Bis[μ(2)-bis-(diphenyl-phosphan-yl)methane-κP:P']bis-(μ(4)-diphenyl-phosphinato-κO:O:O':O')bis-(μ(2)-trifluoro-acetato-κO:O')tetra-silver(I) acetonitrile disolvate.

In the cation of the title compound, [Ag(4)(C(2)F(3)O(2))(2)(C(12)H(10)O(2)P)(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, the two independent Ag(+) cations are four-coordinated in a distorted tetra-hedral geometry by one P atom from a bis-(diphenyl-phosphan-yl)methane (dppm) ligand, one O atom from a trifluoro-acetate anion and two O atoms from two diphenyl-phosphinate (dpp) ligands. Two dppm ligands, two dpp ligands and two trifluoro-acetate anions bridge four metal atoms, forming a centrosymmetric tetra-nuclear complex. Intra-molecular C-H⋯O hydrogen bonds and a weak π-π inter-action [centroid-centroid distance = 3.9804 (13) Å] are also observed.

Related literature

For applications of metals complexes with diphosphine ligands, see: Catalano & Malwitz (2004 ▶); Chiu & Lee (2005 ▶). For related structures, see: Kuang et al. (2002 ▶); Rudler et al. (1997 ▶); Zank et al. (1999 ▶).

Experimental

Crystal data

[Ag4(C2F3O2)2(C12H10O2P)2(C25H22P2)2]·2C2H3N

M = 1942.70

Monoclinic,

a = 11.724 (5) Å

b = 14.777 (6) Å

c = 24.183 (10) Å

β = 102.254 (5)°

V = 4094 (3) Å3

Z = 2

Mo Kα radiation

μ = 1.13 mm−1

T = 296 K

0.20 × 0.20 × 0.20 mm

Data collection

Rigaku Mercury CCD diffractometer

Absorption correction: multi-scan (CrystalClear-SM Expert; Rigaku, 2009 ▶) T min = 0.806, T max = 0.806

34844 measured reflections

7192 independent reflections

6033 reflections with I > 2σ(I)

R int = 0.057

Refinement

R[F 2 > 2σ(F 2)] = 0.046

wR(F 2) = 0.117

S = 1.01

7192 reflections

480 parameters

60 restraints

H-atom parameters constrained

Δρmax = 1.08 e Å−3

Δρmin = −0.59 e Å−3

Data collection: CrystalClear-SM Expert (Rigaku, 2009 ▶); cell refinement: CrystalClear-SM Expert; data reduction: CrystalClear-SM Expert; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536811045466/rz2658sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811045466/rz2658Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag4(C2F3O2)2(C12H10O2P)2(C25H22P2)2]·2C2H3N	F(000) = 1944
Mr = 1942.70	Dx = 1.576 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 9421 reflections
a = 11.724 (5) Å	θ = 2.1–27.5°
b = 14.777 (6) Å	µ = 1.13 mm−1
c = 24.183 (10) Å	T = 296 K
β = 102.254 (5)°	Prism, colourless
V = 4094 (3) Å3	0.20 × 0.20 × 0.20 mm
Z = 2

Rigaku Mercury CCD diffractometer	7192 independent reflections
Radiation source: fine-focus sealed tube	6033 reflections with I > 2σ(I)
graphite	Rint = 0.057
Detector resolution: 13.6612 pixels mm-1	θmax = 25.0°, θmin = 2.5°
ω scans	h = −13→13
Absorption correction: multi-scan (CrystalClear-SM Expert; Rigaku, 2009)	k = −17→17
Tmin = 0.806, Tmax = 0.806	l = −28→28
34844 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.046	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.117	H-atom parameters constrained
S = 1.01	w = 1/[σ2(Fo2) + (0.0503P)2 + 7.4307P] where P = (Fo2 + 2Fc2)/3
7192 reflections	(Δ/σ)max = 0.001
480 parameters	Δρmax = 1.08 e Å−3
60 restraints	Δρmin = −0.59 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Ag1	0.54210 (3)	0.92166 (3)	0.087708 (16)	0.04807 (13)
Ag2	0.66296 (3)	0.91321 (2)	−0.026597 (15)	0.04551 (13)
C1	0.6904 (4)	0.7175 (3)	0.06180 (18)	0.0384 (10)
H1A	0.7435	0.6710	0.0803	0.046*
H1B	0.6232	0.6873	0.0389	0.046*
C2	0.7857 (4)	0.6966 (3)	−0.0368 (2)	0.0457 (11)
C3	0.8256 (6)	0.6101 (4)	−0.0213 (3)	0.0708 (17)
H3	0.8354	0.5916	0.0162	0.085*
C4	0.8511 (7)	0.5508 (5)	−0.0616 (3)	0.087 (2)
H4	0.8787	0.4930	−0.0508	0.104*
C5	0.8363 (6)	0.5760 (5)	−0.1163 (3)	0.083 (2)
H5	0.8561	0.5364	−0.1427	0.099*
C6	0.7922 (6)	0.6594 (5)	−0.1331 (3)	0.0785 (19)
H6	0.7787	0.6756	−0.1711	0.094*
C7	0.7674 (5)	0.7208 (4)	−0.0931 (2)	0.0618 (14)
H7	0.7384	0.7779	−0.1046	0.074*
C8	0.9111 (4)	0.8015 (3)	0.0557 (2)	0.0438 (11)
C9	0.9731 (5)	0.7357 (4)	0.0905 (3)	0.081 (2)
H9	0.9382	0.6805	0.0951	0.098*
C10	1.0871 (6)	0.7523 (5)	0.1185 (4)	0.106 (3)
H10	1.1290	0.7078	0.1414	0.128*
C11	1.1380 (5)	0.8335 (5)	0.1127 (3)	0.086 (2)
H11	1.2150	0.8435	0.1312	0.103*
C12	1.0781 (6)	0.8999 (5)	0.0803 (3)	0.0767 (18)
H12	1.1129	0.9557	0.0772	0.092*
C13	0.9638 (5)	0.8835 (4)	0.0518 (2)	0.0608 (14)
H13	0.9223	0.9290	0.0296	0.073*
C14	0.5474 (4)	0.7051 (3)	0.14380 (18)	0.0438 (11)
C15	0.5558 (6)	0.6126 (4)	0.1397 (2)	0.0673 (16)
H15	0.6127	0.5872	0.1230	0.081*
C16	0.4787 (7)	0.5568 (5)	0.1607 (3)	0.087 (2)
H16	0.4850	0.4942	0.1584	0.105*
C17	0.3939 (6)	0.5940 (6)	0.1848 (3)	0.085 (2)
H17	0.3410	0.5567	0.1976	0.102*
C18	0.3867 (5)	0.6852 (6)	0.1902 (3)	0.075 (2)
H18	0.3307	0.7098	0.2079	0.090*
C19	0.4623 (4)	0.7420 (4)	0.1696 (2)	0.0590 (14)
H19	0.4563	0.8044	0.1729	0.071*
C20	0.7694 (4)	0.7932 (3)	0.17396 (19)	0.0448 (11)
C21	0.8085 (5)	0.7232 (4)	0.2106 (3)	0.0722 (17)
H21	0.7679	0.6687	0.2071	0.087*
C22	0.9087 (6)	0.7338 (6)	0.2529 (3)	0.091 (2)
H22	0.9336	0.6863	0.2778	0.109*
C23	0.9698 (7)	0.8112 (6)	0.2584 (3)	0.100 (3)
H23	1.0357	0.8174	0.2873	0.120*
C24	0.9360 (7)	0.8798 (6)	0.2221 (4)	0.106 (3)
H24	0.9804	0.9324	0.2252	0.128*
C25	0.8344 (6)	0.8724 (4)	0.1798 (3)	0.0770 (18)
H25	0.8103	0.9208	0.1556	0.092*
C26	0.6109 (4)	1.2297 (3)	0.0284 (2)	0.0469 (12)
C27	0.5551 (6)	1.2773 (4)	0.0637 (3)	0.0758 (19)
H27	0.5217	1.2470	0.0900	0.091*
C28	0.5490 (8)	1.3714 (6)	0.0598 (4)	0.113 (3)
H28	0.5077	1.4036	0.0821	0.135*
C29	0.6024 (9)	1.4159 (5)	0.0238 (5)	0.126 (5)
H29	0.6035	1.4788	0.0242	0.152*
C30	0.6548 (8)	1.3706 (5)	−0.0131 (4)	0.109 (3)
H30	0.6870	1.4023	−0.0393	0.131*
C31	0.6599 (5)	1.2760 (4)	−0.0113 (3)	0.0732 (18)
H31	0.6955	1.2443	−0.0362	0.088*
C32	0.7743 (4)	1.1088 (3)	0.08724 (19)	0.0411 (10)
C33	0.8771 (4)	1.1165 (4)	0.0682 (3)	0.0623 (15)
H33	0.8753	1.1158	0.0295	0.075*
C34	0.9828 (5)	1.1255 (5)	0.1063 (3)	0.083 (2)
H34	1.0516	1.1303	0.0932	0.100*
C35	0.9864 (6)	1.1272 (5)	0.1625 (3)	0.083 (2)
H35	1.0577	1.1337	0.1878	0.099*
C36	0.8866 (6)	1.1196 (5)	0.1822 (3)	0.081 (2)
H36	0.8901	1.1208	0.2210	0.097*
C38	0.3389 (7)	1.0357 (6)	0.2187 (3)	0.0934 (15)
C39	0.3725 (6)	1.0221 (5)	0.1619 (3)	0.0804 (12)
C40	0.8585 (15)	0.3690 (11)	0.1793 (11)	0.393 (18)
H40A	0.9376	0.3619	0.1999	0.590*
H40B	0.8366	0.3177	0.1551	0.590*
H40C	0.8076	0.3734	0.2055	0.590*
C41	0.8488 (9)	0.4537 (7)	0.1442 (6)	0.150 (5)
C37O	0.7795 (3)	1.1099 (2)	0.14489 (10)	0.0608 (14)
H37O	0.7116	1.1042	0.1587	0.073*
F1	0.2990 (3)	1.1197 (2)	0.22513 (10)	0.1335 (18)
F2	0.4197 (3)	1.0317 (2)	0.26317 (10)	0.155 (2)
F3	0.2555 (3)	0.9843 (2)	0.22562 (10)	0.160 (2)
N1	0.8428 (7)	0.5182 (5)	0.1215 (4)	0.124 (3)
O1	0.5435 (3)	1.0716 (2)	0.06592 (14)	0.0466 (8)
O2	0.6484 (3)	1.0685 (2)	−0.01761 (13)	0.0440 (7)
O3	0.4545 (4)	0.9706 (3)	0.16520 (18)	0.0879 (12)
O4	0.3134 (4)	1.0629 (3)	0.12293 (16)	0.0762 (12)
P1	0.76367 (10)	0.78230 (8)	0.01470 (5)	0.0374 (3)
P2	0.64141 (10)	0.78438 (8)	0.11642 (5)	0.0375 (3)
P3	0.63580 (10)	1.10991 (8)	0.03764 (5)	0.0385 (3)

	U11	U22	U33	U12	U13	U23
Ag1	0.0513 (2)	0.0492 (2)	0.0450 (2)	0.01425 (17)	0.01323 (17)	0.00685 (16)
Ag2	0.0429 (2)	0.0487 (2)	0.0454 (2)	0.01025 (16)	0.01052 (16)	0.00678 (15)
C1	0.039 (2)	0.041 (2)	0.036 (2)	0.0013 (19)	0.0084 (18)	0.0010 (18)
C2	0.040 (2)	0.051 (3)	0.050 (3)	−0.003 (2)	0.016 (2)	−0.005 (2)
C3	0.100 (5)	0.055 (3)	0.065 (4)	0.013 (3)	0.033 (3)	−0.006 (3)
C4	0.111 (6)	0.063 (4)	0.094 (5)	0.008 (4)	0.041 (4)	−0.023 (4)
C5	0.084 (5)	0.090 (5)	0.080 (5)	−0.007 (4)	0.029 (4)	−0.042 (4)
C6	0.086 (5)	0.103 (5)	0.049 (3)	−0.006 (4)	0.022 (3)	−0.024 (3)
C7	0.060 (3)	0.076 (4)	0.052 (3)	0.003 (3)	0.016 (3)	−0.010 (3)
C8	0.033 (2)	0.050 (3)	0.048 (3)	0.004 (2)	0.009 (2)	−0.005 (2)
C9	0.046 (3)	0.058 (4)	0.127 (6)	0.003 (3)	−0.012 (3)	0.002 (4)
C10	0.052 (4)	0.079 (5)	0.162 (8)	0.008 (4)	−0.035 (4)	0.005 (5)
C11	0.043 (3)	0.095 (5)	0.109 (6)	−0.002 (4)	−0.006 (3)	−0.021 (4)
C12	0.065 (4)	0.079 (4)	0.083 (5)	−0.028 (4)	0.009 (3)	−0.009 (4)
C13	0.059 (3)	0.062 (3)	0.059 (3)	−0.009 (3)	0.008 (3)	0.007 (3)
C14	0.042 (2)	0.056 (3)	0.033 (2)	−0.004 (2)	0.0079 (19)	0.003 (2)
C15	0.094 (5)	0.064 (4)	0.050 (3)	−0.018 (3)	0.030 (3)	−0.001 (3)
C16	0.134 (7)	0.074 (4)	0.062 (4)	−0.047 (4)	0.036 (4)	−0.004 (3)
C17	0.081 (5)	0.122 (6)	0.054 (4)	−0.048 (5)	0.019 (3)	0.013 (4)
C18	0.043 (3)	0.122 (6)	0.063 (4)	0.004 (4)	0.017 (3)	0.036 (4)
C19	0.048 (3)	0.079 (4)	0.052 (3)	0.009 (3)	0.014 (2)	0.022 (3)
C20	0.043 (3)	0.054 (3)	0.035 (2)	−0.001 (2)	0.0044 (19)	−0.002 (2)
C21	0.063 (4)	0.074 (4)	0.071 (4)	0.002 (3)	−0.005 (3)	0.010 (3)
C22	0.072 (4)	0.116 (6)	0.070 (4)	0.013 (4)	−0.017 (3)	0.020 (4)
C23	0.084 (5)	0.113 (6)	0.083 (5)	−0.004 (5)	−0.028 (4)	−0.005 (5)
C24	0.093 (6)	0.102 (6)	0.105 (6)	−0.029 (5)	−0.024 (5)	−0.024 (5)
C25	0.076 (4)	0.062 (4)	0.082 (4)	−0.001 (3)	−0.007 (3)	−0.007 (3)
C26	0.044 (3)	0.042 (3)	0.046 (3)	0.003 (2)	−0.009 (2)	−0.003 (2)
C27	0.074 (4)	0.064 (4)	0.080 (4)	0.024 (3)	−0.006 (3)	−0.022 (3)
C28	0.115 (7)	0.074 (5)	0.125 (8)	0.035 (5)	−0.030 (6)	−0.045 (5)
C29	0.131 (9)	0.043 (4)	0.162 (11)	0.012 (5)	−0.065 (8)	−0.015 (5)
C30	0.119 (7)	0.060 (5)	0.126 (7)	−0.023 (5)	−0.027 (6)	0.037 (5)
C31	0.072 (4)	0.053 (3)	0.083 (4)	−0.014 (3)	−0.010 (3)	0.017 (3)
C32	0.038 (2)	0.041 (2)	0.043 (3)	−0.001 (2)	0.0029 (19)	−0.0015 (19)
C33	0.041 (3)	0.086 (4)	0.061 (3)	−0.007 (3)	0.011 (2)	−0.008 (3)
C34	0.035 (3)	0.117 (6)	0.094 (5)	−0.010 (3)	0.008 (3)	−0.013 (4)
C35	0.051 (4)	0.101 (5)	0.080 (5)	0.001 (4)	−0.020 (3)	−0.009 (4)
C36	0.075 (4)	0.107 (5)	0.049 (3)	0.004 (4)	−0.015 (3)	−0.002 (3)
C38	0.108 (3)	0.123 (3)	0.062 (3)	0.014 (3)	0.047 (2)	0.003 (3)
C39	0.099 (3)	0.096 (3)	0.060 (2)	0.034 (2)	0.048 (2)	0.013 (2)
C40	0.195 (16)	0.238 (18)	0.68 (4)	−0.046 (14)	−0.05 (2)	0.32 (2)
C41	0.095 (7)	0.094 (7)	0.238 (14)	−0.001 (6)	−0.019 (8)	0.025 (8)
C37O	0.055 (3)	0.075 (4)	0.050 (3)	0.002 (3)	0.004 (2)	0.001 (3)
F1	0.157 (4)	0.148 (4)	0.111 (3)	0.031 (3)	0.061 (3)	−0.034 (3)
F2	0.164 (5)	0.242 (6)	0.056 (3)	0.039 (5)	0.018 (3)	0.006 (3)
F3	0.210 (5)	0.187 (5)	0.121 (4)	−0.077 (4)	0.121 (4)	−0.039 (3)
N1	0.138 (7)	0.076 (5)	0.142 (7)	0.013 (5)	−0.005 (5)	0.022 (4)
O1	0.0314 (16)	0.0489 (19)	0.059 (2)	−0.0002 (14)	0.0086 (14)	0.0036 (15)
O2	0.0459 (18)	0.0400 (17)	0.0433 (18)	0.0018 (14)	0.0030 (14)	−0.0048 (13)
O3	0.108 (3)	0.101 (3)	0.067 (2)	0.042 (2)	0.0471 (19)	0.013 (2)
O4	0.085 (3)	0.103 (3)	0.047 (2)	0.024 (3)	0.027 (2)	0.019 (2)
P1	0.0333 (6)	0.0411 (6)	0.0386 (6)	0.0049 (5)	0.0098 (5)	0.0001 (5)
P2	0.0355 (6)	0.0428 (6)	0.0348 (6)	0.0044 (5)	0.0086 (5)	0.0029 (5)
P3	0.0337 (6)	0.0376 (6)	0.0416 (6)	−0.0001 (5)	0.0021 (5)	−0.0008 (5)

Ag1—O1	2.278 (3)	C20—P2	1.822 (5)
Ag1—P2	2.3685 (14)	C21—C22	1.393 (8)
Ag1—O3	2.430 (4)	C21—H21	0.9300
Ag1—O2i	2.505 (3)	C22—C23	1.342 (10)
Ag1—Ag2	3.3655 (12)	C22—H22	0.9300
Ag2—O2	2.314 (3)	C23—C24	1.343 (11)
Ag2—P1	2.3734 (14)	C23—H23	0.9300
Ag2—O1i	2.416 (3)	C24—C25	1.400 (9)
Ag2—O4i	2.429 (4)	C24—H24	0.9300
C1—P1	1.835 (4)	C25—H25	0.9300
C1—P2	1.837 (4)	C26—C27	1.375 (8)
C1—H1A	0.9700	C26—C31	1.396 (8)
C1—H1B	0.9700	C26—P3	1.800 (5)
C2—C7	1.380 (7)	C27—C28	1.394 (10)
C2—C3	1.386 (8)	C27—H27	0.9300
C2—P1	1.832 (5)	C28—C29	1.346 (14)
C3—C4	1.390 (8)	C28—H28	0.9300
C3—H3	0.9300	C29—C30	1.362 (14)
C4—C5	1.350 (10)	C29—H29	0.9300
C4—H4	0.9300	C30—C31	1.399 (9)
C5—C6	1.365 (10)	C30—H30	0.9300
C5—H5	0.9300	C31—H31	0.9300
C6—C7	1.399 (8)	C32—C37O	1.383 (5)
C6—H6	0.9300	C32—C33	1.384 (7)
C7—H7	0.9300	C32—P3	1.802 (5)
C8—C13	1.373 (7)	C33—C34	1.385 (8)
C8—C9	1.386 (8)	C33—H33	0.9300
C8—P1	1.823 (5)	C34—C35	1.350 (9)
C9—C10	1.386 (8)	C34—H34	0.9300
C9—H9	0.9300	C35—C36	1.359 (10)
C10—C11	1.360 (10)	C35—H35	0.9300
C10—H10	0.9300	C36—C37O	1.390 (7)
C11—C12	1.355 (9)	C36—H36	0.9300
C11—H11	0.9300	C38—F2	1.275 (8)
C12—C13	1.393 (8)	C38—F3	1.277 (9)
C12—H12	0.9300	C38—F1	1.347 (9)
C13—H13	0.9300	C38—C39	1.521 (8)
C14—C15	1.376 (7)	C39—O4	1.206 (7)
C14—C19	1.394 (7)	C39—O3	1.215 (7)
C14—P2	1.826 (5)	C40—C41	1.503 (16)
C15—C16	1.396 (8)	C40—H40A	0.9600
C15—H15	0.9300	C40—H40B	0.9600
C16—C17	1.370 (10)	C40—H40C	0.9600
C16—H16	0.9300	C41—N1	1.096 (11)
C17—C18	1.358 (10)	C37O—H37O	0.9300
C17—H17	0.9300	O1—P3	1.508 (3)
C18—C19	1.388 (8)	O1—Ag2i	2.416 (3)
C18—H18	0.9300	O2—P3	1.505 (3)
C19—H19	0.9300	O2—Ag1i	2.505 (3)
C20—C21	1.376 (7)	O4—Ag2i	2.429 (4)
C20—C25	1.387 (8)
O1—Ag1—P2	150.88 (8)	C21—C22—H22	119.4
O1—Ag1—O3	85.06 (14)	C22—C23—C24	120.1 (7)
P2—Ag1—O3	106.90 (11)	C22—C23—H23	120.0
O1—Ag1—O2i	80.56 (11)	C24—C23—H23	120.0
P2—Ag1—O2i	124.08 (8)	C23—C24—C25	120.4 (7)
O3—Ag1—O2i	92.43 (14)	C23—C24—H24	119.8
O1—Ag1—Ag2	79.70 (9)	C25—C24—H24	119.8
P2—Ag1—Ag2	86.71 (3)	C20—C25—C24	120.2 (7)
O3—Ag1—Ag2	164.76 (12)	C20—C25—H25	119.9
O2i—Ag1—Ag2	85.22 (8)	C24—C25—H25	119.9
O2—Ag2—P1	143.96 (8)	C27—C26—C31	119.6 (6)
O2—Ag2—O1i	81.77 (11)	C27—C26—P3	120.7 (5)
P1—Ag2—O1i	127.51 (8)	C31—C26—P3	119.3 (4)
O2—Ag2—O4i	88.39 (14)	C26—C27—C28	119.5 (8)
P1—Ag2—O4i	111.96 (11)	C26—C27—H27	120.2
O1i—Ag2—O4i	85.26 (13)	C28—C27—H27	120.2
O2—Ag2—Ag1	80.43 (8)	C29—C28—C27	120.5 (9)
P1—Ag2—Ag1	86.74 (3)	C29—C28—H28	119.8
O1i—Ag2—Ag1	76.03 (8)	C27—C28—H28	119.8
O4i—Ag2—Ag1	159.35 (10)	C28—C29—C30	121.3 (8)
P1—C1—P2	115.1 (2)	C28—C29—H29	119.4
P1—C1—H1A	108.5	C30—C29—H29	119.4
P2—C1—H1A	108.5	C29—C30—C31	119.5 (9)
P1—C1—H1B	108.5	C29—C30—H30	120.2
P2—C1—H1B	108.5	C31—C30—H30	120.2
H1A—C1—H1B	107.5	C26—C31—C30	119.4 (8)
C7—C2—C3	118.6 (5)	C26—C31—H31	120.3
C7—C2—P1	118.5 (4)	C30—C31—H31	120.3
C3—C2—P1	122.8 (4)	C37O—C32—C33	118.6 (4)
C2—C3—C4	120.2 (6)	C37O—C32—P3	120.8 (3)
C2—C3—H3	119.9	C33—C32—P3	120.2 (4)
C4—C3—H3	119.9	C32—C33—C34	120.3 (6)
C5—C4—C3	120.8 (7)	C32—C33—H33	119.8
C5—C4—H4	119.6	C34—C33—H33	119.8
C3—C4—H4	119.6	C35—C34—C33	120.3 (6)
C4—C5—C6	120.1 (6)	C35—C34—H34	119.8
C4—C5—H5	119.9	C33—C34—H34	119.8
C6—C5—H5	119.9	C34—C35—C36	120.4 (6)
C5—C6—C7	120.1 (6)	C34—C35—H35	119.8
C5—C6—H6	119.9	C36—C35—H35	119.8
C7—C6—H6	119.9	C35—C36—C37O	120.5 (6)
C2—C7—C6	120.1 (6)	C35—C36—H36	119.8
C2—C7—H7	119.9	C37O—C36—H36	119.8
C6—C7—H7	119.9	F2—C38—F3	108.4 (6)
C13—C8—C9	118.4 (5)	F2—C38—F1	99.1 (6)
C13—C8—P1	119.2 (4)	F3—C38—F1	103.8 (5)
C9—C8—P1	122.4 (4)	F2—C38—C39	117.9 (6)
C10—C9—C8	120.0 (6)	F3—C38—C39	113.1 (7)
C10—C9—H9	120.0	F1—C38—C39	112.9 (6)
C8—C9—H9	120.0	O4—C39—O3	132.8 (6)
C11—C10—C9	120.3 (7)	O4—C39—C38	115.1 (6)
C11—C10—H10	119.9	O3—C39—C38	112.1 (6)
C9—C10—H10	119.9	C41—C40—H40A	109.5
C12—C11—C10	120.9 (6)	C41—C40—H40B	109.5
C12—C11—H11	119.5	H40A—C40—H40B	109.5
C10—C11—H11	119.5	C41—C40—H40C	109.5
C11—C12—C13	119.1 (6)	H40A—C40—H40C	109.5
C11—C12—H12	120.4	H40B—C40—H40C	109.5
C13—C12—H12	120.4	N1—C41—C40	175.8 (18)
C8—C13—C12	121.3 (6)	C32—C37O—C36	119.8 (4)
C8—C13—H13	119.4	C32—C37O—H37O	120.1
C12—C13—H13	119.4	C36—C37O—H37O	120.1
C15—C14—C19	119.3 (5)	P3—O1—Ag1	120.75 (18)
C15—C14—P2	123.7 (4)	P3—O1—Ag2i	122.82 (19)
C19—C14—P2	117.1 (4)	Ag1—O1—Ag2i	97.24 (11)
C14—C15—C16	120.0 (6)	P3—O2—Ag2	120.65 (18)
C14—C15—H15	120.0	P3—O2—Ag1i	109.62 (17)
C16—C15—H15	120.0	Ag2—O2—Ag1i	93.85 (11)
C17—C16—C15	120.1 (7)	C39—O3—Ag1	126.4 (4)
C17—C16—H16	119.9	C39—O4—Ag2i	131.2 (4)
C15—C16—H16	119.9	C8—P1—C2	102.9 (2)
C18—C17—C16	120.3 (6)	C8—P1—C1	105.0 (2)
C18—C17—H17	119.8	C2—P1—C1	102.3 (2)
C16—C17—H17	119.8	C8—P1—Ag2	115.56 (16)
C17—C18—C19	120.5 (6)	C2—P1—Ag2	113.99 (17)
C17—C18—H18	119.7	C1—P1—Ag2	115.47 (15)
C19—C18—H18	119.7	C20—P2—C14	103.4 (2)
C18—C19—C14	119.8 (6)	C20—P2—C1	104.8 (2)
C18—C19—H19	120.1	C14—P2—C1	102.7 (2)
C14—C19—H19	120.1	C20—P2—Ag1	115.88 (17)
C21—C20—C25	118.0 (5)	C14—P2—Ag1	111.04 (16)
C21—C20—P2	123.0 (4)	C1—P2—Ag1	117.35 (15)
C25—C20—P2	118.9 (4)	O2—P3—O1	117.7 (2)
C20—C21—C22	120.1 (6)	O2—P3—C26	109.4 (2)
C20—C21—H21	120.0	O1—P3—C26	108.3 (2)
C22—C21—H21	120.0	O2—P3—C32	110.1 (2)
C23—C22—C21	121.2 (7)	O1—P3—C32	109.1 (2)
C23—C22—H22	119.4	C26—P3—C32	101.0 (2)
O1—Ag1—Ag2—O2	4.02 (11)	O4—C39—O3—Ag1	−0.8 (14)
P2—Ag1—Ag2—O2	−150.12 (8)	C38—C39—O3—Ag1	178.5 (5)
O3—Ag1—Ag2—O2	3.6 (5)	O1—Ag1—O3—C39	48.8 (6)
O2i—Ag1—Ag2—O2	85.27 (11)	P2—Ag1—O3—C39	−158.3 (6)
O1—Ag1—Ag2—P1	150.22 (9)	O2i—Ag1—O3—C39	−31.5 (7)
P2—Ag1—Ag2—P1	−3.92 (4)	Ag2—Ag1—O3—C39	49.2 (10)
O3—Ag1—Ag2—P1	149.8 (5)	O3—C39—O4—Ag2i	−10.2 (14)
O2i—Ag1—Ag2—P1	−128.54 (8)	C38—C39—O4—Ag2i	170.4 (5)
O1—Ag1—Ag2—O1i	−79.80 (12)	C13—C8—P1—C2	112.4 (4)
P2—Ag1—Ag2—O1i	126.07 (8)	C9—C8—P1—C2	−66.9 (5)
O3—Ag1—Ag2—O1i	−80.2 (5)	C13—C8—P1—C1	−140.9 (4)
O2i—Ag1—Ag2—O1i	1.45 (10)	C9—C8—P1—C1	39.8 (5)
O1—Ag1—Ag2—O4i	−54.1 (3)	C13—C8—P1—Ag2	−12.5 (5)
P2—Ag1—Ag2—O4i	151.8 (3)	C9—C8—P1—Ag2	168.2 (4)
O3—Ag1—Ag2—O4i	−54.5 (6)	C7—C2—P1—C8	−112.0 (4)
O2i—Ag1—Ag2—O4i	27.1 (3)	C3—C2—P1—C8	64.6 (5)
C7—C2—C3—C4	2.7 (9)	C7—C2—P1—C1	139.2 (4)
P1—C2—C3—C4	−173.9 (5)	C3—C2—P1—C1	−44.1 (5)
C2—C3—C4—C5	−0.7 (11)	C7—C2—P1—Ag2	13.9 (4)
C3—C4—C5—C6	−2.1 (11)	C3—C2—P1—Ag2	−169.5 (4)
C4—C5—C6—C7	2.9 (11)	P2—C1—P1—C8	78.2 (3)
C3—C2—C7—C6	−1.9 (8)	P2—C1—P1—C2	−174.7 (2)
P1—C2—C7—C6	174.9 (5)	P2—C1—P1—Ag2	−50.3 (3)
C5—C6—C7—C2	−0.9 (10)	O2—Ag2—P1—C8	−26.8 (2)
C13—C8—C9—C10	−2.6 (10)	O1i—Ag2—P1—C8	−165.19 (19)
P1—C8—C9—C10	176.7 (6)	O4i—Ag2—P1—C8	93.4 (2)
C8—C9—C10—C11	1.0 (13)	Ag1—Ag2—P1—C8	−95.58 (17)
C9—C10—C11—C12	1.0 (13)	O2—Ag2—P1—C2	−145.7 (2)
C10—C11—C12—C13	−1.4 (12)	O1i—Ag2—P1—C2	75.89 (19)
C9—C8—C13—C12	2.2 (9)	O4i—Ag2—P1—C2	−25.5 (2)
P1—C8—C13—C12	−177.1 (5)	Ag1—Ag2—P1—C2	145.50 (16)
C11—C12—C13—C8	−0.3 (10)	O2—Ag2—P1—C1	96.2 (2)
C19—C14—C15—C16	0.7 (9)	O1i—Ag2—P1—C1	−42.2 (2)
P2—C14—C15—C16	−178.6 (5)	O4i—Ag2—P1—C1	−143.6 (2)
C14—C15—C16—C17	0.8 (10)	Ag1—Ag2—P1—C1	27.41 (16)
C15—C16—C17—C18	−2.3 (11)	C21—C20—P2—C14	31.1 (5)
C16—C17—C18—C19	2.4 (10)	C25—C20—P2—C14	−152.1 (5)
C17—C18—C19—C14	−0.9 (9)	C21—C20—P2—C1	−76.2 (5)
C15—C14—C19—C18	−0.6 (8)	C25—C20—P2—C1	100.6 (5)
P2—C14—C19—C18	178.7 (4)	C21—C20—P2—Ag1	152.8 (4)
C25—C20—C21—C22	1.6 (9)	C25—C20—P2—Ag1	−30.4 (5)
P2—C20—C21—C22	178.5 (5)	C15—C14—P2—C20	−85.6 (5)
C20—C21—C22—C23	−1.0 (12)	C19—C14—P2—C20	95.1 (4)
C21—C22—C23—C24	−1.2 (14)	C15—C14—P2—C1	23.2 (5)
C22—C23—C24—C25	2.5 (14)	C19—C14—P2—C1	−156.1 (4)
C21—C20—C25—C24	−0.3 (10)	C15—C14—P2—Ag1	149.5 (4)
P2—C20—C25—C24	−177.3 (6)	C19—C14—P2—Ag1	−29.8 (4)
C23—C24—C25—C20	−1.8 (13)	P1—C1—P2—C20	−84.1 (3)
C31—C26—C27—C28	−0.5 (9)	P1—C1—P2—C14	168.1 (2)
P3—C26—C27—C28	172.6 (5)	P1—C1—P2—Ag1	46.0 (3)
C26—C27—C28—C29	−3.5 (12)	O1—Ag1—P2—C20	43.1 (3)
C27—C28—C29—C30	5.9 (14)	O3—Ag1—P2—C20	−68.0 (2)
C28—C29—C30—C31	−4.1 (13)	O2i—Ag1—P2—C20	−173.02 (19)
C27—C26—C31—C30	2.2 (8)	Ag2—Ag1—P2—C20	105.01 (17)
P3—C26—C31—C30	−171.0 (5)	O1—Ag1—P2—C14	160.7 (2)
C29—C30—C31—C26	0.0 (11)	O3—Ag1—P2—C14	49.6 (2)
C37O—C32—C33—C34	−0.1 (9)	O2i—Ag1—P2—C14	−55.46 (19)
P3—C32—C33—C34	173.0 (5)	Ag2—Ag1—P2—C14	−137.43 (16)
C32—C33—C34—C35	−0.4 (11)	O1—Ag1—P2—C1	−81.6 (3)
C33—C34—C35—C36	0.5 (12)	O3—Ag1—P2—C1	167.3 (2)
C34—C35—C36—C37O	0.0 (12)	O2i—Ag1—P2—C1	62.24 (19)
F2—C38—C39—O4	−148.7 (7)	Ag2—Ag1—P2—C1	−19.73 (16)
F3—C38—C39—O4	83.5 (9)	Ag2—O2—P3—O1	−49.7 (3)
F1—C38—C39—O4	−34.0 (10)	Ag1i—O2—P3—O1	57.4 (2)
F2—C38—C39—O3	31.8 (11)	Ag2—O2—P3—C26	−173.8 (2)
F3—C38—C39—O3	−96.0 (8)	Ag1i—O2—P3—C26	−66.7 (2)
F1—C38—C39—O3	146.5 (7)	Ag2—O2—P3—C32	76.0 (2)
C33—C32—C37O—C36	0.6 (7)	Ag1i—O2—P3—C32	−176.91 (18)
P3—C32—C37O—C36	−172.6 (4)	Ag1—O1—P3—O2	56.4 (3)
C35—C36—C37O—C32	−0.5 (9)	Ag2i—O1—P3—O2	−67.5 (3)
P2—Ag1—O1—P3	33.9 (3)	Ag1—O1—P3—C26	−178.9 (2)
O3—Ag1—O1—P3	150.2 (2)	Ag2i—O1—P3—C26	57.2 (3)
O2i—Ag1—O1—P3	−116.5 (2)	Ag1—O1—P3—C32	−69.8 (3)
Ag2—Ag1—O1—P3	−29.65 (19)	Ag2i—O1—P3—C32	166.3 (2)
P2—Ag1—O1—Ag2i	169.19 (9)	C27—C26—P3—O2	155.7 (4)
O3—Ag1—O1—Ag2i	−74.42 (15)	C31—C26—P3—O2	−31.1 (5)
O2i—Ag1—O1—Ag2i	18.88 (12)	C27—C26—P3—O1	26.3 (5)
Ag2—Ag1—O1—Ag2i	105.69 (10)	C31—C26—P3—O1	−160.6 (4)
P1—Ag2—O2—P3	−50.7 (3)	C27—C26—P3—C32	−88.2 (4)
O1i—Ag2—O2—P3	97.1 (2)	C31—C26—P3—C32	84.9 (4)
O4i—Ag2—O2—P3	−177.4 (2)	C37O—C32—P3—O2	−155.2 (3)
Ag1—Ag2—O2—P3	20.03 (18)	C33—C32—P3—O2	31.7 (5)
P1—Ag2—O2—Ag1i	−166.27 (7)	C37O—C32—P3—O1	−24.8 (4)
O1i—Ag2—O2—Ag1i	−18.40 (11)	C33—C32—P3—O1	162.2 (4)
O4i—Ag2—O2—Ag1i	67.05 (14)	C37O—C32—P3—C26	89.1 (4)
Ag1—Ag2—O2—Ag1i	−95.51 (9)	C33—C32—P3—C26	−83.9 (5)

D—H···A	D—H	H···A	D···A	D—H···A
C19—H19···O3	0.93	2.46	3.380 (8)	169
C7—H7···O4i	0.93	2.45	3.368 (7)	171

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C19—H19⋯O3	0.93	2.46	3.380 (8)	169
C7—H7⋯O4i	0.93	2.45	3.368 (7)	171

Symmetry code: (i) .