Literature DB >> 22219775

Poly[bis-[μ-1,3-bis-(diphenyl-phosphan-yl)propane-κP:P']-di-μ-thio-cyanato-κS:N;κN:S-disilver(I)].

Li-Na Cui, Yu-Han Jiang, Li-Li Zhou, Qiong-Hua Jin, Cun-Lin Zhang.

Abstract

In the title coordinpan>ation polymer, [Ag(2)(NCS)(2)(C(27)H(26)P(2))(2)](n), two centrosymmetrically related Ag(+) cations are linked by two thio-cyanate anions into binuclear eight-membered macrocycles. The Ag⋯Ag separation within the macrocycle is 5.4400 (6) Å. The distorted tetra-hedral coordination about each metal atom is completed by the P atoms of two bridging 1,3-bis-(diphenyl-phosphan-yl)propane ligands, forming polymeric ribbons parallel to the a axis.

Entities: CellLine Chemical Disease Gene Species

Year: 2011 PMID： 22219775 PMCID： PMC3246955 DOI： 10.1107/S1600536811041250

Source DB: PubMed Journal: Acta Crystallogr Sect E Struct Rep Online ISSN： 1600-5368

Related literature

For silver(I) pan> class="Chemical">complexes containing phosphane ligands and coordinated anions, see: Jin, Hu et al. (2010 ▶); Jin, Song et al. (2010 ▶); Effendy et al. (2007 ▶). For related structures, see: Cui, Hu et al. (2010 ▶); Cui, Jin et al. (2010 ▶); Mu et al. (2010 ▶); Affandi et al. (1997 ▶).

Experimental

Crystal data

[Ag2(pan> class="Chemical">NCS)2(C27H26P2)2] M = 1156.74 Monon class="Chemical">clinpan>in class="Chemical">c, a = 7.5478 (9) Å b = 15.8275 (17) Å n class="Chemical">c = 22.229 (3) Å β = 99.727 (1)° V = 2617.4 (5) Å3 Z = 2 Mo Kα radiation μ = 0.99 mm−1 T = 298 K 0.42 × 0.21 × 0.15 mm

Data collection

Bruker SMART Cpan> class="Chemical">CD area-detector diffractometer Absorption correction: multi-scan (SADABS; Bruker, 2007 ▶) T min = 0.682, T max = 0.866 12975 measured reflen class="Chemical">ctionpan>s 4605 independent reflen class="Chemical">ctions 3068 reflen class="Chemical">ctionpan>s with I > 2σ(I) R int = 0.042

Refinement

R[F 2 > 2σ(F 2)] = 0.038 wR(F 2) = 0.079 S = 1.03 4605 reflen class="Chemical">ctionpan>s 298 parameters H-atom parameters n class="Chemical">conpan>strainpan>ed Δρmax = 0.44 e Å−3 Δρmin = −0.50 e Å−3 Data collepan> class="Chemical">ction: SMART (Bruker, 2007 ▶); cell refinement: SAINT-Plus (Bruker, 2007 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL. Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536811041250/rz2645sup1.cif Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811041250/rz2645Isup2.hkl Additional supplementary materials: crystallographipan> class="Chemical">c information; 3D view; checkCIF report

[Ag₂(NCS)₂(C₂₇H₂₆P₂)₂]	F(000) = 1176
M_r = 1156.74	D_x = 1.468 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 3146 reflections
a = 7.5478 (9) Å	θ = 2.3–23.9°
b = 15.8275 (17) Å	µ = 0.99 mm⁻¹
c = 22.229 (3) Å	T = 298 K
β = 99.727 (1)°	Prism, white
V = 2617.4 (5) Å³	0.42 × 0.21 × 0.15 mm
Z = 2

Bruker SMART CCD area-detector diffractometer	4605 independent reflections
Radiation source: fine-focus sealed tube	3068 reflections with I > 2σ(I)
graphite	R_int = 0.042
φ and ω scans	θ_max = 25.0°, θ_min = 2.3°
Absorption correction: multi-scan (SADABS; Bruker, 2007)	h = −8→8
T_min = 0.682, T_max = 0.866	k = −18→18
12975 measured reflections	l = −26→23

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.038	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.079	H-atom parameters constrained
S = 1.03	w = 1/[σ²(F_o²) + (0.0218P)² + 2.1307P] where P = (F_o² + 2F_c²)/3
4605 reflections	(Δ/σ)_max = 0.002
298 parameters	Δρ_max = 0.44 e Å⁻³
0 restraints	Δρ_min = −0.50 e Å⁻³

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	U_iso*/U_eq
Ag1	0.67725 (4)	0.369866 (19)	0.563731 (15)	0.04506 (12)
P1	0.84677 (14)	0.23813 (6)	0.56205 (5)	0.0330 (3)
P2	0.53770 (14)	0.35222 (6)	0.65884 (5)	0.0356 (3)
S1	0.82981 (18)	0.51569 (8)	0.57515 (8)	0.0920 (6)
N1	0.5431 (6)	0.6134 (3)	0.51878 (19)	0.0707 (13)
C1	0.6602 (7)	0.5719 (3)	0.5414 (2)	0.0519 (12)
C2	1.0481 (5)	0.2237 (2)	0.61989 (17)	0.0356 (9)
H2A	1.0149	0.2270	0.6601	0.043*
H2B	1.0970	0.1678	0.6154	0.043*
C3	0.1935 (5)	0.2899 (2)	0.61504 (18)	0.0400 (10)
H3A	0.2256	0.2877	0.5746	0.048*
H3B	0.1468	0.3458	0.6209	0.048*
C4	0.3605 (5)	0.2739 (2)	0.66287 (17)	0.0368 (10)
H4A	0.4067	0.2179	0.6568	0.044*
H4B	0.3276	0.2756	0.7032	0.044*
C5	0.9279 (5)	0.2047 (2)	0.49304 (17)	0.0350 (9)
C6	0.9994 (6)	0.2658 (3)	0.46022 (18)	0.0483 (12)
H6	0.9932	0.3223	0.4712	0.058*
C7	1.0802 (7)	0.2442 (3)	0.4110 (2)	0.0641 (14)
H7	1.1306	0.2859	0.3898	0.077*
C8	1.0861 (7)	0.1617 (3)	0.3936 (2)	0.0651 (14)
H8	1.1424	0.1471	0.3609	0.078*
C9	1.0091 (6)	0.1002 (3)	0.4243 (2)	0.0588 (13)
H9	1.0096	0.0442	0.4116	0.071*
C10	0.9309 (5)	0.1216 (3)	0.47387 (18)	0.0449 (11)
H10	0.8795	0.0798	0.4947	0.054*
C11	0.6995 (5)	0.1523 (2)	0.57727 (17)	0.0343 (10)
C12	0.5367 (6)	0.1429 (3)	0.5382 (2)	0.0523 (12)
H12	0.5077	0.1790	0.5050	0.063*
C13	0.4176 (6)	0.0806 (4)	0.5481 (2)	0.0721 (15)
H13	0.3098	0.0743	0.5213	0.087*
C14	0.4571 (7)	0.0281 (3)	0.5973 (3)	0.0702 (15)
H14	0.3768	−0.0142	0.6037	0.084*
C15	0.6145 (7)	0.0377 (3)	0.6370 (2)	0.0641 (14)
H15	0.6407	0.0026	0.6709	0.077*
C16	0.7344 (6)	0.0994 (3)	0.6269 (2)	0.0480 (11)
H16	0.8414	0.1055	0.6542	0.058*
C17	0.4373 (5)	0.4470 (2)	0.68533 (19)	0.0369 (10)
C18	0.3580 (6)	0.5036 (3)	0.6417 (2)	0.0508 (12)
H18	0.3670	0.4949	0.6009	0.061*
C19	0.2658 (7)	0.5725 (3)	0.6579 (3)	0.0698 (15)
H19	0.2119	0.6099	0.6280	0.084*
C20	0.2531 (7)	0.5864 (3)	0.7180 (3)	0.0699 (16)
H20	0.1897	0.6327	0.7290	0.084*
C21	0.3336 (7)	0.5319 (3)	0.7613 (2)	0.0666 (14)
H21	0.3265	0.5416	0.8021	0.080*
C22	0.4260 (6)	0.4621 (3)	0.7455 (2)	0.0532 (12)
H22	0.4806	0.4253	0.7756	0.064*
C23	0.7159 (5)	0.3225 (2)	0.72144 (18)	0.0376 (10)
C24	0.8650 (6)	0.3745 (3)	0.7347 (2)	0.0527 (12)
H24	0.8677	0.4252	0.7136	0.063*
C25	1.0084 (6)	0.3527 (3)	0.7782 (2)	0.0658 (15)
H25	1.1065	0.3889	0.7866	0.079*
C26	1.0090 (7)	0.2786 (4)	0.8094 (2)	0.0685 (15)
H26	1.1063	0.2645	0.8392	0.082*
C27	0.8650 (7)	0.2248 (3)	0.7963 (2)	0.0623 (14)
H27	0.8660	0.1735	0.8168	0.075*
C28	0.7187 (6)	0.2465 (3)	0.75300 (19)	0.0490 (11)
H28	0.6212	0.2099	0.7448	0.059*

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag1	0.0491 (2)	0.03714 (18)	0.0486 (2)	0.00698 (17)	0.00730 (15)	0.00473 (16)
P1	0.0307 (6)	0.0291 (6)	0.0388 (6)	0.0003 (4)	0.0047 (5)	0.0014 (4)
P2	0.0317 (6)	0.0380 (6)	0.0375 (6)	−0.0022 (5)	0.0072 (5)	−0.0028 (5)
S1	0.0498 (9)	0.0493 (8)	0.1629 (16)	−0.0138 (7)	−0.0224 (10)	0.0306 (9)
N1	0.067 (3)	0.062 (3)	0.072 (3)	−0.004 (2)	−0.021 (2)	0.019 (2)
C1	0.060 (3)	0.039 (3)	0.051 (3)	−0.018 (2)	−0.004 (3)	0.006 (2)
C2	0.033 (2)	0.036 (2)	0.038 (2)	−0.0019 (18)	0.0040 (19)	−0.0019 (18)
C3	0.035 (2)	0.037 (2)	0.046 (3)	−0.0038 (19)	0.000 (2)	−0.0005 (19)
C4	0.032 (2)	0.033 (2)	0.045 (3)	−0.0007 (18)	0.005 (2)	−0.0008 (19)
C5	0.032 (2)	0.035 (2)	0.037 (2)	−0.0003 (18)	0.0022 (19)	0.0000 (18)
C6	0.067 (3)	0.038 (3)	0.040 (3)	−0.009 (2)	0.009 (2)	0.001 (2)
C7	0.091 (4)	0.059 (3)	0.046 (3)	−0.025 (3)	0.025 (3)	−0.006 (2)
C8	0.078 (4)	0.077 (4)	0.046 (3)	−0.013 (3)	0.028 (3)	−0.016 (3)
C9	0.078 (4)	0.048 (3)	0.053 (3)	0.001 (3)	0.019 (3)	−0.017 (2)
C10	0.051 (3)	0.038 (3)	0.047 (3)	−0.007 (2)	0.012 (2)	−0.001 (2)
C11	0.031 (2)	0.033 (2)	0.041 (3)	−0.0021 (17)	0.011 (2)	−0.0036 (18)
C12	0.043 (3)	0.059 (3)	0.052 (3)	−0.009 (2)	−0.001 (2)	0.004 (2)
C13	0.039 (3)	0.096 (4)	0.078 (4)	−0.026 (3)	0.001 (3)	−0.014 (3)
C14	0.059 (4)	0.067 (4)	0.091 (4)	−0.031 (3)	0.029 (3)	−0.007 (3)
C15	0.064 (4)	0.048 (3)	0.082 (4)	−0.013 (3)	0.016 (3)	0.021 (3)
C16	0.039 (3)	0.048 (3)	0.056 (3)	−0.006 (2)	0.006 (2)	0.012 (2)
C17	0.027 (2)	0.036 (2)	0.047 (3)	−0.0043 (18)	0.003 (2)	−0.003 (2)
C18	0.051 (3)	0.043 (3)	0.056 (3)	0.000 (2)	0.001 (2)	−0.010 (2)
C19	0.065 (4)	0.041 (3)	0.098 (4)	0.008 (3)	−0.002 (3)	0.000 (3)
C20	0.051 (3)	0.042 (3)	0.117 (5)	0.004 (2)	0.017 (3)	−0.028 (3)
C21	0.068 (4)	0.066 (3)	0.069 (4)	−0.002 (3)	0.023 (3)	−0.026 (3)
C22	0.057 (3)	0.054 (3)	0.049 (3)	0.003 (2)	0.009 (2)	−0.006 (2)
C23	0.033 (2)	0.040 (2)	0.040 (2)	0.0045 (19)	0.008 (2)	−0.0065 (19)
C24	0.044 (3)	0.053 (3)	0.058 (3)	0.001 (2)	−0.001 (2)	−0.012 (2)
C25	0.038 (3)	0.080 (4)	0.075 (4)	−0.001 (3)	−0.005 (3)	−0.029 (3)
C26	0.047 (3)	0.089 (4)	0.063 (4)	0.025 (3)	−0.009 (3)	−0.008 (3)
C27	0.057 (3)	0.069 (3)	0.060 (3)	0.021 (3)	0.007 (3)	0.011 (3)
C28	0.038 (3)	0.056 (3)	0.054 (3)	0.003 (2)	0.010 (2)	0.002 (2)

Ag1—N1ⁱ	2.274 (4)	C11—C16	1.374 (5)
Ag1—P1	2.4499 (10)	C11—C12	1.388 (5)
Ag1—P2	2.5316 (11)	C12—C13	1.377 (6)
Ag1—S1	2.5726 (13)	C12—H12	0.9300
P1—C11	1.823 (4)	C13—C14	1.365 (7)
P1—C5	1.823 (4)	C13—H13	0.9300
P1—C2	1.832 (4)	C14—C15	1.363 (6)
P2—C17	1.823 (4)	C14—H14	0.9300
P2—C23	1.826 (4)	C15—C16	1.376 (5)
P2—C4	1.837 (4)	C15—H15	0.9300
S1—C1	1.633 (5)	C16—H16	0.9300
N1—C1	1.147 (5)	C17—C22	1.375 (5)
N1—Ag1ⁱ	2.274 (4)	C17—C18	1.380 (5)
C2—C3ⁱⁱ	1.535 (5)	C18—C19	1.374 (6)
C2—H2A	0.9700	C18—H18	0.9300
C2—H2B	0.9700	C19—C20	1.375 (7)
C3—C4	1.527 (5)	C19—H19	0.9300
C3—C2ⁱⁱⁱ	1.535 (5)	C20—C21	1.356 (7)
C3—H3A	0.9700	C20—H20	0.9300
C3—H3B	0.9700	C21—C22	1.384 (6)
C4—H4A	0.9700	C21—H21	0.9300
C4—H4B	0.9700	C22—H22	0.9300
C5—C6	1.376 (5)	C23—C24	1.386 (5)
C5—C10	1.384 (5)	C23—C28	1.391 (5)
C6—C7	1.382 (6)	C24—C25	1.369 (6)
C6—H6	0.9300	C24—H24	0.9300
C7—C8	1.365 (6)	C25—C26	1.362 (7)
C7—H7	0.9300	C25—H25	0.9300
C8—C9	1.373 (6)	C26—C27	1.372 (7)
C8—H8	0.9300	C26—H26	0.9300
C9—C10	1.378 (5)	C27—C28	1.381 (6)
C9—H9	0.9300	C27—H27	0.9300
C10—H10	0.9300	C28—H28	0.9300

N1ⁱ—Ag1—P1	113.55 (11)	C5—C10—H10	119.6
N1ⁱ—Ag1—P2	109.61 (12)	C16—C11—C12	117.8 (4)
P1—Ag1—P2	102.18 (4)	C16—C11—P1	124.3 (3)
N1ⁱ—Ag1—S1	103.26 (10)	C12—C11—P1	117.9 (3)
P1—Ag1—S1	122.60 (4)	C13—C12—C11	120.7 (4)
P2—Ag1—S1	105.01 (5)	C13—C12—H12	119.7
C11—P1—C5	103.99 (17)	C11—C12—H12	119.7
C11—P1—C2	103.66 (17)	C14—C13—C12	120.2 (5)
C5—P1—C2	101.39 (17)	C14—C13—H13	119.9
C11—P1—Ag1	107.16 (12)	C12—C13—H13	119.9
C5—P1—Ag1	120.68 (12)	C15—C14—C13	119.9 (5)
C2—P1—Ag1	117.99 (12)	C15—C14—H14	120.0
C17—P2—C23	105.00 (18)	C13—C14—H14	120.0
C17—P2—C4	101.19 (17)	C14—C15—C16	119.9 (5)
C23—P2—C4	103.73 (18)	C14—C15—H15	120.1
C17—P2—Ag1	115.67 (13)	C16—C15—H15	120.1
C23—P2—Ag1	107.94 (13)	C11—C16—C15	121.5 (4)
C4—P2—Ag1	121.62 (13)	C11—C16—H16	119.3
C1—S1—Ag1	98.04 (15)	C15—C16—H16	119.3
C1—N1—Ag1ⁱ	145.6 (4)	C22—C17—C18	118.7 (4)
N1—C1—S1	177.9 (4)	C22—C17—P2	123.7 (3)
C3ⁱⁱ—C2—P1	112.6 (3)	C18—C17—P2	117.5 (3)
C3ⁱⁱ—C2—H2A	109.1	C19—C18—C17	120.7 (4)
P1—C2—H2A	109.1	C19—C18—H18	119.7
C3ⁱⁱ—C2—H2B	109.1	C17—C18—H18	119.7
P1—C2—H2B	109.1	C18—C19—C20	120.2 (5)
H2A—C2—H2B	107.8	C18—C19—H19	119.9
C4—C3—C2ⁱⁱⁱ	110.7 (3)	C20—C19—H19	119.9
C4—C3—H3A	109.5	C21—C20—C19	119.5 (5)
C2ⁱⁱⁱ—C3—H3A	109.5	C21—C20—H20	120.3
C4—C3—H3B	109.5	C19—C20—H20	120.3
C2ⁱⁱⁱ—C3—H3B	109.5	C20—C21—C22	120.8 (5)
H3A—C3—H3B	108.1	C20—C21—H21	119.6
C3—C4—P2	112.1 (3)	C22—C21—H21	119.6
C3—C4—H4A	109.2	C17—C22—C21	120.2 (4)
P2—C4—H4A	109.2	C17—C22—H22	119.9
C3—C4—H4B	109.2	C21—C22—H22	119.9
P2—C4—H4B	109.2	C24—C23—C28	117.7 (4)
H4A—C4—H4B	107.9	C24—C23—P2	118.4 (3)
C6—C5—C10	118.5 (4)	C28—C23—P2	123.6 (3)
C6—C5—P1	117.4 (3)	C25—C24—C23	121.1 (5)
C10—C5—P1	124.1 (3)	C25—C24—H24	119.4
C5—C6—C7	120.7 (4)	C23—C24—H24	119.4
C5—C6—H6	119.6	C26—C25—C24	120.7 (5)
C7—C6—H6	119.7	C26—C25—H25	119.6
C8—C7—C6	120.1 (4)	C24—C25—H25	119.6
C8—C7—H7	119.9	C25—C26—C27	119.5 (5)
C6—C7—H7	119.9	C25—C26—H26	120.2
C7—C8—C9	120.0 (4)	C27—C26—H26	120.2
C7—C8—H8	120.0	C26—C27—C28	120.3 (5)
C9—C8—H8	120.0	C26—C27—H27	119.8
C8—C9—C10	119.8 (4)	C28—C27—H27	119.8
C8—C9—H9	120.1	C27—C28—C23	120.6 (4)
C10—C9—H9	120.1	C27—C28—H28	119.7
C9—C10—C5	120.8 (4)	C23—C28—H28	119.7
C9—C10—H10	119.6

N1ⁱ—Ag1—P1—C11	−72.24 (18)	C5—P1—C11—C16	113.2 (3)
P2—Ag1—P1—C11	45.70 (13)	C2—P1—C11—C16	7.6 (4)
S1—Ag1—P1—C11	162.61 (14)	Ag1—P1—C11—C16	−117.9 (3)
N1ⁱ—Ag1—P1—C5	46.28 (19)	C5—P1—C11—C12	−70.8 (3)
P2—Ag1—P1—C5	164.22 (15)	C2—P1—C11—C12	−176.4 (3)
S1—Ag1—P1—C5	−78.87 (15)	Ag1—P1—C11—C12	58.1 (3)
N1ⁱ—Ag1—P1—C2	171.41 (18)	C16—C11—C12—C13	−2.1 (6)
P2—Ag1—P1—C2	−70.65 (14)	P1—C11—C12—C13	−178.4 (4)
S1—Ag1—P1—C2	46.26 (15)	C11—C12—C13—C14	1.1 (7)
N1ⁱ—Ag1—P2—C17	−71.60 (18)	C12—C13—C14—C15	0.5 (8)
P1—Ag1—P2—C17	167.68 (14)	C13—C14—C15—C16	−1.1 (8)
S1—Ag1—P2—C17	38.74 (15)	C12—C11—C16—C15	1.6 (6)
N1ⁱ—Ag1—P2—C23	171.17 (17)	P1—C11—C16—C15	177.6 (3)
P1—Ag1—P2—C23	50.46 (14)	C14—C15—C16—C11	0.0 (7)
S1—Ag1—P2—C23	−78.48 (14)	C23—P2—C17—C22	−32.1 (4)
N1ⁱ—Ag1—P2—C4	51.68 (18)	C4—P2—C17—C22	75.6 (4)
P1—Ag1—P2—C4	−69.03 (15)	Ag1—P2—C17—C22	−150.9 (3)
S1—Ag1—P2—C4	162.02 (15)	C23—P2—C17—C18	152.4 (3)
N1ⁱ—Ag1—S1—C1	24.7 (2)	C4—P2—C17—C18	−99.9 (3)
P1—Ag1—S1—C1	154.31 (17)	Ag1—P2—C17—C18	33.6 (4)
P2—Ag1—S1—C1	−90.17 (18)	C22—C17—C18—C19	−1.5 (6)
C11—P1—C2—C3ⁱⁱ	179.5 (3)	P2—C17—C18—C19	174.2 (3)
C5—P1—C2—C3ⁱⁱ	71.8 (3)	C17—C18—C19—C20	0.6 (7)
Ag1—P1—C2—C3ⁱⁱ	−62.3 (3)	C18—C19—C20—C21	0.6 (8)
C2ⁱⁱⁱ—C3—C4—P2	−179.7 (3)	C19—C20—C21—C22	−0.9 (8)
C17—P2—C4—C3	69.1 (3)	C18—C17—C22—C21	1.2 (6)
C23—P2—C4—C3	177.8 (3)	P2—C17—C22—C21	−174.2 (3)
Ag1—P2—C4—C3	−60.7 (3)	C20—C21—C22—C17	0.0 (7)
C11—P1—C5—C6	161.6 (3)	C17—P2—C23—C24	−68.3 (3)
C2—P1—C5—C6	−91.1 (3)	C4—P2—C23—C24	−174.1 (3)
Ag1—P1—C5—C6	41.5 (4)	Ag1—P2—C23—C24	55.6 (3)
C11—P1—C5—C10	−22.2 (4)	C17—P2—C23—C28	118.0 (3)
C2—P1—C5—C10	85.2 (4)	C4—P2—C23—C28	12.2 (4)
Ag1—P1—C5—C10	−142.3 (3)	Ag1—P2—C23—C28	−118.1 (3)
C10—C5—C6—C7	−3.1 (6)	C28—C23—C24—C25	−1.3 (6)
P1—C5—C6—C7	173.3 (4)	P2—C23—C24—C25	−175.4 (3)
C5—C6—C7—C8	1.5 (7)	C23—C24—C25—C26	0.6 (7)
C6—C7—C8—C9	1.1 (8)	C24—C25—C26—C27	0.8 (7)
C7—C8—C9—C10	−2.1 (8)	C25—C26—C27—C28	−1.5 (7)
C8—C9—C10—C5	0.4 (7)	C26—C27—C28—C23	0.8 (7)
C6—C5—C10—C9	2.2 (6)	C24—C23—C28—C27	0.6 (6)
P1—C5—C10—C9	−174.1 (3)	P2—C23—C28—C27	174.4 (3)

3 in total

Poly[bis-[μ-1,3-bis-(diphenyl-phosphan-yl)propane-κP:P']-di-μ-thio-cyanato-κS:N;κN:S-disilver(I)].

Related literature

Experimental

Crystal data

Data collection

Refinement

1. A short history of SHELX.

2. (Methanol-κO)(perchlorato-κO)bis-(triphenyl-phosphine-κP)silver(I).

3. (Perchlorato-κO)tris-(triphenyl-phosphine-κP)silver(I).