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Literature DB >> 22190385

An achiral-acid-induced switch in the enantioselectivity of a chiral cis-diamine-based organocatalyst for asymmetric aldol and Mannich reactions.

Shin A Moteki¹, Jianwei Han, Satoru Arimitsu, Matsujiro Akakura, Keiji Nakayama, Keiji Maruoka.

Abstract

Entities: Chemical

Mesh：

Substances：

Year: 2011 PMID： 22190385 DOI： 10.1002/anie.201107239

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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10 in total

1. Formal [4 + 2] cycloaddition of imines with alkoxyisocoumarins.

Authors: Claire L Jarvis; Neyra M Jemal; Spencer Knapp; Daniel Seidel
Journal: Org Biomol Chem Date: 2018-06-13 Impact factor: 3.876

2. Design and synthesis of chiral Zn2+ complexes mimicking natural aldolases for catalytic C-C bond forming reactions in aqueous solution.

Authors: Susumu Itoh; Shotaro Sonoike; Masanori Kitamura; Shin Aoki
Journal: Int J Mol Sci Date: 2014-01-29 Impact factor: 5.923

3. Photoswitchable interlocked thiodiglycolamide as a cocatalyst of a chalcogeno-Baylis-Hillman reaction.

Authors: Alberto Martinez-Cuezva; Adrian Saura-Sanmartin; Tomas Nicolas-Garcia; Cristian Navarro; Raul-Angel Orenes; Mateo Alajarin; Jose Berna
Journal: Chem Sci Date: 2017-03-07 Impact factor: 9.825

4. Reagent-controlled enantioselectivity switch for the asymmetric fluorination of β-ketocarbonyls by chiral primary amine catalysis.

Authors: Yang'en You; Long Zhang; Sanzhong Luo
Journal: Chem Sci Date: 2016-08-26 Impact factor: 9.825

5. Enantiodivergent Steglich rearrangement of O-carboxylazlactones catalyzed by a chirality switchable helicene containing a 4-aminopyridine unit.

Authors: Chien-Tien Chen; Cheng-Che Tsai; Pei-Kang Tsou; Gou-Tao Huang; Chin-Hui Yu
Journal: Chem Sci Date: 2016-08-25 Impact factor: 9.825

An achiral-acid-induced switch in the enantioselectivity of a chiral cis-diamine-based organocatalyst for asymmetric aldol and Mannich reactions.

1. Formal [4 + 2] cycloaddition of imines with alkoxyisocoumarins.

2. Design and synthesis of chiral Zn2+ complexes mimicking natural aldolases for catalytic C-C bond forming reactions in aqueous solution.

3. Photoswitchable interlocked thiodiglycolamide as a cocatalyst of a chalcogeno-Baylis-Hillman reaction.

4. Reagent-controlled enantioselectivity switch for the asymmetric fluorination of β-ketocarbonyls by chiral primary amine catalysis.

5. Enantiodivergent Steglich rearrangement of O-carboxylazlactones catalyzed by a chirality switchable helicene containing a 4-aminopyridine unit.

6. Stereocontrolled synthesis and functionalization of cyclobutanes and cyclobutanones.

7. Enantiodivergence by minimal modification of an acyclic chiral secondary aminocatalyst.

8. An organocatalytic route to 2-heteroarylmethylene decorated N-arylpyrroles.

9. A convenient enantioselective decarboxylative aldol reaction to access chiral α-hydroxy esters using β-keto acids.

10. Effects of Water Addition on a Catalytic Fluorination of Dienamine.