024 (3)	0.191 (2)
H11B	−0.1520	0.1210	0.3556	0.029*	0.191 (2)
C12A	−0.171 (5)	0.178 (8)	0.5029 (14)	0.027 (2)	0.191 (2)
H12B	−0.2923	0.1394	0.5319	0.032*	0.191 (2)

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Br1	0.0307 (5)	0.0262 (4)	0.0540 (6)	−0.0087 (3)	−0.0146 (5)	−0.0002 (5)
Br2	0.0281 (4)	0.0272 (4)	0.0537 (7)	−0.0054 (3)	−0.0079 (5)	−0.0030 (5)
Zn1	0.0226 (5)	0.0275 (5)	0.0292 (6)	−0.0083 (4)	−0.0068 (5)	−0.0006 (6)
O1	0.041 (9)	0.039 (4)	0.031 (5)	−0.007 (6)	−0.013 (4)	−0.010 (4)
O2	0.037 (7)	0.035 (4)	0.029 (5)	−0.010 (5)	−0.009 (4)	0.009 (4)
N1	0.028 (4)	0.024 (4)	0.031 (5)	−0.005 (3)	−0.008 (4)	0.001 (5)
N2	0.026 (4)	0.016 (4)	0.031 (4)	−0.004 (3)	−0.009 (4)	−0.004 (4)
N3	0.023 (6)	0.029 (4)	0.031 (4)	0.006 (5)	−0.013 (4)	−0.003 (5)
C1	0.026 (5)	0.032 (5)	0.040 (7)	−0.001 (4)	−0.013 (5)	0.003 (6)
C2	0.042 (6)	0.043 (7)	0.017 (5)	−0.007 (6)	0.003 (5)	−0.006 (6)
C3	0.018 (5)	0.065 (9)	0.028 (7)	−0.005 (5)	0.002 (5)	−0.008 (7)
C4	0.023 (5)	0.060 (8)	0.042 (8)	−0.010 (5)	−0.006 (6)	0.012 (8)
C5	0.026 (6)	0.029 (4)	0.034 (5)	−0.009 (5)	−0.008 (5)	−0.009 (5)
C6	0.023 (4)	0.023 (5)	0.037 (6)	−0.006 (4)	−0.011 (5)	0.001 (5)
C7	0.020 (6)	0.020 (4)	0.024 (4)	−0.002 (5)	−0.002 (4)	0.001 (4)
C8	0.025 (6)	0.022 (5)	0.030 (6)	−0.009 (4)	−0.001 (5)	0.000 (5)
C9	0.031 (6)	0.019 (8)	0.033 (7)	−0.004 (5)	−0.008 (5)	−0.007 (5)
C10	0.025 (4)	0.015 (8)	0.027 (4)	0.003 (4)	−0.006 (4)	0.001 (4)
C11	0.033 (6)	0.014 (6)	0.021 (6)	−0.005 (4)	0.001 (5)	0.002 (4)
C12	0.025 (6)	0.027 (5)	0.029 (6)	−0.011 (5)	−0.003 (4)	−0.001 (5)
Zn1A	0.0226 (5)	0.0275 (5)	0.0292 (6)	−0.0083 (4)	−0.0068 (5)	−0.0006 (6)
O1A	0.041 (9)	0.039 (4)	0.031 (5)	−0.007 (6)	−0.013 (4)	−0.010 (4)
O2A	0.037 (7)	0.035 (4)	0.029 (5)	−0.010 (5)	−0.009 (4)	0.009 (4)
N1A	0.028 (4)	0.024 (4)	0.031 (5)	−0.005 (3)	−0.008 (4)	0.001 (5)
N2A	0.026 (4)	0.016 (4)	0.031 (4)	−0.004 (3)	−0.009 (4)	−0.004 (4)
N3A	0.023 (6)	0.029 (4)	0.031 (4)	0.006 (5)	−0.013 (4)	−0.003 (5)
C1A	0.026 (5)	0.032 (5)	0.040 (7)	−0.001 (4)	−0.013 (5)	0.003 (6)
C2A	0.042 (6)	0.043 (7)	0.017 (5)	−0.007 (6)	0.003 (5)	−0.006 (6)
C3A	0.018 (5)	0.065 (9)	0.028 (7)	−0.005 (5)	0.002 (5)	−0.008 (7)
C4A	0.023 (5)	0.060 (8)	0.042 (8)	−0.010 (5)	−0.006 (6)	0.012 (8)
C5A	0.026 (6)	0.029 (4)	0.034 (5)	−0.009 (5)	−0.008 (5)	−0.009 (5)
C6A	0.023 (4)	0.023 (5)	0.037 (6)	−0.006 (4)	−0.011 (5)	0.001 (5)
C7A	0.020 (6)	0.020 (4)	0.024 (4)	−0.002 (5)	−0.002 (4)	0.001 (4)
C8A	0.025 (6)	0.022 (5)	0.030 (6)	−0.009 (4)	−0.001 (5)	0.000 (5)
C9A	0.031 (6)	0.019 (8)	0.033 (7)	−0.004 (5)	−0.008 (5)	−0.007 (5)
C10A	0.025 (4)	0.015 (8)	0.027 (4)	0.003 (4)	−0.006 (4)	0.001 (4)
C11A	0.033 (6)	0.014 (6)	0.021 (6)	−0.005 (4)	0.001 (5)	0.002 (4)
C12A	0.025 (6)	0.027 (5)	0.029 (6)	−0.011 (5)	−0.003 (4)	−0.001 (5)

Br1—Zn1Aⁱ	2.340 (5)	C12—H12A	0.9500
Br1—Zn1	2.3428 (14)	Zn1A—N1A	2.033 (9)
Br2—Zn1	2.3357 (16)	Zn1A—N2A	2.074 (8)
Br2—Zn1Aⁱ	2.339 (5)	Zn1A—Br2ⁱⁱ	2.339 (5)
Zn1—N1	2.034 (9)	Zn1A—Br1ⁱⁱ	2.340 (5)
Zn1—N2	2.074 (7)	O1A—N3A	1.239 (10)
O1—N3	1.239 (10)	O2A—N3A	1.226 (10)
O2—N3	1.226 (10)	N1A—C1A	1.340 (14)
N1—C1	1.340 (14)	N1A—C5A	1.361 (16)
N1—C5	1.361 (16)	N2A—C6A	1.284 (11)
N2—C6	1.284 (11)	N2A—C7A	1.422 (12)
N2—C7	1.421 (12)	N3A—C10A	1.472 (10)
N3—C10	1.472 (10)	C1A—C2A	1.394 (14)
C1—C2	1.394 (14)	C1A—H1AA	0.9500
C1—H1A	0.9500	C2A—C3A	1.394 (15)
C2—C3	1.394 (15)	C2A—H2AA	0.9500
C2—H2A	0.9500	C3A—C4A	1.357 (18)
C3—C4	1.357 (18)	C3A—H3AA	0.9500
C3—H3A	0.9500	C4A—C5A	1.373 (16)
C4—C5	1.373 (16)	C4A—H4AA	0.9500
C4—H4A	0.9500	C5A—C6A	1.459 (14)
C5—C6	1.459 (14)	C6A—H6AA	0.9500
C6—H6A	0.9500	C7A—C8A	1.400 (14)
C7—C8	1.400 (14)	C7A—C12A	1.406 (12)
C7—C12	1.405 (12)	C8A—C9A	1.379 (18)
C8—C9	1.379 (18)	C8A—H8AA	0.9500
C8—H8A	0.9500	C9A—C10A	1.381 (18)
C9—C10	1.381 (18)	C9A—H9AA	0.9500
C9—H9A	0.9500	C10A—C11A	1.380 (19)
C10—C11	1.380 (19)	C11A—C12A	1.390 (16)
C11—C12	1.390 (16)	C11A—H11B	0.9500
C11—H11A	0.9500	C12A—H12B	0.9500

Zn1Aⁱ—Br1—Zn1	64.77 (11)	C7—C12—H12A	120.6
Zn1—Br2—Zn1Aⁱ	64.90 (12)	N1A—Zn1A—N2A	81.2 (3)
N1—Zn1—N2	81.2 (3)	N1A—Zn1A—Br2ⁱⁱ	114.8 (13)
N1—Zn1—Br2	116.1 (3)	N2A—Zn1A—Br2ⁱⁱ	110.8 (8)
N2—Zn1—Br2	118.0 (2)	N1A—Zn1A—Br1ⁱⁱ	111.9 (12)
N1—Zn1—Br1	112.3 (3)	N2A—Zn1A—Br1ⁱⁱ	120.6 (8)
N2—Zn1—Br1	111.5 (2)	Br2ⁱⁱ—Zn1A—Br1ⁱⁱ	113.73 (19)
Br2—Zn1—Br1	113.75 (5)	C1A—N1A—C5A	116.9 (9)
C1—N1—C5	117.0 (8)	C1A—N1A—Zn1A	130.7 (7)
C1—N1—Zn1	130.6 (7)	C5A—N1A—Zn1A	112.4 (7)
C5—N1—Zn1	112.4 (7)	C6A—N2A—C7A	121.1 (8)
C6—N2—C7	121.2 (7)	C6A—N2A—Zn1A	111.5 (6)
C6—N2—Zn1	111.5 (6)	C7A—N2A—Zn1A	127.0 (6)
C7—N2—Zn1	127.2 (5)	O2A—N3A—O1A	124.4 (8)
O2—N3—O1	124.5 (7)	O2A—N3A—C10A	117.9 (9)
O2—N3—C10	118.0 (9)	O1A—N3A—C10A	117.4 (9)
O1—N3—C10	117.5 (9)	N1A—C1A—C2A	123.4 (10)
N1—C1—C2	123.6 (10)	N1A—C1A—H1AA	118.3
N1—C1—H1A	118.2	C2A—C1A—H1AA	118.3
C2—C1—H1A	118.2	C1A—C2A—C3A	117.0 (12)
C1—C2—C3	117.2 (12)	C1A—C2A—H2AA	121.5
C1—C2—H2A	121.4	C3A—C2A—H2AA	121.5
C3—C2—H2A	121.4	C4A—C3A—C2A	119.8 (12)
C4—C3—C2	120.0 (11)	C4A—C3A—H3AA	120.1
C4—C3—H3A	120.0	C2A—C3A—H3AA	120.1
C2—C3—H3A	120.0	C3A—C4A—C5A	119.3 (11)
C3—C4—C5	119.4 (11)	C3A—C4A—H4AA	120.4
C3—C4—H4A	120.3	C5A—C4A—H4AA	120.4
C5—C4—H4A	120.3	N1A—C5A—C4A	122.7 (10)
N1—C5—C4	122.6 (10)	N1A—C5A—C6A	115.1 (9)
N1—C5—C6	115.1 (9)	C4A—C5A—C6A	122.1 (12)
C4—C5—C6	122.1 (11)	N2A—C6A—C5A	119.5 (9)
N2—C6—C5	119.5 (9)	N2A—C6A—H6AA	120.2
N2—C6—H6A	120.2	C5A—C6A—H6AA	120.2
C5—C6—H6A	120.2	C8A—C7A—C12A	119.9 (9)
C8—C7—C12	119.9 (8)	C8A—C7A—N2A	123.9 (8)
C8—C7—N2	123.9 (8)	C12A—C7A—N2A	116.0 (8)
C12—C7—N2	116.1 (8)	C9A—C8A—C7A	121.2 (10)
C9—C8—C7	121.2 (10)	C9A—C8A—H8AA	119.4
C9—C8—H8A	119.4	C7A—C8A—H8AA	119.4
C7—C8—H8A	119.4	C8A—C9A—C10A	117.6 (12)
C8—C9—C10	117.6 (11)	C8A—C9A—H9AA	121.2
C8—C9—H9A	121.2	C10A—C9A—H9AA	121.2
C10—C9—H9A	121.2	C11A—C10A—C9A	122.9 (9)
C11—C10—C9	122.9 (8)	C11A—C10A—N3A	118.6 (12)
C11—C10—N3	118.7 (12)	C9A—C10A—N3A	118.4 (13)
C9—C10—N3	118.4 (13)	C10A—C11A—C12A	119.5 (10)
C10—C11—C12	119.4 (9)	C10A—C11A—H11B	120.3
C10—C11—H11A	120.3	C12A—C11A—H11B	120.3
C12—C11—H11A	120.3	C11A—C12A—C7A	118.7 (10)
C11—C12—C7	118.7 (10)	C11A—C12A—H12B	120.6
C11—C12—H12A	120.6	C7A—C12A—H12B	120.6

Br1—Zn1	2.3428 (14)
Br2—Zn1	2.3357 (16)
Zn1—N1	2.034 (9)
Zn1—N2	2.074 (7)

N1—Zn1—N2	81.2 (3)
N1—Zn1—Br2	116.1 (3)
N2—Zn1—Br2	118.0 (2)
N1—Zn1—Br1	112.3 (3)
N2—Zn1—Br1	111.5 (2)
Br2—Zn1—Br1	113.75 (5)

6 in total

1. A short history of SHELX.

Authors: George M Sheldrick
Journal: Acta Crystallogr A Date: 2007-12-21 Impact factor: 2.290

2. An empirical correction for absorption anisotropy.

Authors: R H Blessing
Journal: Acta Crystallogr A Date: 1995-01-01 Impact factor: 2.290

3. Dibromido{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).

Authors: Mehdi Khalaj; Saeed Dehghanpour; Ali Mahmoudi; Shila Seyedidarzam
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2009-07-11

4. Bromidotricarbon-yl[4-chloro-N-(2-pyridyl-methyl-idene)aniline-κN,N']rhenium(I).

Authors: Mehdi Khalaj; Saeed Dehghanpour; Roghaieh Aleeshah; Ali Mahmoudi
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2010-11-24

5. Di-μ-chlorido-bis-{chlorido[4-nitro-N-(pyridin-2-yl-methyl-idene-κN)aniline-κN]mercury(II)}.

Authors: Sadegh Salehzadeh; Saeed Dehghanpour; Mehdi Khalaj; Mohammad Rahimishakiba
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2011-02-12

6. Structure validation in chemical crystallography.

Authors: Anthony L Spek
Journal: Acta Crystallogr D Biol Crystallogr Date: 2009-01-20

6 in total

2 in total

1. [N,N'-Bis(2,6-dichloro-benzyl-idene)propane-1,3-diamine-κ(2)N,N']dibromidozinc.

Authors: Aliakbar Dehno Khalaji; Gholamhossein Grivani; Mohammad Seyyedi; Karla Fejfarová; Michal Dušek
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2012-06-23

2. Dibromido{2-[(4-fluoro-phen-yl)imino-meth-yl]pyridine-κ(2)N,N'}zinc.

Authors: Saeed Dehghanpour; Ali Mahmoudi
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2012-07-25

2 in total