| Literature DB >> 22185581 |
Federica Bertini1, Volodymyr Lyaskovskyy, Brian J J Timmer, Frans J J de Kanter, Martin Lutz, Andreas W Ehlers, J Chris Slootweg, Koop Lammertsma.
Abstract
Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu(2)PCH(2)BPh(2) with H(2), CO(2), and isocyanates and supported computationally.Entities:
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Year: 2011 PMID： 22185581 DOI： 10.1021/ja210214r
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419