| Literature DB >> 22181054 |
Masaki Hayashi1, Masatoshi Shibuya, Yoshiharu Iwabuchi.
Abstract
The oxidative conversion of silyl enol ethers to α,β-unsaturated ketones using a less-hindered class of oxoammonium salts (AZADO(+)BF(4)(-)) is described. The reaction proceeds via the ene-like addition of oxoammonium salts to silyl enol ethers.Entities:
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Year: 2011 PMID: 22181054 DOI: 10.1021/ol2029417
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005