Literature DB >> 22187024

Reductive heterocoupling mediated by Cp*2U(2,2'-bpy).

Adil Mohammad1, Dennis P Cladis, William P Forrest, Phillip E Fanwick, Suzanne C Bart.   

Abstract

Trivalent Cp*(2)U(2,2'-bpy) (2) (Cp* = C(5)Me(5), 2,2'-bpy = 2,2'-bipyridine), which has a monoanionic bipyridine, was treated with p-tolualdehyde (a), furfuraldehyde (b), acetone (c), and benzophenone (d). Reduction of the C[double bond, length as m-dash]O bond followed by radical coupling with bipyridine forms the U(iv) derivatives [Cp*(2)U(2,2'-bpy)(OCRR')] (3a-d). This journal is © The Royal Society of Chemistry 2012

Entities:  

Year:  2011        PMID: 22187024     DOI: 10.1039/c2cc16200h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  The role of uranium-arene bonding in H2O reduction catalysis.

Authors:  Dominik P Halter; Frank W Heinemann; Laurent Maron; Karsten Meyer
Journal:  Nat Chem       Date:  2017-12-11       Impact factor: 24.427

  1 in total

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