Literature DB >> 22175464

Decreasing reactivity with increasing nucleophile basicity. The effect of solvation on .beta.nuc for phosphoryl transfer to amines.

W P Jencks, M T Haber, D Herschlag, K L Nazaretian.   

Abstract

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Year:  1986        PMID: 22175464     DOI: 10.1021/ja00263a019

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


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  5 in total

1.  Molecular basis of the mechanism of thiol oxidation by hydrogen peroxide in aqueous solution: challenging the SN2 paradigm.

Authors:  Ari Zeida; Ryan Babbush; Mariano C González Lebrero; Madia Trujillo; Rafael Radi; Darío A Estrin
Journal:  Chem Res Toxicol       Date:  2012-02-16       Impact factor: 3.739

2.  Structure-reactivity effects on primary deuterium isotope effects on protonation of ring-substituted alpha-methoxystyrenes.

Authors:  Wing-Yin Tsang; John P Richard
Journal:  J Am Chem Soc       Date:  2009-10-07       Impact factor: 15.419

3.  Electronic and solvent effects on kinetics of SNAr substitution reactions of substituted anilines with 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole in MeOH-Me2SO mixtures of varying composition: one reaction with two mechanistic pathways.

Authors:  Nizar El Guesmi; Guillaume Berionni; Basim H Asghar
Journal:  Monatsh Chem       Date:  2013-07-12       Impact factor: 1.451

4.  Reactions of aryl dimethylphosphinothioate esters with anionic oxygen nucleophiles: transition state structure in 70% water-30% ethanol.

Authors:  Georgina I Kalu; Collins I Ubochi; Ikenna Onyido
Journal:  RSC Adv       Date:  2021-02-25       Impact factor: 3.361

Review 5.  Linear Free Energy Relationships for Enzymatic Reactions: Fresh Insight from a Venerable Probe.

Authors:  John P Richard; Judith R Cristobal; Tina L Amyes
Journal:  Acc Chem Res       Date:  2021-05-03       Impact factor: 22.384

  5 in total

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