| Literature DB >> 22218406 |
Massimo Cametti1, Kari Raatikainen, Pierangelo Metrangolo, Tullio Pilati, Giancarlo Terraneo, Giuseppe Resnati.
Abstract
A detailed (1)H-NMR study of the anion binding properties of the 2-iodo-imidazolium receptor 1 in DMSO allows to fully attribute the observed affinities to strong charge-assisted C-I···X(-) halogen bonding (XB). Stronger binding was observed for oxoanions over halides. Phosphate, in particular, binds to 1 with an association constant of ca. 10(3) M(-1), which is particularly high for a single X-bond. A remarkably short C-I···O(-) contact is observed in the structure of the salt 1·H(2)PO(4)(-).Entities:
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Year: 2012 PMID: 22218406 DOI: 10.1039/c1ob06524f
Source DB: PubMed Journal: Org Biomol Chem ISSN: 1477-0520 Impact factor: 3.876